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    • 4. 发明授权
    • Procedure and device for detecting manipulations at lambda probes
    • 用于检测λ探针操作的步骤和装置
    • US08381567B2
    • 2013-02-26
    • US12611237
    • 2009-11-03
    • Kersten WehmeierMichael FeyAndreas Koring
    • Kersten WehmeierMichael FeyAndreas Koring
    • G01M15/10F02D41/22
    • F02D41/1474F02D41/1495F02D41/222F02D2041/2051F02D2041/2058G01M15/104Y02T10/40
    • A procedure for detecting manipulations at lambda comprises the following steps; the lambda probe is excited by at least one electric excitation signal; at least one electric response signal of the probe is detected; the at least one response signal is compared to at least one default electric response signal that characterizes a not manipulated probe; the deviation of the detected at least one electric response signal from the at least one default electric response signal is used for detecting a manipulation of the probe. A device for detecting manipulations at lambda probes characterized by a switch assembly, with which the probe can be impinged with an electric excitation signal, in particular a step-wise electric excitation, preferably with a current impulse, by a evaluation switch device for evaluating a response signal, in particular the probe voltage and for comparing the excitation signal with the response signal and for assuming a manipulation in the case of a deviation of the response signal from a response signal that characterizes a not manipulated probe.
    • 用于检测λ的操作的过程包括以下步骤: λ探针由至少一个电激励信号激发; 检测探头的至少一个电响应信号; 将至少一个响应信号与表征未被操纵的探针的至少一个默认电响应信号进行比较; 检测到的至少一个电响应信号与至少一个默认电响应信号的偏差用于检测探头的操作。 一种用于检测在λ探针上的操作的装置,其特征在于开关组件,探针可以通过评估开关装置用电激励信号,特别是逐步电激励,优选地以电流脉冲冲击,用于评估 响应信号,特别是探针电压,并用于将激励信号与响应信号进行比较,并且用于在响应信号与表征未操纵的探针的响应信号偏离的情况下进行操作。
    • 6. 发明申请
    • Method for automatic shimming for nuclear magnetic resonance spectroscopy
    • US20080116894A1
    • 2008-05-22
    • US11975207
    • 2007-10-18
    • Markus WeigerMichael FeyThomas Speck
    • Markus WeigerMichael FeyThomas Speck
    • G01R33/38G06F19/00
    • G01R33/3875G01R33/243G01R33/4625G01R33/56572
    • A method for homogenizing a static magnetic field with a magnetic field distribution B0(r) for nuclear magnetic resonance spectroscopy by adjusting the currents Ci through the shim coils, thus creating spatial field distributions Ci·Si(r), where r stands for one, two, or three of the spatial dimensions x, y, and z, and said magnetic field distribution B0(r) has only a field component along z, in a working volume of a magnetic resonance apparatus with one or more radio frequency (=RF) coils (5) for inducing RF pulses and receiving RF signals within a working volume, said RF coils having a spatial sensitivity distribution of magnitudes B1k(r), and with shim coils (6) for homogenizing the magnetic field within the working volume, said shim coils (6) being characterized by their magnetic field distributions per unit current Si(r) and having components only along z, includes the following steps: (a) Mapping the magnetic field distribution B0(r) of the main magnetic field, (b) calculating a simulated spectrum IS(f) based on the sum of the magnetic field distribution B0(r) and the additional field distributions Ci·Si(r) generated by the shim coils (6), and on the sensitivity distributions B1k(r) of the RF coils(5), (c) optimising a quality criterion derived from the simulated spectrum IS(f) by using an optimisation procedure within a search range with the shim currents Ci as a set of parameters, whereby for each new set of parameter values step (b) has to be repeated, (d) realising the found optimum of the quality criterion of step (c) by generating the associated target field distribution B0T(r). In this way a direct one-to-one link is obtained between a set of shim currents and the associated NMR spectrum The quality of the desired NMR spectra can be improved with this method.
    • 7. 发明授权
    • Device for precise centering of an NMR sample tube
    • 用于精确定心的NMR样品管的装置
    • US06867594B2
    • 2005-03-15
    • US10444998
    • 2003-05-27
    • Michael FeyMarcel Urfer
    • Michael FeyMarcel Urfer
    • G01R33/30G01V3/00
    • G01R33/307
    • A device for centering an elongated sample tube (8), filled with a measuring substance, relative to a vertical axis of a nuclear magnetic resonance (NMR) receiver coil system (9) which is rigidly mounted in a support device is characterized in that at least two centering means are provided which are mutually separated in an axial direction of the receiver coil axis and act exclusively in a radial direction on the sample tube (8), one of which is disposed in the upper region (9a) and the other in the lower region (9b, 9b′) of the NMR receiver coil system (9a-k) and with at least one positioning means acting on the sample tube (8) in an exclusively axial direction which may be located either below (20a) or above (17) the NMR receiver coil system, wherein the exclusively radially acting centering means (9a, 9b, 9b′) are components of the NMR receiver coil system (9a-k). The centering accuracy can be increased compared to known devices to obtain optimum results even for sample tubes in the form of measuring capillaries which pose the highest requirements with respect to centering accuracy.
    • 用于使装有测量物质的细长样品管(8)相对于刚性地安装在支撑装置中的核磁共振(NMR)接收器线圈系统(9)的垂直轴定心的装置的特征在于, 提供了至少两个定心装置,其在接收器线圈轴线的轴向方向上相互分离,并且仅在径向方向上作用在样品管(8)上,其中一个设置在上部区域(9a)中,另一个位于 NMR接收器线圈系统(9a-k)的下部区域(9b,9b')和至少一个位于样本管(8)上的排列轴向方向上的定位装置,该位置可以位于(20a)或 (17)NMR接收器线圈系统,其中专用径向作用的定心装置(9a,9b,9b')是NMR接收器线圈系统(9a-k)的组件。 与已知的设备相比,即使对于测量毛细管的样品管而言,相对于已知的设备也可以提高定心精度,这对于定心精度构成最高要求。
    • 8. 发明授权
    • Method and device for correcting a characteristic curve of a two-step lambda oxygen sensor
    • 用于校正两级λ氧传感器特征曲线的方法和装置
    • US09354213B2
    • 2016-05-31
    • US13933920
    • 2013-07-02
    • Michael Fey
    • Michael Fey
    • G01M15/04G01N33/00F02D41/14G01M15/10G01N27/417F02D41/24
    • G01N33/0006F02D41/1454F02D41/1458F02D41/2474G01M15/104G01N27/4175
    • A method and device for correcting a voltage-lambda characteristic curve of a two-step lambda oxygen sensor in an exhaust tract relative to a reference-voltage lambda characteristic curve of the oxygen sensor; a deviation in the characteristic curve relative to the reference characteristic curve at lambda=1 being corrected; based on a value pair on the reference-voltage lambda characteristic curve, the composition of the air-fuel mixture supplied to the engine being changed toward lambda=1; the actual value of lambda being inferred from the change in the composition of the air-fuel mixture. The adaptation of the operating parameters of the oxygen sensor is intended to eliminate the cause of a deviation. Efforts are not merely directed to adapting the deviation to the reference characteristic curve by shifting the voltage-lambda characteristic curve. Effects, which may lead to tolerance- or aging-induced falsifications of the voltage-lambda characteristic curve, can be fully compensated.
    • 一种用于校正相对于氧传感器的参考电压λ特性曲线的排气道中两级λ氧传感器的电压 - 拉特征曲线的方法和装置; 特征曲线相对于λ= 1处的参考特性曲线的偏差被校正; 基于参考电压λ特性曲线上的值对,提供给发动机的空气燃料混合物的组成改变为λ= 1; 根据空气 - 燃料混合物组成的变化推断出λ的实际值。 氧传感器的操作参数的适应性旨在消除偏差的原因。 努力不仅仅是通过移动电压-λ特性曲线来将偏差适应于参考特性曲线。 可能完全补偿了可能导致电压 - 拉特征曲线的公差或老化引起的伪造的影响。
    • 10. 发明授权
    • NMR reaction monitoring flow cell
    • NMR反应监测流通池
    • US08686729B2
    • 2014-04-01
    • US13181105
    • 2011-07-12
    • Brian MarquezMichael FeyKimberly L. ColsonRobert KrullEckhard BezDon PiroliWerner E. Maas
    • Brian MarquezMichael FeyKimberly L. ColsonRobert KrullEckhard BezDon PiroliWerner E. Maas
    • G01V3/00
    • G01N24/08G01R33/307G01R33/31G01R33/46
    • A monitoring cell, used to perform a measurement in an NMR spectrometer of a reaction fluid produced by a reaction vessel, has a body having inlet and outlet transport coaxial capillaries for transporting the reaction fluid between the body and the reaction vessel. Cooling lines are also positioned coaxially with the transport capillaries to transport cooling liquid between the body and the reaction vessel. The cell further has a hollow sample probe for insertion into the NMR spectrometer and a coupler section that removably connects the sample probe to the body so that the inlet transport capillary extends through the body into the interior of the sample probe and the outlet transport capillary is sealed to the sample probe to allow reaction fluid that enters the sample probe via the inlet transport capillary to exit the sample probe via the outlet transport capillary.
    • 用于在由反应容器产生的反应流体的NMR光谱仪中进行测量的监测单元具有用于在体和反应容器之间输送反应流体的入口和出口输送同轴毛细管的主体。 冷却管线也与运输毛细管同轴地定位,以在主体和反应容器之间输送冷却液体。 细胞还具有用于插入NMR光谱仪的中空样品探针和可将样品探针可移除地连接到身体的耦合器部分,使得入口输送毛细管延伸穿过身体进入样品探针的内部,并且出口输送毛细管 密封到样品探针,以允许经由入口输送毛细管进入样品探针的反应流体通过出口输送毛细管离开样品探针。