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1. 发明授权

US4767457A Plaster, renders, masonry paints, interior paints and glazes containing an aqueous distearyldiketene emulsion as a water repellent 失效
标题翻译：石膏，涂料，石工漆，内部涂料和釉料，含有二硬脂基杜烯酮水溶液作为防水剂
公开(公告)号：US4767457A
公开(公告)日：1988-08-30
申请号：US924766
申请日：1986-10-30
申请人： Gregor Ley , Michael Melan , Eckehardt Wistuba
发明人： Gregor Ley , Michael Melan , Eckehardt Wistuba
IPC分类号： C09D5/34 , C09D7/12 , C09K3/18
CPC分类号： C09D7/1233 , C04B26/06 , C04B28/04 , C09D5/34 , C04B2111/27
摘要： Plasters, renders, masonry paints, interior paints and glazes which contain from 0.5 to 10% by weight of a distearyldiketene emulsion consisting of(a) from 3 to 40 parts by weight of distearyldiketene,(b) from 10 to 70 parts by weight of a solvent,(c) from 5 to 50 parts by weight of water and(d) from 0.5 to 5 parts by weight of emulsifier have particularly advantageous properties.
摘要翻译：含有0.5〜10重量％的二硬脂基杜烯酮乳液的石膏，涂料，砖石漆，内部涂料和釉料，由（a）3〜40重量份的二硬脂基二乙烯基组成，（b）10〜70重量份的溶剂，（c）5至50重量份的水和（d）0.5至5重量份的乳化剂具有特别有利的性质。

2. 发明授权

US4663384A Paints and renders containing aqueous dispersions of vinylidene chloride/(meth)acrylate copolymers as binders 失效
标题翻译：含有偏二氯乙烯/（甲基）丙烯酸酯共聚物的水性分散体作为粘合剂的涂料和涂料
公开(公告)号：US4663384A
公开(公告)日：1987-05-05
申请号：US793831
申请日：1985-11-01
申请人： Erich Penzel , Walter Prange , Michael Melan , Eckehardt Wistuba , Alfred Mueller
发明人： Erich Penzel , Walter Prange , Michael Melan , Eckehardt Wistuba , Alfred Mueller
IPC分类号： C08L27/08 , C08F214/08 , C08F220/00 , C08F220/10 , C08F220/12 , C08L1/00 , C08L27/00 , C08L33/00 , C08L33/02 , C09D127/04 , C09D133/06
CPC分类号： C08F220/12 , C09D133/064 , C08L33/02
摘要： Paints and renders contain, as binders, aqueous dispersions of copolymers which have a minimum film-forming temperature of from -15.degree. to 20.degree. C. and consist of(a) from 10 to 50% by weight of vinylidene chloride, up to half of which may be replaced with vinyl chloride,(b) from 44 to 88% by weight of esters of acrylic and/or methacrylic acid with alkanols of 1 to 18 carbon atoms and, if required, styrene, vinyl acetate, vinyl propionate or a mixture of these monomers and(c) from 2 to 6% by weight of .alpha.,.beta.-monoolefinically unsaturated mono- and/or dicarboxylic acids of 3 to 5 carbon atoms and/or their amides.
摘要翻译：涂料和涂料作为粘合剂含有最低成膜温度为-15℃至20℃的共聚物的水分散体，并由（a）10至50重量％的偏二氯乙烯组成，最多达一半其中可以用氯乙烯替代，（b）按重量计为44至88％的丙烯酸和/或甲基丙烯酸与1至18个碳原子的链烷醇，如果需要，苯乙烯，乙酸乙烯酯，丙酸乙烯酯或这些单体的混合物和（c）2至6重量％的3至5个碳原子的α，β-单烯属不饱和单 - 和/或二羧酸和/或它们的酰胺。

3. 发明申请

US20050014889A1 Aqueous synthetic resin preparation 有权
标题翻译：水性合成树脂制剂
公开(公告)号：US20050014889A1
公开(公告)日：2005-01-20
申请号：US10494444
申请日：2002-10-29
申请人： Christian Lach , Michael Melan
发明人： Christian Lach , Michael Melan
IPC分类号： C08F220/12 , C08F257/02 , C08F265/04 , C08K5/00 , C08K5/132 , C08L51/00 , C09D151/00 , C09J151/00 , C08J3/00
CPC分类号： C09J151/003 , C08F220/12 , C08F257/02 , C08F265/04 , C08K5/0091 , C08K5/132 , C08L51/003 , C09D151/003
摘要： An aqueous synthetic resin formulation essentially comprising a synthetic resin A, a metallic cation with a charge number of from 2 to 4, dispersants, water, and finely divided fillers, and also, if desired, acetophenone derivatives or benzophenone derivatives, the resin A being prepared by free-radically initiated aqueous emulsion polymerization of monomers in the presence of from 0.01 to 3 parts by weight of an alien polymer seed per 100 parts by weight of the monomer mixture.
摘要翻译：一种水性合成树脂制剂，其基本上包含合成树脂A，电荷数为2至4的金属阳离子，分散剂，水和细碎填料，以及如果需要的话，苯乙酮衍生物或二苯甲酮衍生物，树脂A为通过在每100重量份单体混合物的存在下，在0.01至3重量份的外来聚合物种子的存在下，通过自由基引发的单体水乳液聚合制备。

4. 发明授权

US06566472B1 Binder formulations based on aqueous polymer dispersions 有权
标题翻译：基于含水聚合物分散体的粘合剂配方
公开(公告)号：US06566472B1
公开(公告)日：2003-05-20
申请号：US09640072
申请日：2000-08-17
申请人： Roland Baumstark , Stefan Kirsch , Rolf Dersch , Johannes Dobbelaar , Michael Melan
发明人： Roland Baumstark , Stefan Kirsch , Rolf Dersch , Johannes Dobbelaar , Michael Melan
IPC分类号： C08F22606
CPC分类号： C08F220/12 , C08F212/04 , C09D133/064 , E04C2/042
摘要： Binder formulations based on aqueous polymer dispersions having a minimum film-forming temperature of below 10° C. and comprising at least one binder polymer P in the form of an aqueous dispersion comprising at least one anionic emulsifier and at least one nonionic emulsifier.
摘要翻译：基于具有低于10℃的最低成膜温度的含水聚合物分散体并包含至少一种包含至少一种阴离子乳化剂和至少一种非离子乳化剂的水性分散体形式的粘合剂聚合物P的粘合剂配方。

5. 发明授权

US4654397A Preparation of polymer dispersions which form block-resistant films 失效
标题翻译：制备形成阻挡层的聚合物分散体
公开(公告)号：US4654397A
公开(公告)日：1987-03-31
申请号：US803164
申请日：1985-12-02
申请人： Rudolf Mueller-Mall , Michael Melan , Eckehardt Wistuba , Lothar Matthaei
发明人： Rudolf Mueller-Mall , Michael Melan , Eckehardt Wistuba , Lothar Matthaei
IPC分类号： C08F2/00 , C08F2/22 , C08F2/24 , C08F2/26 , C08F2/28 , C08F20/52 , C08F220/04 , C08F220/10 , C08F220/54 , C08F285/00 , C09D5/00 , C09D5/02 , C09D151/00 , C08F265/02
CPC分类号： C09D151/00 , C08F2/26 , C08F285/00
摘要： A process for the preparation of aqueous polymer dispersions which have a low film-forming temperature but still give films having a high block resistance, and the use of these polymer dispersions as binders for coating materials.
摘要翻译：制备具有低成膜温度但仍得到具有高阻块性的膜的水性聚合物分散体的方法，以及这些聚合物分散体作为涂料的粘合剂的用途。

6. 发明授权

US4358403A Aqueous low-emulsifier dispersions of butadiene-styrene emulsion copolymers containing carboxyl groups 失效
标题翻译：含有羧基的丁二烯 - 苯乙烯乳液共聚物的水性低乳化剂分散体
公开(公告)号：US4358403A
公开(公告)日：1982-11-09
申请号：US292223
申请日：1981-08-12
申请人： Dieter Distler , Michael Melan
发明人： Dieter Distler , Michael Melan
IPC分类号： C08L7/00 , C08F236/10 , C08K5/41 , C08K5/42 , C08L9/08 , C08L21/00 , C08L21/02 , C08L25/00 , C08L25/10 , C09D5/08 , C09D121/00 , C09D125/00 , C09D125/10
CPC分类号： C08L13/02 , C08F236/10 , C08L9/08 , C09D125/10 , C09D5/08
摘要： Aqueous low-emulsifier dispersions of emulsion copolymers which contain, as copolymerized units,(a) from 35 to 55% by weight of butadiene,(b) from 35 to 60% by weight of styrene,(c) from 1 to 3% by weight of .alpha.,.beta.-monoolefinically unsaturated monocarboxylic acids and/or dicarboxylic acids of 3 to 6 carbon atoms,(d) from 1 to 3% by weight of amides of .alpha.,.beta.-monoolefinically unsaturated monocarboxylic acids and/or dicarboxylic acids of 3 to 5 carbon atoms,(e) from 1 to 4% by weight of N-methylolamides of .alpha.,.beta.-monoolefinically unsaturated monocarboxylic acids and/or dicarboxylic acids of 3 to 5 carbon atoms, or their alkyl ethers, and(f) from 1 to 3% by weight of acrylic acid and/or methacrylic acid monoesters of alkanediols of 2 to 6 carbon atoms,the emulsion containing, as emulsifier, from 0.1 to 0.8% by weight, based on emulsion copolymers, of fatty alcohol-sulfonates and/or alkylbenzenesulfonates, where alkyl is of 12 to 16 carbon atoms, are of particular value as binders for aqueous anti-corrosion paints.
摘要翻译：乳液共聚物的水性低乳化剂分散体含有（a）35-55％（重量）丁二烯，（b）35-60％（重量）苯乙烯，（c）1-3％具有3至6个碳原子的α，β-单烯属不饱和单羧酸和/或二羧酸的重量，（d）1至3重量％的α，β-单烯属不饱和一元羧酸和/或二羧酸的酰胺3 至5个碳原子，（e）1至4重量％的α，β-单烯属不饱和单羧酸和/或3至5个碳原子的二羧酸的N-甲基酰胺或其烷基醚，和（f） 1至3重量％的2至6个碳原子的链烷二醇的丙烯酸和/或甲基丙烯酸单酯，乳液含有基于乳液共聚物的0.1至0.8重量％的脂肪醇 - 磺酸盐和 /或烷基苯磺酸盐，其中烷基为12至16个碳原子 ar值作为水性防腐涂料的粘合剂。

7. 发明授权

US4265796A Preparation of aqueous polyacrylate dispersions having improved flow characteristics 失效
标题翻译：具有改善的流动特性的聚丙烯酸酯水分散体的制备
公开(公告)号：US4265796A
公开(公告)日：1981-05-05
申请号：US73300
申请日：1979-09-07
申请人： Rudolf Mueller-Mall , Kurt Wendel , Hans J. Geelhaar , Michael Melan
发明人： Rudolf Mueller-Mall , Kurt Wendel , Hans J. Geelhaar , Michael Melan
IPC分类号： C08F2/00 , C08F2/22 , C08F2/24 , C08F2/38 , C08F20/12 , C08L33/08 , C08L33/10
CPC分类号： C08F20/12
摘要： Aqueous polyacrylate dispersions having improved flow characteristics are prepared by polymerizing esters of acrylic acid and/or methacrylic acid and alkanols of 1 to 10 carbon atoms, with or without admixture of styrene and/or vinyl esters and/or water-soluble monoolefinically unsaturated comonomers (the monomer feed being in the form of an emulsion), in aqueous emulsion in the presence of a free radical polymerization initiator, a protective colloid, a nonionic emulsifier and a regulator, at least a part of the protective colloid being introduced into an aqueous initial charge, and a water-soluble regulator being employed in the initial charge and in the feed.
摘要翻译：具有改善的流动特性的聚丙烯酸酯水分散体通过聚合丙烯酸和/或甲基丙烯酸和具有1-10个碳原子的链烷醇的酯来制备，具有或不包含苯乙烯和/或乙烯基酯和/或水溶性单烯属不饱和共聚单体的混合物（单体进料为乳液形式），在自由基聚合引发剂，保护胶体，非离子乳化剂和调节剂的存在下，在水乳液中，将至少一部分保护胶体引入水性初始电荷和在初始充电和饲料中使用的水溶性调节剂。

8. 发明授权

US07632883B2 Aqueous synthetic resin preparation 有权
标题翻译：水性合成树脂制剂
公开(公告)号：US07632883B2
公开(公告)日：2009-12-15
申请号：US10494444
申请日：2002-10-29
申请人： Christian Lach , Michael Melan
发明人： Christian Lach , Michael Melan
IPC分类号： C08K5/07 , C08K5/04 , C08K3/26 , C08J3/00
CPC分类号： C09J151/003 , C08F220/12 , C08F257/02 , C08F265/04 , C08K5/0091 , C08K5/132 , C08L51/003 , C09D151/003
摘要： An aqueous synthetic resin formulation essentially comprising a synthetic resin A, a metallic cation with a charge number of from 2 to 4, dispersants, water, and finely divided fillers, and also, if desired, acetophenone derivatives or benzophenone derivatives, the resin A being prepared by free-radically initiated aqueous emulsion polymerization of monomers in the presence of from 0.01 to 3 parts by weight of an alien polymer seed per 100 parts by weight of the monomer mixture.
摘要翻译：一种水性合成树脂制剂，其基本上包含合成树脂A，电荷数为2至4的金属阳离子，分散剂，水和细碎填料，以及如果需要的话，苯乙酮衍生物或二苯甲酮衍生物，树脂A为通过在每100重量份单体混合物的存在下，在0.01至3重量份的外来聚合物种子的存在下，通过自由基引发的单体水乳液聚合制备。

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