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1. 发明授权

US07381774B2 Perfluoroelastomer compositions for low temperature applications 有权
标题翻译：用于低温应用的全氟弹性体组合物
公开(公告)号：US07381774B2
公开(公告)日：2008-06-03
申请号：US11257539
申请日：2005-10-25
申请人： Christopher John Bish , Michael Cregg Coughlin
发明人： Christopher John Bish , Michael Cregg Coughlin
IPC分类号： C08F214/18
CPC分类号： C08G65/007 , C08G2650/48 , C08L27/18 , C08L71/00 , C08L2666/14 , C08L2666/04
摘要： Perfluoroelastomers that contain high levels (i.e. about 40 mole percent or more) of perfluoro(alkyl vinyl ether) copolymerized units can form stable blends with higher levels of perfluoropolyethers than can perfluoroelastomers that contain lower levels of perfluoro(alkyl vinyl ether) units. Thus, the former blends have better low temperature properties than the latter.
摘要翻译：含有高水平（即约40摩尔％以上）全氟（烷基乙烯基醚）共聚单元的全氟弹性体可以形成具有比含有较低水平全氟（烷基乙烯基醚）单元的全氟弹性体更高水平的全氟聚醚的稳定共混物。因此，前者的混合物具有比后者更好的低温性能。

2. 发明授权

US07989566B2 Process for producing fluoropolymers 有权
标题翻译：制备含氟聚合物的方法
公开(公告)号：US07989566B2
公开(公告)日：2011-08-02
申请号：US12354218
申请日：2009-01-15
申请人： Michael Cregg Coughlin , Ming-Hong Hung
发明人： Michael Cregg Coughlin , Ming-Hong Hung
IPC分类号： C08F12/20
CPC分类号： C08F14/18 , C07F9/091 , C08F2/26 , C08F2/20
摘要： An emulsion polymerization process for the production of non-elastomeric fluoropolymers is disclosed wherein at least one fluorosurfactant is employed as dispersant, said fluorosurfactant being a fluoroalkylphosphoric acid ester of the formula X-Rf-(CH2)n—O—P(O)(OM)2, wherein n is 1 or 2, X═H or F, M=a univalent cation, and Rf is a C4-C6 fluoroalkyl or fluoroalkoxy group. Optionally, a second dispersing agent may be employed in the polymerization, said second agent being a perfluoropolyether having at least one endgroup selected from the group consisting of carboxylic acid, a salt thereof, sulfonic acid and a salt thereof, phosphoric acid and a salt thereof.
摘要翻译：公开了一种用于生产非弹性体含氟聚合物的乳液聚合方法，其中使用至少一种含氟表面活性剂作为分散剂，所述含氟表面活性剂是式X-Rf-（CH 2）n -O-P（O）的氟代烷基磷酸酯 OM）2，其中n为1或2，X = H或F，M =单价阳离子，Rf为C4-C6氟烷基或氟代烷氧基。任选地，在聚合中可以使用第二分散剂，所述第二试剂是具有至少一个选自羧酸，其盐，磺酸及其盐的端基的全氟聚醚，磷酸及其盐。

3. 发明授权

US07754810B2 Process for producing fluoropolymers 失效
标题翻译：制备含氟聚合物的方法
公开(公告)号：US07754810B2
公开(公告)日：2010-07-13
申请号：US12255082
申请日：2008-10-21
申请人： Michael Cregg Coughlin , Ming-Hong Hung , Phan Linh Tang
发明人： Michael Cregg Coughlin , Ming-Hong Hung , Phan Linh Tang
IPC分类号： C08K5/01
CPC分类号： C08F14/18 , C08F214/26 , C08F2/26 , C08F2/22
摘要： An emulsion polymerization process for the production of fluoropolymers is disclosed wherein a combination of at least two fluorosurfactants is employed as dispersants. At least one fluorosurfactant is a perfluoroalkyl or perfluoroalkoxy sulfinate. At least one other fluorosurfactant is a perfluoropolyether having at least one endgroup selected from the group consisting of carboxylic acid, a slat thereof, sulfonic acid and a salt thereof.
摘要翻译：公开了用于生产含氟聚合物的乳液聚合方法，其中使用至少两种含氟表面活性剂的组合作为分散剂。至少一种含氟表面活性剂是全氟烷基或全氟烷氧基亚磺酸酯。至少一种其它含氟表面活性剂是具有至少一个选自羧酸，其盐，磺酸及其盐的端基的全氟聚醚。

4. 发明授权

US5789489A Fast-curing perfluoroelastomer composition 失效
标题翻译：快速固化全氟弹性体组合物
公开(公告)号：US5789489A
公开(公告)日：1998-08-04
申请号：US908762
申请日：1997-08-08
申请人： Michael Cregg Coughlin , Charles David Monaco
发明人： Michael Cregg Coughlin , Charles David Monaco
IPC分类号： C08F8/00 , C08F8/42 , C08F214/26
CPC分类号： C08F214/262 , C08K5/57
摘要： Fast curing perfluoroelastomer compositions are provided which comprise a perfluoroelastomer having a plurality of nitrile groups and a plurality of carboxyl-containing groups, carboxylate-containing groups, carboxamide groups, or mixtures thereof; and an organotin curing agent.
摘要翻译：提供快速固化全氟弹性体组合物，其包含具有多个腈基和多个含羧基的全氟弹性体，含羧酸酯的基团，羧酰胺基团或其混合物; 和有机锡固化剂。

5. 发明授权

US07999049B2 Process for producing fluoroelastomers 有权
标题翻译：制备含氟弹性体的方法
公开(公告)号：US07999049B2
公开(公告)日：2011-08-16
申请号：US12354195
申请日：2009-01-15
申请人： Michael Cregg Coughlin , Ming-Hong Hung , Phan Linh Tang
发明人： Michael Cregg Coughlin , Ming-Hong Hung , Phan Linh Tang
IPC分类号： C08F12/20
CPC分类号： C08F14/18 , C07F9/091 , C08F2/26 , C08F2/20
摘要： An emulsion polymerization process for the production of fluoroelastomers is disclosed wherein at least one fluorosurfactant is employed as dispersant, said fluorosurfactant being a fluoroalkylphosphoric acid ester of the formula X—Rf-(CH2)n—O—P(O)(OM)2, wherein n=1 or 2, X=H or F, M=a univalent cation, and Rf is a C4-C6 fluoroalkyl or fluoroalkoxy group. Optionally, a second dispersing agent may be employed in the polymerization, said second agent being a perfluoropolyether having at least one endgroup selected from the group consisting of carboxylic acid, a salt thereof, sulfonic acid and a salt thereof, phosphoric acid and a salt thereof.
摘要翻译：公开了用于生产含氟弹性体的乳液聚合方法，其中使用至少一种含氟表面活性剂作为分散剂，所述含氟表面活性剂是式X-Rf-（CH2）n-O-P（O）（OM）2的氟代烷基磷酸酯其中n = 1或2，X = H或F，M =一价阳离子，Rf为C4-C6氟代烷基或氟代烷氧基。任选地，在聚合中可以使用第二分散剂，所述第二试剂是具有至少一个选自羧酸，其盐，磺酸及其盐的端基的全氟聚醚，磷酸及其盐。

6. 发明申请

US20090186997A1 PROCESS FOR PRODUCING FLUOROELASTOMERS 有权
标题翻译：生产荧光体的方法
公开(公告)号：US20090186997A1
公开(公告)日：2009-07-23
申请号：US12354195
申请日：2009-01-15
申请人： Michael Cregg Coughlin , Ming-Hong Hung , Phan Linh Tang
发明人： Michael Cregg Coughlin , Ming-Hong Hung , Phan Linh Tang
IPC分类号： C08F2/00 , C07F9/141
CPC分类号： C08F14/18 , C07F9/091 , C08F2/26 , C08F2/20
摘要： An emulsion polymerization process for the production of fluoroelastomers is disclosed wherein at least one fluorosurfactant is employed as dispersant, said fluorosurfactant being a fluoroalkylphosphoric acid ester of the formula X—Rf—(CH2)n—O—P(O)(OM)2, wherein n=1 or 2, X═H or F, M=a univalent cation, and Rf is a C4-C6 fluoroalkyl or fluoroalkoxy group. Optionally, a second dispersing agent may be employed in the polymerization, said second agent being a perfluoropolyether having at least one endgroup selected from the group consisting of carboxylic acid, a salt thereof, sulfonic acid and a salt thereof, phosphoric acid and a salt thereof.
摘要翻译：公开了用于生产含氟弹性体的乳液聚合方法，其中使用至少一种含氟表面活性剂作为分散剂，所述含氟表面活性剂是式X-Rf-（CH2）nOP（O）（OM）2的氟代烷基磷酸酯，其中n = 1或2，XH或F，M =单价阳离子，Rf为C4-C6氟烷基或氟代烷氧基。任选地，在聚合中可以使用第二分散剂，所述第二试剂是具有至少一个选自羧酸，其盐，磺酸及其盐的端基的全氟聚醚，磷酸及其盐。

7. 发明申请

US20090186969A1 PROCESS FOR PRODUCING FLUOROPOLYMERS 有权
标题翻译：生产氟聚合物的方法
公开(公告)号：US20090186969A1
公开(公告)日：2009-07-23
申请号：US12354218
申请日：2009-01-15
申请人： Michael Cregg Coughlin , Ming-Hong Hung
发明人： Michael Cregg Coughlin , Ming-Hong Hung
IPC分类号： C08K5/51
CPC分类号： C08F14/18 , C07F9/091 , C08F2/26 , C08F2/20
摘要： An emulsion polymerization process for the production of non-elastomeric fluoropolymers is disclosed wherein at least one fluorosurfactant is employed as dispersant, said fluorosurfactant being a fluoroalkylphosphoric acid ester of the formula X-Rf-(CH2)n—O—P(O)(OM)2, wherein n is 1 or 2, X═H or F, M=a univalent cation, and Rf is a C4-C6 fluoroalkyl or fluoroalkoxy group. Optionally, a second dispersing agent may be employed in the polymerization, said second agent being a perfluoropolyether having at least one endgroup selected from the group consisting of carboxylic acid, a salt thereof, sulfonic acid and a salt thereof, phosphoric acid and a salt thereof.
摘要翻译：公开了用于制备非弹性体含氟聚合物的乳液聚合方法，其中使用至少一种含氟表面活性剂作为分散剂，所述含氟表面活性剂是式X-Rf-（CH2）nOP（O）（OM）2的氟代烷基磷酸酯，其中n为1或2，XH或F，M =单价阳离子，Rf为C4-C6氟代烷基或氟代烷氧基。任选地，在聚合中可以使用第二分散剂，所述第二试剂是具有至少一个选自羧酸，其盐，磺酸及其盐的端基的全氟聚醚，磷酸及其盐。

8. 发明申请

US20090124754A1 PROCESS FOR PRODUCING FLUOROPOLYMERS 失效
标题翻译：生产氟聚合物的方法
公开(公告)号：US20090124754A1
公开(公告)日：2009-05-14
申请号：US12255082
申请日：2008-10-21
申请人： Michael Cregg Coughlin , Ming-Hong Hung , Phan Linh Tang
发明人： Michael Cregg Coughlin , Ming-Hong Hung , Phan Linh Tang
IPC分类号： C08F16/24 , C08K5/36
CPC分类号： C08F14/18 , C08F214/26 , C08F2/26 , C08F2/22
摘要： An emulsion polymerization process for the production of fluoropolymers is disclosed wherein a combination of at least two fluorosurfactants is employed as dispersants. At least one fluorosurfactant is a perfluoroalkyl or perfluoroalkoxy sulfinate. At least one other fluorosurfactant is a perfluoropolyether having at least one endgroup selected from the group consisting of carboxylic acid, a slat thereof, sulfonic acid and a salt thereof.
摘要翻译：公开了用于生产含氟聚合物的乳液聚合方法，其中使用至少两种含氟表面活性剂的组合作为分散剂。至少一种含氟表面活性剂是全氟烷基或全氟烷氧基亚磺酸酯。至少一种其它含氟表面活性剂是具有至少一个选自羧酸，其盐，磺酸及其盐的端基的全氟聚醚。

9. 发明申请

US20110257423A1 PROCESS FOR PRODUCING FLUOROELASTOMERS 审中-公开
标题翻译：生产荧光体的方法
公开(公告)号：US20110257423A1
公开(公告)日：2011-10-20
申请号：US13169329
申请日：2011-06-27
申请人： Michael Cregg Coughlin , Ming-Hong Hung , Phan Linh Tang
发明人： Michael Cregg Coughlin , Ming-Hong Hung , Phan Linh Tang
IPC分类号： C07F9/09
CPC分类号： C08F14/18 , C07F9/091 , C08F2/26 , C08F2/20
摘要： An emulsion polymerization process for the production of fluoroelastomers is disclosed wherein at least one fluorosurfactant is employed as dispersant, said fluorosurfactant being a fluoroalkylphosphoric acid ester of the formula X—Rf—(CH2)n—O—P(O)(OM)2, wherein n=1 or 2, X=H or F, M=a univalent cation, and Rf is a C4-C6 fluoroalkyl or fluoroalkoxy group. Optionally, a second dispersing agent may be employed in the polymerization, said second agent being a perfluoropolyether having at least one endgroup selected from the group consisting of carboxylic acid, a salt thereof, sulfonic acid and a salt thereof, phosphoric acid and a salt thereof.
摘要翻译：公开了用于生产含氟弹性体的乳液聚合方法，其中使用至少一种含氟表面活性剂作为分散剂，所述含氟表面活性剂是式X-Rf-（CH2）n-O-P（O）（OM）2的氟代烷基磷酸酯其中n = 1或2，X = H或F，M =一价阳离子，Rf为C4-C6氟代烷基或氟代烷氧基。任选地，在聚合中可以使用第二分散剂，所述第二试剂是具有至少一个选自羧酸，其盐，磺酸及其盐的端基的全氟聚醚，磷酸及其盐。

10. 发明申请

US20090124755A1 PROCESS FOR PRODUCING FLUOROPOLYMERS 审中-公开
标题翻译：生产氟聚合物的方法
公开(公告)号：US20090124755A1
公开(公告)日：2009-05-14
申请号：US12255142
申请日：2008-10-21
申请人： Michael Cregg Coughlin , Ming-Hong Hung , Phan Linh Tang
发明人： Michael Cregg Coughlin , Ming-Hong Hung , Phan Linh Tang
IPC分类号： C08K5/42
CPC分类号： C08F14/26 , C08F214/262 , C08F2/22 , C08F2/26
摘要： An emulsion polymerization process for the production of fluoropolymers that contain polymerized units of tetrafluoroethylene is disclosed wherein a perfluoroaliphatic sulfinate is employed as dispersant.
摘要翻译：公开了一种用于制备含有四氟乙烯聚合单元的含氟聚合物的乳液聚合方法，其中使用全氟脂族亚磺酸酯作为分散剂。

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