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1. 发明申请

US20050049140A1 Activated catalyst systems from substituted dialuminoxane complexes 有权
公开(公告)号：US20050049140A1
公开(公告)日：2005-03-03
申请号：US10650471
申请日：2003-08-28
申请人： Matthew Holtcamp
发明人： Matthew Holtcamp
IPC分类号： B01J31/00 , C08F4/602 , C08F4/622 , C08F4/64 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/16
CPC分类号： B01J31/0231 , B01J31/143 , B01J31/1616 , B01J31/1805 , B01J31/1815 , B01J31/2226 , B01J31/2243 , B01J31/2295 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C08F4/65908 , C08F4/65912 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08F210/16 , C08F4/65916 , C08F210/14 , C08F2500/03
摘要： A catalyst composition and method for preparing a supported catalyst system for olefin polymerization is provided. In one aspect, the catalyst composition includes a reaction product of a dialuminoxane and a halogen substituted aryl borane, wherein the reaction takes place on a support and at conditions sufficient to exchange one or more ligands on the dialuminoxane for one or more ligands on the halogen substituted aryl borane while on the support. In one embodiment, the method for preparing the supported catalyst system includes combining a dialuminoxane with a support to form a treated catalyst support, and combining a halogen substituted aryl borane with the treated catalyst support at conditions sufficient to exchange one or more ligands on the dialuminoxane for one or more ligands on the halogen substituted aryl borane while on the support to form a supported activator. The method further includes reacting one or more polymerization catalysts with the supported activator.

2. 发明申请

US20060293539A1 Oxidation of alkanes 失效
标题翻译：烷烃氧化
公开(公告)号：US20060293539A1
公开(公告)日：2006-12-28
申请号：US11431944
申请日：2006-05-10
申请人： Matthew Holtcamp , James Vartuli
发明人： Matthew Holtcamp , James Vartuli
IPC分类号： C07C51/16 , C07F15/00
CPC分类号： C07C5/48 , B01J23/002 , B01J27/0576 , B01J31/1805 , B01J31/181 , B01J35/0006 , B01J2231/70 , B01J2523/00 , B01J2531/828 , C07C45/33 , C07C51/215 , C07C2531/36 , Y02P20/52 , Y02P20/582 , C07C11/06 , C07C57/03 , C07C57/04 , C07C47/22 , B01J2523/55 , B01J2523/56 , B01J2523/64 , B01J2523/68 , B01J2523/828
摘要： Alkanes are oxidised to oxygenates such as carboxylic acids with molecular oxygen employing a two component catalyst system which uses a liganded heavy metal compound and a mixed metal oxide.
摘要翻译：使用双组分催化剂体系，使用配体重金属化合物和混合金属氧化物，将烷烃氧化成含氧化合物，例如具有分子氧的羧酸。

3. 发明申请

US20060079394A1 Trialkylaluminum treated supports 有权
标题翻译：三烷基铝处理的载体
公开(公告)号：US20060079394A1
公开(公告)日：2006-04-13
申请号：US11220164
申请日：2005-09-06
申请人： Matthew Holtcamp
发明人： Matthew Holtcamp
IPC分类号： B01J31/00
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65925 , C08F110/02 , C08F210/16 , Y10S526/943 , C08F4/02 , C08F4/65916 , C08F210/14 , C08F2500/03
摘要： This invention relates to a process to prepare a trialkylaluminum treated support comprising: 1) combining a support with first trialkylaluminum compound(s), where the alkyl groups have at least 2 carbon atoms; then 2) calcining the combination of the support and the trialkylaluminum compound(s); then 3) combining the calcined support with second trialkylaluminum compound(s), where the alkyl groups have at least 2 carbon atoms; where the first and second trialkylaluminum compound(s) may be the same or different. This invention further relates to catalyst systems comprising catalyst compounds and such supports, as well as processes to polymerize unsaturated monomers using the supports in combination with catalyst compounds.
摘要翻译：本发明涉及一种制备三烷基铝处理的载体的方法，包括：1）将载体与第一三烷基铝化合物组合，其中烷基具有至少2个碳原子; 然后2）煅烧载体与三烷基铝化合物的组合; 然后3）将煅烧的载体与第二个三烷基铝化合物组合，其中烷基具有至少2个碳原子; 其中第一和第二三烷基铝化合物可以相同或不同。本发明还涉及包含催化剂化合物和这种载体的催化剂体系，以及使用该载体与催化剂化合物组合使不饱和单体聚合的方法。

4. 发明申请

US20050165183A1 Methods of forming a supported activated catalyst composition 失效
标题翻译：形成负载型活化催化剂组合物的方法
公开(公告)号：US20050165183A1
公开(公告)日：2005-07-28
申请号：US11039533
申请日：2005-01-20
申请人： Laughlin McCullough , Matthew Holtcamp
发明人： Laughlin McCullough , Matthew Holtcamp
IPC分类号： C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/02 , C08F4/44
CPC分类号： B01J31/165 , B01J27/12 , B01J31/143 , B01J31/1616 , B01J31/2226 , B01J31/2295 , B01J35/002 , B01J2531/48 , C08F4/65912 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08F110/02 , Y10S526/943 , C08F4/65916
摘要： Processes of forming a supported activated catalyst composition and method of polymerization are disclosed, the process of forming the composition including combining a halogenated aromatic aluminum activator compound with a fluorinated support and a catalyst to form a supported activated catalyst composition. Also disclosed is a supported activated catalyst composition, comprising the reaction product of a fluorinated support, a perfluorophenyl aluminum activator and in one embodiment a metallocene catalyst. In one embodiment, the halogenated aromatic aluminum activator is represented by the formula RnAl(ArHal)3-n, wherein ArHal is a halogenated aryl group, R is a monoanionic ligand, and n is 1 or 2.
摘要翻译：公开了形成负载型活化催化剂组合物和聚合方法的方法，该方法包括将卤化芳族铝活化剂化合物与氟化载体和催化剂组合以形成负载型活化催化剂组合物。还公开了一种负载的活化催化剂组合物，其包含氟化载体，全氟苯基铝活化剂和在一个实施方案中为茂金属催化剂的反应产物。在一个实施方案中，卤化芳族铝活化剂由式R n Al（ArHal）3-n N表示，其中ArHal是卤代芳基，R是单阴离子配体，n为1或2。

5. 发明申请

US20050075242A1 Heterocyclic nitrogen-containing activators and catalyst systems for olefin polymerization 失效
标题翻译：用于烯烃聚合的杂环含氮活化剂和催化剂体系
公开(公告)号：US20050075242A1
公开(公告)日：2005-04-07
申请号：US10602543
申请日：2003-06-24
申请人： Matthew Holtcamp , David Cano
发明人： Matthew Holtcamp , David Cano
IPC分类号： B01J31/18 , B01J31/22 , C07F5/06 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/02 , C08F210/02 , C08F210/16 , B01J31/00 , C07F15/00
CPC分类号： C08F210/02 , B01J31/181 , B01J31/1825 , B01J31/2295 , B01J2531/31 , B01J2531/46 , C07F5/062 , C08F4/65916 , C08F4/6592 , C08F4/65922 , C08F10/00 , C08F110/02 , C08F210/16 , C08F4/12 , C08F4/65912 , C08F4/61908 , C08F4/76 , C08F2500/03 , C08F2500/01 , C08F210/14
摘要： An aluminum activator and catalyst system for olefin polymerization is provided. In one aspect, the catalyst system comprises a polymerization catalyst and an activator comprising two or more heterocyclic nitrogen-containing ligands coordinated to a Group 13 atom. Preferably, the activator is a reaction product of one or more Group 13 atom-containing compounds and one or more heterocyclic nitrogen-containing compounds.
摘要翻译：提供了一种用于烯烃聚合的铝活化剂和催化剂体系。一方面，催化剂体系包括聚合催化剂和包含与第13族原子配位的两个或多个杂环含氮配体的活化剂。优选地，活化剂是一种或多种含13族原子的化合物和一种或多种杂环含氮化合物的反应产物。

6. 发明申请

US20070112151A1 Catalyst system for olefin polymerization and polymers produced therefrom 有权
标题翻译：用于烯烃聚合的催化剂体系和由其制备的聚合物
公开(公告)号：US20070112151A1
公开(公告)日：2007-05-17
申请号：US11589499
申请日：2006-10-30
申请人： Matthew Holtcamp , Renuka Ganesh
发明人： Matthew Holtcamp , Renuka Ganesh
IPC分类号： C08F4/44
CPC分类号： C08F10/00 , C08F110/02 , C08F210/16 , C08F4/69 , C08F2500/04 , C08F210/14
摘要： This invention relates to a catalyst composition represented by the formula: where Z-O is a support material, where O is oxygen, preferably Z is Si, Ti, Al, Sn, Fe, Ga, Zr, B, Mg, or Cr; each X is, independently, N, O, P or S; each n is, independently, 1 or 2; each R is, independently, an alkyl group, a substituted alkyl group, an aryl group, or a substituted aryl group, provided at least one R group is an aryl or substituted aryl group. This invention also relates to the use of the above catalyst compound with an aluminum alkyl to polymerize olefins and other monomers.
摘要翻译：本发明涉及一种由下式表示的催化剂组合物：其中Z-O为载体材料，其中O为氧，优选Z为Si，Ti，Al，Sn，Fe，Ga，Zr，B，Mg或Cr; 每个X独立地是N，O，P或S; 每个n独立地为1或2; 每个R独立地是烷基，取代的烷基，芳基或取代的芳基，条件是至少一个R基团是芳基或取代的芳基。本发明还涉及上述催化剂化合物与烷基铝聚合烯烃和其它单体的用途。

7. 发明申请

US20050266982A1 Activated catalyst systems from substituted dialuminoxane complexes 审中-公开
公开(公告)号：US20050266982A1
公开(公告)日：2005-12-01
申请号：US11168103
申请日：2005-06-28
申请人： Matthew Holtcamp
发明人： Matthew Holtcamp
IPC分类号： B01J31/00 , C08F4/602 , C08F4/622 , C08F4/64 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/16
CPC分类号： B01J31/0231 , B01J31/143 , B01J31/1616 , B01J31/1805 , B01J31/1815 , B01J31/2226 , B01J31/2243 , B01J31/2295 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C08F4/65908 , C08F4/65912 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08F210/16 , C08F4/65916 , C08F210/14 , C08F2500/03
摘要： A catalyst composition and method for preparing a supported catalyst system for olefin polymerization is provided. In one aspect, the catalyst composition includes a reaction product of a dialuminoxane and a halogen substituted aryl borane, wherein the reaction takes place on a support and at conditions sufficient to exchange one or more ligands on the dialuminoxane for one or more ligands on the halogen substituted aryl borane while on the support. In one embodiment, the method for preparing the supported catalyst system includes combining a dialuminoxane with a support to form a treated catalyst support, and combining a halogen substituted aryl borane with the treated catalyst support at conditions sufficient to exchange one or more ligands on the dialuminoxane for one or more ligands on the halogen substituted aryl borane while on the support to form a supported activator. The method further includes reacting one or more polymerization catalysts with the supported activator.

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