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    • 5. 发明授权
    • Method for detecting source of error in an amperometric measuring cell
    • 用于检测电流测量单元中误差源的方法
    • US5611909A
    • 1997-03-18
    • US576457
    • 1995-12-21
    • Matthias Studer
    • Matthias Studer
    • G01N27/416G01N27/26
    • G01N27/4163
    • The invention is directed to a method for detecting error sources in an amperometric measuring cell 1 which includes at least a measuring electrode 2 and a counter electrode 3 within an electrolyte chamber 4 filled with an electrolyte solution 6. A permeable membrane 7 closes off the electrolyte chamber 4 with respect to the measuring sample. The method includes the steps of: providing a voltage source 10 outputting a voltage U to apply across the electrodes to generate a sensor current i(t) between the electrodes; starting with the voltage U across the electrodes at a reference voltage U.sub.0 with a reference current i.sub.0, increasing or decreasing the voltage U to a first voltage U.sub.1 during a first time span T.sub.1 ; shortly after the voltage U assumes the first voltage U.sub.1, measuring a first sensor current i.sub.1 and/or, toward the end of the first time span T.sub.1, measuring a second sensor current i.sub.2 ; and, comparing the sensor currents i.sub.1 and/or i.sub.2 to the reference current i.sub.0.
    • 本发明涉及一种用于检测电流测量单元1中的误差源的方法,该电流计测量单元1至少包括一个填充有电解液6的电解液室4内的测量电极2和对电极3.透过膜7封闭电解液 室4相对于测量样品。 该方法包括以下步骤:提供电压源10,输出电压U以跨电极施加以在电极之间产生传感器电流i(t); 从参考电流i0以参考电压U0跨越电极的电压U开始,在第一时间跨度T1期间增加或减小电压U到第一电压U1; 在电压U呈现第一电压U1之后不久,测量第一传感器电流i1和/或在第一时间跨度T1的结束时测量第二传感器电流i2; 并且将传感器电流i1和/或i2与参考电流i0进行比较。
    • 7. 发明授权
    • Process and device for measuring the concentrations of a plurality of gas components in a gas sample
    • 用于测量气体样品中多个气体组分的浓度的方法和装置
    • US06728643B2
    • 2004-04-27
    • US10170741
    • 2002-06-13
    • Michael HackenbergMatthias Studer
    • Michael HackenbergMatthias Studer
    • G01N3100
    • G01N33/0031G01N33/0006G01N35/00603
    • A process and device measures and checks concentration values of a plurality of gas components in a gas sample. The distortion of the measuring results by temperature and moisture effects, contamination as well as cross sensitivity and drift phenomena of the sensors of the gas-measuring device is a frequent problem in the measurement of gases by a gas-measuring device. It is possible with the process to recognize implausible measuring results as such on the gas-measuring device without design measures. This is achieved by the evaluation of data of suitably selected calibrating gases, from which a subvector space is constructed in the vector space of all possible measurement data (s1, s2, s3), represented as a plane (E), and a corresponding tolerance range is constructed. If the data (*) determined later during a measurement, are in the tolerance range, they are classified as plausible, and otherwise as implausible. The subvector space is constructed, e.g., such that the sum of the distances of the measurement points belonging to the calibrating gases from the subvector space is as small as possible.
    • 过程和装置测量和检查气体样品中多个气体组分的浓度值。 温度和湿度影响的测量结果的变形,气体测量装置的传感器的污染以及交叉灵敏度和漂移现象是通过气体测量装置测量气体的常见问题。 该方法可以在气体测量装置上识别不合理的测量结果,而无需设计措施。 这通过评估适当选择的校准气体的数据来实现,在所述校准气体的数据中,在所有可能的测量数据(s1,s2,s3)的矢量空间中构造子向量空间(s1,s2,s3),表示为平面(E) 范围构建。 如果在测量期间确定的数据(*)在容差范围内,则将它们分类为似是而非的。 子载波空间被构造成例如属于来自子载波空间的校准气体的测量点的距离之和尽可能小。