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    • 5. 发明授权
    • Polyol blend, cellular polyurethane foam product made therefrom, and
halogenated hydrocarbon-free process therefor
    • 多元醇共混物,由其制成的蜂窝状聚氨酯泡沫体产品及其无卤烃类方法
    • US5690855A
    • 1997-11-25
    • US180086
    • 1994-01-11
    • Charles B. NicholsMichael R. SandnerRichard R. Zielinski, II
    • Charles B. NicholsMichael R. SandnerRichard R. Zielinski, II
    • C08G18/48C08J9/08
    • C08G18/4883C08G18/4816C08G2101/0025C08G2101/005C08G2101/0083
    • A polyol blend is disclosed for making cellular polyurethane foam products in the absence of halogenated hydrocarbon blowing agents. The products have good insulating performance, good compressive strength, and excellent dimensional stability. The blend comprises first and second polyols and is suitable for one-shot and two component reaction systems. The first polyol is the reaction product of one or more alkylene oxides and a compound selected from the group consisting of aliphatic diols, triols, pentaerythritol, water in an amount sufficient to form a diol upon reaction with alkylene oxide, and mixtures thereof. The second polyol is the reaction product of one or more alkylene oxides and, in the absence of polyol precursor compounds containing amine moieties, a compound selected from the group consisting of carbohydrates, a mixture of carbohydrates, and a mixture of one or more carbohydrates and one or more compounds selected from the group consisting of aliphatic diols, triols, water in an amount sufficient to form a diol upon reaction with alkylene oxide, and mixtures thereof.
    • 公开了在不存在卤代烃发泡剂的情况下制备多孔聚氨酯泡沫产品的多元醇共混物。 该产品绝缘性能好,抗压强度好,尺寸稳定性好。 共混物包含第一和第二多元醇,并且适用于单次和双组分反应体系。 第一种多元醇是一种或多种烯化氧和选自脂肪族二醇,三醇,季戊四醇,水,足以与烯化氧反应形成二醇的化合物及其混合物的反应产物。 第二多元醇是一种或多种烯化氧的反应产物,并且在不存在含有胺部分的多元醇前体化合物的情况下,选自碳水化合物,碳水化合物的混合物和一种或多种碳水化合物的混合物和 一种或多种选自脂肪族二醇,三醇,足以在与烯化氧反应形成二醇的量的水中的化合物及其混合物。
    • 7. 发明授权
    • Tertiary amine catalyst mixtures useful in cellular polyurethane
formation
    • 可用于细胞聚氨酯形成的叔胺催化剂混合物
    • US4379757A
    • 1983-04-12
    • US191991
    • 1980-09-29
    • Feyyaz O. BaskentMichael R. Sandner
    • Feyyaz O. BaskentMichael R. Sandner
    • C08G18/00C08G18/18C08G18/20B01J31/02
    • C08G18/2027C08G18/1825Y10S521/902Y10S521/904
    • Tertiary amine catalyst mixtures comprising at least one hydroxyalkyl piperazine, preferably 2-hydroxyethyl piperazine or 1,4-di-(2-hydroxyethyl) piperazine, and at least one other tertiary amine for increasing the processability of hydroxyalkyl piperazine in controlling the water-isocyanate reaction rate to obtain optimum performance in cellular polyurethane foam formulations and/or enhancing the compatibility of hydroxyalkyl piperazine with other foaming ingredients in flexible polyester polyurethane foam formulation; and a process for producing cellular polyurethanes, such as flexible polyester or polyether polyurethane foam and high resilience polyether polyurethane foam, by effecting the reaction of an organic polyol reactant and an organic polyisocyanate reactant in the presence of a blowing agent and said tertiary amine catalyst mixture, the resulting cellular polyurethanes exhibiting very low residual amine odor.
    • 包含至少一种羟烷基哌嗪,优选2-羟乙基哌嗪或1,4-二(2-羟乙基)哌嗪的叔胺催化剂混合物和至少一种其它叔胺,用于提高羟基烷基哌嗪在控制水异氰酸酯中的加工性能 反应速率,以获得细胞聚氨酯泡沫制剂中的最佳性能和/或增强羟基烷基哌嗪与柔性聚酯聚氨酯泡沫制剂中其他发泡成分的相容性; 以及通过在发泡剂和所述叔胺催化剂混合物的存在下进行有机多元醇反应物和有机聚异氰酸酯反应物的反应来生产多孔聚氨酯的方法,例如柔性聚酯或聚醚聚氨酯泡沫和高弹性聚醚聚氨酯泡沫体 ,所得的细胞聚氨酯显示非常低的残留胺气味。
    • 8. 发明授权
    • Method of improving the diecuttability of polyester urethane foam and
the improved diecuttable polyester urethane foams themselves
    • 提高聚酯聚氨酯泡沫塑料的可执行性和改进的可再生聚酯聚氨酯泡沫体的方法
    • US4088615A
    • 1978-05-09
    • US645401
    • 1975-12-30
    • Michael R. SandnerWalter R. RosemundRonald D. Carey
    • Michael R. SandnerWalter R. RosemundRonald D. Carey
    • C08G18/28C08G18/66C08G18/14
    • C08G18/283C08G18/6644C08G18/6655
    • Improved diecuttable polyester urethane foams are provided by the inclusion in the foam formulation of specified minor amounts of certain low molecular weight polyols, typically having hydroxyl numbers of 100 or greater. Representative useful species of such polyols include aliphatic alcohols, such as glycerol and erythritol, polymethylols such as trimethylolpropane, alkanolamines such as triethanolamine and relatively low molecular weight alkylene oxide adducts such as propylene - glycerol adducts and the like. Especially effective diecuttable foam formulations are provided by further employing, as co-additives, certain alkylene oxide adducts of linear alcohols or phenols, sulfonated petroleum oils, ammonium salts and silicone-containing copolymers. If desired, the viscosity and compatibility characteristics of the additive and/or additive and co-additive mixture may be modified by the incorporation of a diluent.
    • 通过在泡沫制剂中包含特定的少量某些低分子量多元醇(通常具有100或更大的羟基数)来提供改进的可重复性聚酯聚氨酯泡沫。 这种多元醇的代表性有用物质包括脂族醇,例如甘油和赤藓糖醇,多羟基甲烷如三羟甲基丙烷,链烷醇胺如三乙醇胺和相对低分子量的烯化氧加合物如丙烯 - 甘油加合物等。 通过进一步使用直链醇或酚的某些烯化氧加合物,磺化石油,铵盐和含硅氧烷的共聚物作为共添加剂,提供了特别有效的可再加工泡沫配方。 如果需要,可以通过掺入稀释剂来改变添加剂和/或添加剂和共添加剂混合物的粘度和相容性。