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1. 发明授权

US07268172B2 Radiation curable compositions 有权
标题翻译：辐射固化组合物
公开(公告)号：US07268172B2
公开(公告)日：2007-09-11
申请号：US10966790
申请日：2004-10-15
申请人： Hermann Bach , Roy B. Clemens , Larry Galeza , Charles A. Gambino , Scott A. Grace , Michael Dvorchak , Ramesh Subramanian
发明人： Hermann Bach , Roy B. Clemens , Larry Galeza , Charles A. Gambino , Scott A. Grace , Michael Dvorchak , Ramesh Subramanian
IPC分类号： C08F2/50
CPC分类号： C08G18/672 , C08G18/6755 , C08L33/066 , C08L33/068 , C08L33/14 , C08L63/10 , C08L2205/02 , C09D175/16 , Y10T428/31504 , C08L2666/04
摘要： The present invention is directed to a composition curable by radiation having a wavelength of 300 nm or more, a method of producing a coated substrate using such composition and the coated product so-produced. More particularly, the composition of the present invention comprises A) from about 1 to about 99% by weight of an unsaturated polymer or oligomer, B) from about 1 to about 99% by weight of an unsaturated epoxy acrylate, C) one or more photoinitiators, and, optionally, D) one or more solvents.
摘要翻译：本发明涉及通过波长为300nm以上的辐射固化的组合物，使用这种组合物制造涂布基材的方法和如此制备的涂布产品。更具体地，本发明的组合物包含A）约1至约99重量％的不饱和聚合物或低聚物，B）约1至约99重量％的不饱和环氧丙烯酸酯，C）一种或多种光引发剂，和任选的D）一种或多种溶剂。

2. 发明申请

US20060293484A1 Low viscosity, ethylenically-unsaturated polyurethanes 审中-公开
标题翻译：低粘度，烯属不饱和聚氨酯
公开(公告)号：US20060293484A1
公开(公告)日：2006-12-28
申请号：US11165681
申请日：2005-06-24
申请人： Carol Kinney , Charles Gambino , Michael Dvorchak , Myron Shaffer
发明人： Carol Kinney , Charles Gambino , Michael Dvorchak , Myron Shaffer
IPC分类号： C08G18/00
CPC分类号： C08G18/73 , C08G18/6725 , C08G18/7837 , C08G18/792 , C08G18/797 , C09D175/16
摘要： The present invention relates to low viscosity, ethylenically-unsaturated polyurethanes which are substantially free from isocyanate groups, are liquid at 25° C., have a total content of ethylenically unsaturated groups (calculated as C═C, MW 24) of 1 to 12% by weight and contain the reaction product of A) 4-isocyanatomethyl-1,8-octamethylene diisocyanate (NTI) with B) a hydroxyl component comprising i) 5 to 100 hydroxyl equivalent % of one or more hydroxy functional lactone ester (meth)acrylates having a number average molecular weight of about 200 to 1000, ii) up to 95 hydroxyl equivalent % of a monohydroxy-functional, ethylenically unsaturated compound other than B-i), and iii) up to 20 hydroxyl equivalent % of a saturated hydroxyl compound or an unsaturated hydroxyl compound other than B-i) or B-ii), wherein i) the hydroxyl equivalent %'s of components B-i), B-ii) and B-iii) add up to 100%, based on the total weights of components B-i), B-ii) and B-iii) and ii) the NCO:OH equivalent ratio of component A) to component B) is 1.10:1 to 1:1.10. The present invention also relates to a one-component coating composition containing these ethylenically unsaturated polyurethanes.
摘要翻译：本发明涉及基本上不含异氰酸酯基团的低粘度烯键式不饱和聚氨酯，在25℃下为液体，烯属不饱和基团的总含量（以CC，MW 24计算）为1〜12％，含量为1〜12％含有A）4-异氰酸甲酯基-1,8-八亚甲基二异氰酸酯（NTI）与B）羟基组分的反应产物，其包含i）5至100个羟基当量％的一种或多种羟基官能的内酯酯（甲基）丙烯酸酯，其具有数均分子量为约200至1000，ii）除Bi之外的至多95羟基当量％的单羟基官能的烯键式不饱和化合物），和iii）饱和羟基化合物或不饱和羟基化合物的至多20羟基当量％除了Bi）或B-ii）之外的羟基化合物，其中i）组分Bi），B-ii）和B-iii的羟基当量％）基于组分Bi）的总重量加起来为100％，B-ii）和B-iii）和ii）NCO:OH等同物组分A）与组分B）的比例为1.10:1-1:1.10。本发明还涉及含有这些烯属不饱和聚氨酯的单组分涂料组合物。

3. 发明申请

US20060084713A1 Radiation curable compositions 有权
标题翻译：辐射固化组合物
公开(公告)号：US20060084713A1
公开(公告)日：2006-04-20
申请号：US10966790
申请日：2004-10-15
申请人： Hermann Bach , Roy Clemens , Larry Galeza , Charles Gambino , Scott Grace , Michael Dvorchak , Ramesh Subramanian
发明人： Hermann Bach , Roy Clemens , Larry Galeza , Charles Gambino , Scott Grace , Michael Dvorchak , Ramesh Subramanian
IPC分类号： C08G65/18
CPC分类号： C08G18/672 , C08G18/6755 , C08L33/066 , C08L33/068 , C08L33/14 , C08L63/10 , C08L2205/02 , C09D175/16 , Y10T428/31504 , C08L2666/04
摘要： The present invention is directed to a composition curable by radiation having a wavelength of 300 nm or more, a method of producing a coated substrate using such composition and the coated product so-produced. More particularly, the composition of the present invention comprises A) from about 1 to about 99% by weight of an unsaturated polymer or oligomer, B) from about 1 to about 99% by weight of an unsaturated epoxy acrylate, C) one or more photoinitiators, and, optionally, D) one or more solvents.
摘要翻译：本发明涉及通过波长为300nm以上的辐射固化的组合物，使用这种组合物制造涂布基材的方法和如此制备的涂布产品。更具体地，本发明的组合物包含A）约1至约99重量％的不饱和聚合物或低聚物，B）约1至约99重量％的不饱和环氧丙烯酸酯，C）一种或多种光引发剂，和任选的D）一种或多种溶剂。

4. 发明申请

US20050238815A1 UV curable coating composition 审中-公开
标题翻译：紫外线固化涂料组合物
公开(公告)号：US20050238815A1
公开(公告)日：2005-10-27
申请号：US10832510
申请日：2004-04-27
申请人： Michael Dvorchak , Larry Galeza , Robert Wade , Clifford Bridges , Ramesh Subramanian
发明人： Michael Dvorchak , Larry Galeza , Robert Wade , Clifford Bridges , Ramesh Subramanian
IPC分类号： C08F299/06 , C08G18/08 , C08G18/12 , C08G18/42 , C08G18/48 , C08G18/66 , C08G18/67 , C08G18/70 , C08L75/14 , C08L75/16 , C09D5/00 , C09D7/12 , C09D167/00 , C09D167/07 , C09D175/04 , C09D175/14 , C09D175/16 , C08F2/46
CPC分类号： C08G18/4288 , C08G18/0823 , C08G18/12 , C08G18/4854 , C08G18/6692 , C08G18/672 , C08G18/706 , C08L75/14 , C08L75/16 , C09D167/07 , C09D175/16 , C08G18/3228 , C08G18/42 , C08L2666/20
摘要： The present invention is directed to a composition curable by radiation having a wavelength of 300 nm or more, a method of producing a coated substrate using such composition and the coated product so-produced. More particularly, the composition of the present invention comprises A) from about 1 to about 99% by weight of a specific aqueous polyurethane dispersion having a solids content of from about 20 to about 50% by weight, B) from about 1 to about 99% by weight of an aqueous polyester acrylate/urethane dispersion having a solids content of from about 20 to about 60% by weight, C) one or more photoinitiators, and D) water or a mixture of water and solvent
摘要翻译：本发明涉及通过波长为300nm以上的辐射固化的组合物，使用这种组合物制造涂布基材的方法和如此制备的涂布产品。更具体地，本发明的组合物包含A）约1至约99重量％的固体含量为约20至约50重量％的特定水性聚氨酯分散体，B）约1至约99 重量％的固体含量为约20至约60重量％的聚酯丙烯酸酯/聚氨酯分散体水溶液，C）一种或多种光引发剂，和D）水或水和溶剂的混合物

5. 发明申请

US20050154076A1 UV curable coating composition 有权
标题翻译：紫外线固化涂料组合物
公开(公告)号：US20050154076A1
公开(公告)日：2005-07-14
申请号：US11054020
申请日：2005-02-09
申请人： Hermann Bach , Charles Gambino , Michael Dvorchak , Michael Jeffries , Richard Roesler , Ramesh Subramanian
发明人： Hermann Bach , Charles Gambino , Michael Dvorchak , Michael Jeffries , Richard Roesler , Ramesh Subramanian
IPC分类号： C08G2/00 , C08G18/67 , C08G18/79 , C09D175/16
CPC分类号： C09D175/16 , C08G18/4277 , C08G18/672 , C08G18/6725 , C08G18/792 , Y10T428/31504 , Y10T428/31551 , C08G18/42
摘要： The present invention is directed to a non-aqueous composition curable by UV radiation broadly comprising a mixture of two UV curable urethane acrylates. The invention is also directed to a coating process using such composition. One of the urethane acrylates is the reaction product of an isocyanate and a specific OH functional lactone ester (meth)acrylate. The other urethane acrylate is the reaction product of an isocyanate and a specific hydroxy functional (meth)acrylate.
摘要翻译：本发明涉及通过紫外线辐射固化的非水性组合物，其广泛地包含两种UV可固化聚氨酯丙烯酸酯的混合物。本发明还涉及使用这种组合物的涂覆方法。氨基甲酸酯丙烯酸酯之一是异氰酸酯和特定的OH官能的内酯酯（甲基）丙烯酸酯的反应产物。另一种氨基甲酸酯丙烯酸酯是异氰酸酯和特定的羟基官能（甲基）丙烯酸酯的反应产物。

6. 发明申请

US20050090620A1 Acrylate-functional blocked polyisocyanate resin for UV/thermally curable coatings 有权
标题翻译：用于UV /热固化涂料的丙烯酸酯官能封端多异氰酸酯树脂
公开(公告)号：US20050090620A1
公开(公告)日：2005-04-28
申请号：US10694107
申请日：2003-10-27
申请人： Scott Grace , Michael Dvorchak , Richard Roesler , Dinesh Pethiyagoda , Michael Jeffries , Jan Weikard
发明人： Scott Grace , Michael Dvorchak , Richard Roesler , Dinesh Pethiyagoda , Michael Jeffries , Jan Weikard
IPC分类号： C08G18/42 , C08G18/67 , C08G18/76 , C08G18/79 , C08G18/80 , C08G18/81 , C09D175/16 , C08F4/00
CPC分类号： C08G18/792 , C08G18/4208 , C08G18/4238 , C08G18/672 , C08G18/807 , C08G18/8175 , C09D175/16 , C08G18/42
摘要： Solvent-based, dual cure coatings incorporating thermally curable blocked polyisocyanates, which also contain unsaturated linkages, and a method for preparing these coatings. The unsaturated linkages, such as acrylate groups, can be crosslinked by free-radical mechanisms such as UV curing.
摘要翻译：含有可热固化的封端多异氰酸酯（也含有不饱和键的溶剂型双重固化涂层）和制备这些涂层的方法。不饱和键如丙烯酸酯基团可以通过自由基机制如UV固化而交联。

7. 发明申请

US20050003102A1 UV-curable waterborne polyurethane dispersions for soft touch coatings 审中-公开
标题翻译： UV可固化水性聚氨酯分散体用于柔软触感涂料
公开(公告)号：US20050003102A1
公开(公告)日：2005-01-06
申请号：US10600013
申请日：2003-06-20
申请人： Aaron Lockhart , Michael Dvorchak , Lyubov Gindin
发明人： Aaron Lockhart , Michael Dvorchak , Lyubov Gindin
IPC分类号： C08F2/48 , C08G18/08 , C08G18/12 , C08G18/44 , C08G18/66 , C08G18/68 , C09D175/14 , B05D3/06 , C08G18/00
CPC分类号： C09D175/14 , C08G18/0823 , C08G18/12 , C08G18/44 , C08G18/6637 , C08G18/68 , C08G18/3228
摘要： The present invention is directed to a waterborne, UV-curable polyurethane emulsion and the use thereof in producing soft touch coatings. The emulsion is prepared by a) reacting specified hydroxy-functional components with di- and/or polyisocyanates, b) forming a dispersion of the resultant product with water and reacting the dispersion with amine functional materials.
摘要翻译：本发明涉及一种水性UV可固化聚氨酯乳液及其在生产软触摸涂层中的用途。乳液通过以下步骤制备：a）使特定的羟基官能组分与二 - 和/或多异氰酸酯反应，b）使所得产物与水分散，并使该分散体与胺官能材料反应。

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