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1. 发明授权

US06858693B2 Carbamate-functional resins having improved adhesion, method of making the same, and method of improving intercoat adhesion 有权
标题翻译：具有改进粘合性的氨基甲酸酯官能树脂，其制备方法以及改进层间粘附性的方法
公开(公告)号：US06858693B2
公开(公告)日：2005-02-22
申请号：US10602852
申请日：2003-06-24
申请人： Donald H. Campbell , Walter H. Ohrbom , Joseph Borst , Michael A. Gessner , Donald L. St. Aubin , Marvin L. Green , Bruce E. Oermann
发明人： Donald H. Campbell , Walter H. Ohrbom , Joseph Borst , Michael A. Gessner , Donald L. St. Aubin , Marvin L. Green , Bruce E. Oermann
IPC分类号： C09D5/00 , C08F8/00 , C08F8/30 , C08F220/00 , C08G18/38 , C08G18/81 , C09D133/00 , C09D157/06 , C09D183/04 , C09D201/02 , C09J5/00 , C08F126/02
CPC分类号： C08G18/8116 , C08F8/00 , C08F2800/20 , C08F2810/50 , C08G18/3823 , C09D201/025 , Y10T428/31551 , Y10T428/31573 , Y10T428/31645 , C08F2220/325 , C08F220/34 , C08F220/20 , C08F212/08
摘要： The invention provides carbamate-functional resins and coating compositions incorporating said resins that have improved adhesion with respect to subsequently applied films or coatings. More particularly, the invention relates to carbamate-functional addition polymers having at least 250 grams of polymer per carbamate group which are made with less than 35 percent by weight of nonfunctional monomers, preferably with less than 20 percent by weight and most preferably from 0 to less than 10 percent by weight, based on the total weight of the polymer. The invention further provides a method of making a carbamate-functional polymer and carbamate-functional polymers made by the claimed method. Finally, the invention provides a method for improving the adhesion of a first coating composition to a subsequently applied material as well as a method of making a composite comprising a coated substrate, an adhesive composition, and a glass having at least one surface.
摘要翻译：本发明提供氨基甲酸酯官能树脂和包含所述树脂的涂料组合物，其相对于随后施加的膜或涂层具有改善的粘合性。更具体地说，本发明涉及具有每个氨基甲酸酯基团至少250克聚合物的氨基甲酸酯官能加成聚合物，它们以小于35重量％的非官能单体，优选小于20重量％，最优选0至小于10重量％，基于聚合物的总重量。本发明还提供一种制备通过所要求保护的方法制备的氨基甲酸酯官能聚合物和氨基甲酸酯官能聚合物的方法。最后，本发明提供了一种用于改善第一涂料组合物与随后施加的材料的粘附性的方法，以及制备包含涂覆的基材，粘合剂组合物和具有至少一个表面的玻璃的复合材料的方法。

2. 发明授权

US06855789B2 Carbamate-functional resins having improved adhesion, method of making the same, and method of improving intercoat adhesion 有权
公开(公告)号：US06855789B2
公开(公告)日：2005-02-15
申请号：US10348484
申请日：2003-03-25
申请人： Donald H. Campbell , Walter H. Ohrbom , Joseph Borst , Michael A. Gessner , Donald L. St. Aubin , Marvin L. Green , Bruce E. Oermann
发明人： Donald H. Campbell , Walter H. Ohrbom , Joseph Borst , Michael A. Gessner , Donald L. St. Aubin , Marvin L. Green , Bruce E. Oermann
IPC分类号： C09D5/00 , C08F8/00 , C08F8/30 , C08F220/00 , C08G18/38 , C08G18/81 , C09D133/00 , C09D157/06 , C09D183/04 , C09D201/02 , C09J5/00 , C08F126/02
CPC分类号： C08G18/8116 , C08F8/00 , C08F2800/20 , C08F2810/50 , C08G18/3823 , C09D201/025 , Y10T428/31551 , Y10T428/31573 , Y10T428/31645 , C08F2220/325 , C08F220/34 , C08F220/20 , C08F212/08
摘要： The invention provides carbamate-functional resins and coating compositions incorporating said resins that have improved adhesion with respect to subsequently applied films or coatings. More particularly, the invention relates to carbamate-functional addition polymers having at least 250 grams of polymer per carbamate group which are made with less than 35 percent by weight of nonfunctional monomers, preferably with less than 20 percent by weight and most preferably from 0 to less than 10 percent by weight, based on the total weight of the polymer. The invention further provides a method of making a carbamate-functional polymer and carbamate-functional polymers made by the claimed method. Finally, the invention provides a method for improving the adhesion of a first coating composition to a subsequently applied material as well as a method of making a composite comprising a coated substrate, an adhesive composition, and a glass having at least one surface.

3. 发明授权

US06696159B2 Carbamate-functional resins having improved adhesion, method of making the same, and method of improving intercoat adhesion 有权
公开(公告)号：US06696159B2
公开(公告)日：2004-02-24
申请号：US10348491
申请日：2003-01-21
申请人： Donald H. Campbell , Walter H. Ohrbom , Joseph Borst , Michael A. Gessner , Donald L. St. Aubin , Marvin L. Green , Bruce Oermann
发明人： Donald H. Campbell , Walter H. Ohrbom , Joseph Borst , Michael A. Gessner , Donald L. St. Aubin , Marvin L. Green , Bruce Oermann
IPC分类号： B32B2700
CPC分类号： C08G18/8116 , C08F8/00 , C08F2800/20 , C08F2810/50 , C08G18/3823 , C09D201/025 , Y10T428/31551 , Y10T428/31573 , Y10T428/31645 , C08F2220/325 , C08F220/34 , C08F220/20 , C08F212/08
摘要： The invention provides carbamate-functional resins and coating compositions incorporating said resins that have improved adhesion with respect to subsequently applied films or coatings. More particularly, the invention relates to carbamate-functional addition polymers having at least 250 grams of polymer per carbamate group which are made with less than 35 percent by weight of nonfunctional monomers, preferably with less than 20 percent by weight and most preferably from 0 to less than 10 percent by weight, based on the total weight of the polymer. The invention further provides a method of making a carbamate-functional polymer and carbamate-functional polymers made by the claimed method. Finally, the invention provides a method for improving the adhesion of a first coating composition to a subsequently applied material as well as a method of making a composite comprising a coated substrate, an adhesive composition, and a glass having at least one surface.

4. 发明授权

US06437036B1 Waterborne primer with improved chip resistance 失效
标题翻译：水性底漆具有改善的芯片电阻
公开(公告)号：US06437036B1
公开(公告)日：2002-08-20
申请号：US09441810
申请日：1999-11-17
申请人： Michael A. Gessner , Timothy P. Kandow
发明人： Michael A. Gessner , Timothy P. Kandow
IPC分类号： C08J305
CPC分类号： C09D175/04 , C08G18/0819 , C08L75/04 , C09D133/06 , Y10T428/31551 , Y10T428/31605 , C08L2666/14
摘要： The invention provides a thermosetting aqueous primer composition that includes a polyurethane polymer, an acrylic polymer, and a crosslinking component that is reactive with at least one of the polyurethane polymer and the acrylic polymer. The polyurethane polymer has a glass transition temperature of 0° C. or less. The acrylic polymer has a glass transition temperature that is at least about 20° C. higher than the glass transition temperature of polyurethane resin. The invention further provides a composite coating having as a primer layer a cured layer of the primer composition of the invention and having at least one topcoat layer.
摘要翻译：本发明提供一种热固性水性底漆组合物，其包含聚氨酯聚合物，丙烯酸聚合物和与至少一种聚氨酯聚合物和丙烯酸聚合物反应的交联组分。聚氨酯聚合物的玻璃化转变温度为0℃以下。丙烯酸类聚合物的玻璃化转变温度比聚氨酯树脂的玻璃化转变温度高至少约20℃。本发明还提供一种复合涂层，其具有底漆层本发明的底漆组合物的固化层并具有至少一个外涂层。

5. 发明授权

US06360974B1 Powder slurry coating composition 有权
标题翻译：粉末浆料涂料组合物
公开(公告)号：US06360974B1
公开(公告)日：2002-03-26
申请号：US09314404
申请日：1999-05-19
申请人： Lawrence Sacharski , Michael A. Gessner
发明人： Lawrence Sacharski , Michael A. Gessner
IPC分类号： B02C1912
CPC分类号： C09D5/02
摘要： A powder slurry coating composition is prepared by adding individual particulate materials including at least one resin powder to an aqueous medium and then milling the dispersed particulate materials to produce a median particle size of up to about 15 microns. The powder slurry coating composition is used to prepare a coating on a substrate. The coating is equivalent to coatings obtained from powder slurry coating compositions in which the powder is produced by melt mixing in an extruder and grinding the extrudate.
摘要翻译：通过将包含至少一种树脂粉末的各种颗粒材料加入到水性介质中，然后研磨分散的颗粒材料以产生高达约15微米的中值粒度来制备粉末浆料涂料组合物。粉末浆料涂料组合物用于在基材上制备涂层。涂层相当于从粉末浆料涂料组合物获得的涂料，其中通过在挤出机中熔融混合并研磨挤出物来制备粉末。

6. 发明授权

US06187376B1 Method for improving the adhesion of a repair coating to a previously coated substrate 失效
标题翻译：用于改善修复涂层与预先涂覆的基底的粘附性的方法
公开(公告)号：US06187376B1
公开(公告)日：2001-02-13
申请号：US09165147
申请日：1998-10-01
申请人： Donald H. Campbell , Michael A. Gessner
发明人： Donald H. Campbell , Michael A. Gessner
IPC分类号： B05D714
CPC分类号： C09D201/025 , B05D5/005 , C08K5/57 , C09D7/63 , C08L2666/16
摘要： The invention provides a method for improving the adhesion of a repair coating to a coated substrate. It requires that at least one coating composition be applied to a substrate, the coating composition having (a) a film forming component with (i) a crosslinking component comprising one or more aminoplast resins, and (ii) one or more polymers having one or more functional groups which are reactive with the crosslinking component, (b) an adhesion improving additive comprising one or more compounds containing Sn(IV), (c) a catalyst for promoting a reaction between crosslinking agent (i) and one or more polymers (ii). The at least one coating composition is cured to provide a coated substrate and one or more repair coatings are applied to the coated substrate. In a preferred aspect of the invention, the one or more repair coatings applied are the same as the at least one coating composition. In a preferred aspect of the invention the at least one coating composition of the invention further comprises (d) an adhesion promoting component consisting of (i) an epoxy group containing component, and (ii) a monofunctional carboxy group component.
摘要翻译：本发明提供了一种用于改善修复涂层与涂覆的基底的粘附性的方法。要求将至少一种涂料组合物施用于基材上，涂料组合物具有（a）成膜组分，（i）包含一种或多种氨基塑料树脂的交联组分，和（ii）一种或多种聚合物，其具有一个或多个与交联组分反应的更多官能团，（b）包含一种或多种含有Sn（IV）的化合物的粘合改进添加剂，（c）促进交联剂（i）与一种或多种聚合物之间的反应的催化剂 ii）。将至少一种涂料组合物固化以提供涂覆的基底，并且将一个或多个修复涂层施加到涂覆的基底上。在本发明的优选方面，所施用的一种或多种修复涂层与至少一种涂料组合物相同。在本发明的优选方面，本发明的至少一种涂料组合物还包含（d）由（i）含环氧基的组分和（ii）单官能羧基组分组成的粘合促进组分。

7. 发明授权

US07419703B2 Thermally curable, thixotropic blends containing carbamate and/or allophanate groups 失效
标题翻译：含有氨基甲酸酯和/或脲基甲酸酯基团的可热固化的触变性共混物
公开(公告)号：US07419703B2
公开(公告)日：2008-09-02
申请号：US11213209
申请日：2005-08-26
申请人： Hubert Baumgart , Michael A Gessner , Bruce Oermann , Paul J Harris
发明人： Hubert Baumgart , Michael A Gessner , Bruce Oermann , Paul J Harris
IPC分类号： C08K5/21 , B05D3/02
CPC分类号： C09K3/10 , C08G71/00 , C09D5/04 , C09D201/025 , Y10S525/903
摘要： The invention provides heat-curable thixotropic mixtures containing carbamate and/or allophanate groups, including at least one oligomer and/or polymer containing at least one of carbamate and allophanate groups, and at least one thixotropic agent that is a urea derivative preparable by reacting at least one amine and/or water with at least one isocyanate in the presence of at least one amino resin. The invention further provides processes for preparing the mixtures and coating materials, adhesives and sealing compounds prepared from the mixtures.
摘要翻译：本发明提供含有氨基甲酸酯和/或脲基甲酸酯基团的热固化触变性混合物，包括至少一种含有氨基甲酸酯和脲基甲酸酯基团中的至少一种的低聚物和/或聚合物，以及至少一种触变剂，其是可通过在至少一种胺和/或水与至少一种异氰酸酯在至少一种氨基树脂的存在下进行。本发明还提供了由混合物制备混合物和涂料，粘合剂和密封化合物的方法。

8. 发明授权

US06531560B1 Carbamate-functional resins having improved adhesion, method of making the same, and method of improving intercoat adhesion 有权
公开(公告)号：US06531560B1
公开(公告)日：2003-03-11
申请号：US09677063
申请日：2000-09-29
申请人： Donald H. Campbell , Walter H. Ohrbom , Joseph Borst , Michael A. Gessner , Donald L. St. Aubin , Marvin L. Green , Bruce E. Oermann
发明人： Donald H. Campbell , Walter H. Ohrbom , Joseph Borst , Michael A. Gessner , Donald L. St. Aubin , Marvin L. Green , Bruce E. Oermann
IPC分类号： C08F12602
CPC分类号： C08G18/8116 , C08F8/00 , C08F2800/20 , C08F2810/50 , C08G18/3823 , C09D201/025 , Y10T428/31551 , Y10T428/31573 , Y10T428/31645 , C08F2220/325 , C08F220/34 , C08F220/20 , C08F212/08
摘要： The invention provides carbamate-functional resins and coating compositions incorporating said resins that have improved adhesion with respect to subsequently applied films or coatings. More particularly, the invention relates to carbamate-functional addition polymers having at least 250 grams of polymer per carbamate group which are made with less than 35 percent by weight of nonfunctional monomers, preferably with less than 20 percent by weight and most preferably from 0 to less than 10 percent by weight, based on the total weight of the polymer. The invention further provides a method of making a carbamate-functional polymer and carbamate-functional polymers made by the claimed method. Finally, the invention provides a method for improving the adhesion of a first coating composition to a subsequently applied material as well as a method of making a composite comprising a coated substrate, an adhesive composition, and a glass having at least one surface.

9. 发明授权

US06696535B2 Carbamate-functional resins having improved adhesion, method of making the same, and method of improving intercoat adhesion 有权
标题翻译：具有改进粘合性的氨基甲酸酯官能树脂，其制备方法以及改进层间粘附性的方法
公开(公告)号：US06696535B2
公开(公告)日：2004-02-24
申请号：US10348492
申请日：2003-01-21
申请人： Donald H. Campbell , Walter H. Ohrbom , Joseph Borst , Michael A. Gessner , Donald L. St. Aubin , Marvin L. Green , Bruce E. Oermann
发明人： Donald H. Campbell , Walter H. Ohrbom , Joseph Borst , Michael A. Gessner , Donald L. St. Aubin , Marvin L. Green , Bruce E. Oermann
IPC分类号： C08F12602
CPC分类号： C08G18/8116 , C08F8/00 , C08F2800/20 , C08F2810/50 , C08G18/3823 , C09D201/025 , Y10T428/31551 , Y10T428/31573 , Y10T428/31645 , C08F2220/325 , C08F220/34 , C08F220/20 , C08F212/08
摘要： The invention provides carbamate-functional resins and coating compositions incorporating said resins that have improved adhesion with respect to subsequently applied films or coatings. More particularly, the invention relates to carbamate-functional addition polymers having at least 250 grams of polymer per carbamate group which are made with less than 35 percent by weight of nonfunctional monomers, preferably with less than 20 percent by weight and most preferably from 0 to less than 10 percent by weight, based on the total weight of the polymer. The invention further provides a method of making a carbamate-functional polymer and carbamate-functional polymers made by the claimed method. Finally, the invention provides a method for improving the adhesion of a first coating composition to a subsequently applied material as well as a method of making a composite comprising a coated substrate, an adhesive composition, and a glass having at least one surface.
摘要翻译：本发明提供氨基甲酸酯官能树脂和包含所述树脂的涂料组合物，其相对于随后施加的膜或涂层具有改善的粘合性。更具体地说，本发明涉及具有每个氨基甲酸酯基团至少250克聚合物的氨基甲酸酯官能加成聚合物，它们以小于35重量％的非官能单体，优选小于20重量％，最优选0至小于10重量％，基于聚合物的总重量。本发明还提供一种制备通过所要求保护的方法制备的氨基甲酸酯官能聚合物和氨基甲酸酯官能聚合物的方法。最后，本发明提供了一种用于改善第一涂料组合物与随后施加的材料的粘附性的方法，以及制备包含涂覆的基材，粘合剂组合物和具有至少一个表面的玻璃的复合材料的方法。

10. 发明授权

US5379947A Process for producing a powder coating composition 失效
标题翻译：粉末涂料组合物的制造方法
公开(公告)号：US5379947A
公开(公告)日：1995-01-10
申请号：US149425
申请日：1993-11-09
申请人： Charles F. Williams , Michael A. Gessner
发明人： Charles F. Williams , Michael A. Gessner
IPC分类号： C09D5/03 , C08G18/62 , C09D5/00 , B02C23/18
CPC分类号： C08G18/6229 , C08G2150/20
摘要： A process for producing a powder coating composition having powder particles wherein at least 50% of the particles are of a size between 3 and 5 microns and 100% of the particles are of a size .ltoreq.10 microns. The process includes the steps of preparing a powder coating extrudate, reducing the extrudate to flake, jet milling the powder coating to a powder wherein at least 50% of the particles are a particle size of between 3 and 5 microns and 100% of the particles are of a size less than or equal to 10 microns, and adding the powder to a mixture of water and surfactant. Dispersant and rheology control agents are then added to the mixture.
摘要翻译：一种制备具有粉末颗粒的粉末涂料组合物的方法，其中至少50％的颗粒的尺寸为3至5微米，而100％的颗粒的尺寸为10微米。该方法包括以下步骤：制备粉末涂料挤出物，将挤出物还原成薄片，将粉末涂料喷射研磨成粉末，其中至少50％的颗粒为3至5微米的粒度和100％的颗粒尺寸小于或等于10微米，并将粉末加入到水和表面活性剂的混合物中。然后将分散剂和流变控制剂加入混合物中。

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