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1. 发明授权

US07691940B2 Aqueous polyurethane resin and method for producing aqueous polyurethane resin and film 有权
标题翻译：水性聚氨酯树脂及水性聚氨酯树脂及膜的制造方法
公开(公告)号：US07691940B2
公开(公告)日：2010-04-06
申请号：US11792382
申请日：2005-12-08
申请人： Masahiro Isobe , Fumiaki Hirata
发明人： Masahiro Isobe , Fumiaki Hirata
IPC分类号： C08G18/10 , C08G18/08 , C08L75/04
CPC分类号： C08J5/18 , C08G18/0823 , C08G18/3228 , C08G18/40 , C08G18/66 , C08J2375/04
摘要： An object of the present invention is to provide an aqueous polyurethane resin in which stable emulsion is formed, the balance between hydrophilicity and hydrophobicity is controlled and an obtained film has desired permeability and good stability, a method for producing the aqueous polyurethane resin, and a film obtained from the aqueous polyurethane resin. The aqueous polyurethane resin of the present invention includes a plurality of polyurethane resins obtained by reacting macropolyol, polyisocyanate, and a chain extender, and each of the aqueous polyurethane resins contains the macropolyols which are different from one another, and each of the aqueous polyurethane resins is chemically bonded partially to one another through the chain extender. By casting or coating the aqueous polyurethane resin, the film is obtained.
摘要翻译：本发明的目的是提供一种其中形成稳定乳液的水性聚氨酯树脂，控制亲水性和疏水性之间的平衡，并且所得膜具有期望的渗透性和良好的稳定性，制备水性聚氨酯树脂的方法和从水性聚氨酯树脂获得的膜。本发明的水性聚氨酯树脂包括通过大分子多元醇，多异氰酸酯和扩链剂反应获得的多种聚氨酯树脂，并且每种水性聚氨酯树脂含有彼此不同的大多异氰酸酯，并且每种水性聚氨酯树脂通过扩链剂彼此部分化学键合。通过浇铸或涂布水性聚氨酯树脂，得到膜。

2. 发明授权

US4651839A Radiator supporting device 失效
标题翻译：散热器支撑装置
公开(公告)号：US4651839A
公开(公告)日：1987-03-24
申请号：US734237
申请日：1985-05-14
申请人： Masahiro Isobe
发明人： Masahiro Isobe
IPC分类号： F28F9/00 , B60K11/04 , F01P3/18 , F16F1/373 , B60G11/22 , F16F7/00 , F16M13/00
CPC分类号： F16F1/3732 , B60K11/04 , F28F2275/143
摘要： A radiator supporting device interposed between a lower end of a radiator and a bracket of a body of a vehicle, comprising an upper flange, a lower flange, a skirt portion and an intermediate portion. Between the upper and lower flanges is formed a gap for preventing interference of both flanges. The outside diameter of the upper flange is smaller than that of the lower flange, and the outside diameter of the skirt portion is smaller than that of the upper flange. By this construction, it is made possible to attain a uniform load applied to the radiator supporting device, ensuring a large deformation of the radiator supporting device and a sure bearing of load by the bracket of the body.
摘要翻译：一种插入在散热器的下端和车体的支架之间的散热器支撑装置，包括上凸缘，下凸缘，裙部和中间部分。在上凸缘和下凸缘之间形成有用于防止两凸缘的干涉的间隙。上凸缘的外径小于下凸缘的外径，裙部的外径小于上凸缘的外径。通过这种结构，可以获得施加到散热器支撑装置的均匀载荷，确保散热器支撑装置的大的变形和通过主体的支架的负载的确定的轴承。

3. 发明授权

US06410676B1 Method for producing polyoxyalkylene polyol and derivatives thereof 有权
标题翻译：聚氧化烯多元醇及其衍生物的制备方法
公开(公告)号：US06410676B1
公开(公告)日：2002-06-25
申请号：US09555338
申请日：2000-05-30
申请人： Satoshi Yamasaki , Yasunori Hara , Tamotsu Kunihiro , Fumio Yamazaki , Mikio Matsufuji , Ariko Nishikawa , Shinsuke Matsumoto , Tsukuru Izukawa , Masahiro Isobe , Kazuhiko Ohkubo , Kaoru Ueno
发明人： Satoshi Yamasaki , Yasunori Hara , Tamotsu Kunihiro , Fumio Yamazaki , Mikio Matsufuji , Ariko Nishikawa , Shinsuke Matsumoto , Tsukuru Izukawa , Masahiro Isobe , Kazuhiko Ohkubo , Kaoru Ueno
IPC分类号： C08G1848
CPC分类号： C08G18/48 , C08G65/2642 , C08G65/2675 , C08G65/30
摘要： The object is to provide a method for producing a polyoxyalkylene polyol and a method for producing a derivative thereof wherein the remaining catalyst compound is efficiently removed from a crude polyoxyalkylene polyol by a simple manner, and a method for producing a polyoxyalkylene polyol wherein a crude polyoxyalkylene polyol is produced by addition polymerization of an epoxide compound to an active hydrogen compound using as a catalyst a compound having a P═N bond, then, the crude polyoxyalkylene polyol is allowed to contact with a solid acid having a specific surface area of 450 to 1200 m2/g and an average pore diameter of 40 to 100 Å to control the catalyst-remaining amount in the polyoxyalkylene polyol to 150 ppm or less, and a method for producing a derivative of the-above-described polyol are provided.
摘要翻译：本发明的目的是提供一种聚氧化烯多元醇的制造方法及其衍生物的制造方法，其中通过简单的方法从粗聚氧化烯多元醇中有效地除去剩余的催化剂化合物，以及聚氧化烯多元醇的制备方法，其中粗聚氧化烯通过使用P = N键的化合物作为催化剂将环氧化合物加成活性氢化合物，然后使粗聚氧化烯多元醇与比表面积为450的固体酸接触，生成多元醇 1200m 2 / g，平均孔径为40〜100，将聚氧化烯多元醇中的催化剂残留量控制在150ppm以下，提供上述多元醇的衍生物的制造方法。

4. 发明授权

US06117937A Polymer polyol and flame retardant polyurethane resin and foam prepared therefrom 失效
标题翻译：聚合物多元醇和阻燃聚氨酯树脂及其制备的泡沫
公开(公告)号：US06117937A
公开(公告)日：2000-09-12
申请号：US28525
申请日：1998-02-24
申请人： Shinsuke Matsumoto , Ariko Nishikawa , Tsukuru Izukawa , Masahiro Isobe , Kazuhiko Okubo
发明人： Shinsuke Matsumoto , Ariko Nishikawa , Tsukuru Izukawa , Masahiro Isobe , Kazuhiko Okubo
IPC分类号： C08F220/56 , C08G18/40 , C08G18/63 , C08K5/05
CPC分类号： C08G18/4072 , C08F220/56 , C08G18/638 , C08G2101/0008 , C08G2101/005 , C08G2101/0083
摘要： A polymer dispersed polyol having a vinyl polymer dispersed in polyol, the vinyl polymer comprising containing 5 to 80 wt % of acrylamide compound (A) represented by the formula (1):CH.sub.2 .dbd.CR.sup.1 CONR.sup.2 R.sup.3 (1)wherein R.sup.1, R.sup.2 and R.sup.3 are a hydrogen atom or hydrocarbon group having 1 to 10 carbon atoms, 0 to 70 wt % of one or more monomer (B) selected from acrylonitrile and methacrylonitrile, and 0 to 95 wt % of a vinyl monomer (C) which can copolymerize with (A) and (B), and 95 to 20 wt % of the total amount of (B) and (C); and when (C) is 0 wt %, (A) is the polymer of a vinyl monomer mixture containing an acrylamide derivative represented by the formula (2):CH.sub.2 .dbd.CR.sup.4 CONR.sup.5 R.sup.6 (2)wherein R.sup.4, R.sup.5 and R.sup.6 are a hydrogen atom or hydrocarbon group having 1 to 10 carbon atoms, and not simultaneously the hydrogen atom; and said polyol comprising containing 5 to 50 wt % of the vinyl polymer, and flame retardant polyurethane resin and flame retardant polyurethane foam which are prepared from the same.
摘要翻译：一种聚合物分散的多元醇，其具有分散在多元醇中的乙烯基聚合物，所述乙烯基聚合物含有5-80重量％的由式（1）表示的丙烯酰胺化合物（A）：CH2 = CR1CONR2R3（1）其中R1，R2和R3是氢原子或碳原子数为1〜10的烃基，0〜70重量％的一种或多种选自丙烯腈和甲基丙烯腈的单体（B）和0〜95重量％的可与（A ）和（B），和（B）和（C）的总量的95〜20重量％。当（C）为0重量％时，（A）是含有由式（2）表示的丙烯酰胺衍生物的乙烯基单体混合物的聚合物：CH2 = CR4CONR5R6（2）其中R4，R5和R6是氢原子或具有1〜10个碳原子的烃基，而不是氢原子; 所述多元醇含有5〜50重量％的乙烯基聚合物，以及由其制备的阻燃聚氨酯树脂和阻燃聚氨酯泡沫。

5. 发明授权

US4618336A Belt stretching mechanism 失效
标题翻译：皮带拉伸机制
公开(公告)号：US4618336A
公开(公告)日：1986-10-21
申请号：US707234
申请日：1985-03-01
申请人： Masahiro Isobe , Sumio Okazaki , Hideki Tanaka
发明人： Masahiro Isobe , Sumio Okazaki , Hideki Tanaka
IPC分类号： F02B67/06 , F16H7/08 , F16H7/14
CPC分类号： F16H7/14 , F16H2007/0893
摘要： A belt stretching mechanism to adjust the tension in a belt wound around pulleys by turning an adjust bolt and moving a slider which is fastened together with a stay to an adjust bar by means of a stay-fastening bolt, wherein the axis of the adjust bolt and the axis of the stay-fastening bolt are in the same plane, so that no bending moment acts on the adjust bolt and smooth tensioning of V-belt is ensured.
摘要翻译：一种带拉伸机构，用于通过转动调节螺栓来调节缠绕在皮带轮周围的皮带中的张力，并且通过拉紧螺栓将滑块固定在一起，该拉头通过拉紧螺栓固定在调节杆上，其中调节螺栓的轴线并且拉杆紧固螺栓的轴线在同一平面内，使得没有弯矩作用在调节螺栓上，并且确保了V形带的平滑张紧。

6. 发明授权

US4571221A V-Belt stretching mechanism 失效
标题翻译： V带拉伸机构
公开(公告)号：US4571221A
公开(公告)日：1986-02-18
申请号：US683509
申请日：1984-12-19
申请人： Masahiro Isobe , Masashi Sugiura
发明人： Masahiro Isobe , Masashi Sugiura
IPC分类号： F16H7/14 , F16H7/08
CPC分类号： F16H7/14
摘要： A V-belt stretching mechanism to adjust the tension of the V-belt in an internal combustion engine wherein a spring plate has two arms with ends staggered in the longitudinal direction of an adjust bolt. A slide cam has hooks which engage with the arms. Engagement and disengagement of the cam with the arms of the spring plate makes it possible to automatically adjust the tension in the V-belt.
摘要翻译：一种用于调节内燃机中的V形带张力的V形带拉伸机构，其中弹簧板具有沿调节螺栓的纵向方向交错的两个臂。滑动凸轮具有与臂接合的钩。凸轮与弹簧板的臂的接合和脱离使得可以自动调节V形带中的张力。

7. 发明申请

US20100258762A1 AQUEOUS POLYURETHANE RESIN, HYDROPHILIC RESIN, AND FILM 有权
标题翻译：水性聚氨酯树脂，水解树脂和胶片
公开(公告)号：US20100258762A1
公开(公告)日：2010-10-14
申请号：US12746422
申请日：2008-12-04
申请人： Masahiro Isobe , Akihiro Imai , Atsuko Tachibana
发明人： Masahiro Isobe , Akihiro Imai , Atsuko Tachibana
IPC分类号： C09K3/00
CPC分类号： C08J5/18 , C08G18/0823 , C08G18/0866 , C08G18/12 , C08G18/283 , C08G18/3206 , C08G18/3271 , C08G18/3275 , C08G18/348 , C08G18/44 , C08G18/4833 , C08G18/4854 , C08G18/6692 , C08G18/711 , C08G18/73 , C08G18/757 , C08G18/758 , C08G18/8061 , C08J2375/08 , C08G18/6688 , C08G18/3234 , C08G18/6622 , C08G18/50 , C08G18/3893
摘要： An aqueous polyurethane resin is prepared by reaction of an isocyanate group-terminated prepolymer with a chain extender containing polyamine. The isocyanate group-terminated prepolymer is obtained by reaction of at least a polyisocyanate containing 50 wt % or more of a non-multiple ring polyisocyanate that does not contain an aromatic ring and an aliphatic ring, or contains one aromatic ring or aliphatic ring; polyoxyethylene polyol; and a polyoxyethylene side chain-containing active compound having two or more hydroxyl groups or isocyanate groups at its molecular terminal and having a polyoxyethylene group in the side chain.
摘要翻译：通过异氰酸酯基封端的预聚物与含有多胺的扩链剂的反应来制备水性聚氨酯树脂。异氰酸酯基封端的预聚物通过至少含有50重量％以上的不含芳香环和脂肪族环的非多元环多异氰酸酯或含有一个芳香环或脂肪族环的多异氰酸酯反应而得到; 聚氧乙烯多元醇和在其分子末端具有两个以上羟基或异氰酸酯基并在侧链具有聚氧乙烯基的聚氧乙烯侧链的活性化合物。

8. 发明申请

US20080045650A1 Aqueous Polyurethane Resin and Method For Producing Aqueous Polyurethane Resin and Film 有权
标题翻译：水性聚氨酯树脂及其生产水性聚氨酯树脂和薄膜的方法
公开(公告)号：US20080045650A1
公开(公告)日：2008-02-21
申请号：US11792382
申请日：2005-12-08
申请人： Masahiro Isobe , Fumiaki Hirata
发明人： Masahiro Isobe , Fumiaki Hirata
IPC分类号： C08G18/10 , C08G18/08 , C08L75/04
CPC分类号： C08J5/18 , C08G18/0823 , C08G18/3228 , C08G18/40 , C08G18/66 , C08J2375/04
摘要： An object of the present invention is to provide an aqueous polyurethane resin in which stable emulsion is formed, the balance between hydrophilicity and hydrophobicity is controlled and an obtained film has desired permeability and good stability, a method for producing the aqueous polyurethane resin, and a film obtained from the aqueous polyurethane resin. The aqueous polyurethane resin of the present invention includes a plurality of polyurethane resins obtained by reacting macropolyol, polyisocyanate, and a chain extender, and each of the aqueous polyurethane resins contains the macropolyols which are different from one another, and each of the aqueous polyurethane resins is chemically bonded partially to one another through the chain extender. By casting or coating the aqueous polyurethane resin, the film is obtained.
摘要翻译：本发明的目的是提供一种其中形成稳定乳液的水性聚氨酯树脂，控制亲水性和疏水性之间的平衡，并且所得膜具有期望的渗透性和良好的稳定性，制备水性聚氨酯树脂的方法和从水性聚氨酯树脂获得的膜。本发明的水性聚氨酯树脂包括通过大分子多元醇，多异氰酸酯和扩链剂反应获得的多种聚氨酯树脂，并且每种水性聚氨酯树脂含有彼此不同的大多异氰酸酯，并且每种水性聚氨酯树脂通过扩链剂彼此部分化学键合。通过浇铸或涂布水性聚氨酯树脂，得到膜。

9. 发明授权

US06433033B1 High-durability flexible polyurethane cold cure molded foam and process for producing the same 有权
标题翻译：高耐久性柔性聚氨酯冷固化模塑泡沫及其生产方法
公开(公告)号：US06433033B1
公开(公告)日：2002-08-13
申请号：US09502088
申请日：2000-02-10
申请人： Masahiro Isobe , Kazuhiko Ohkubo , Seijiro Sakai
发明人： Masahiro Isobe , Kazuhiko Ohkubo , Seijiro Sakai
IPC分类号： C08G1810
CPC分类号： C08G18/4866 , C08G18/4072 , C08G18/632 , C08G2101/0008 , C08G2101/005
摘要： The high-durability flexible polyurethane cold cure molded foam of the invention has an overall density of not less than 35 kg/m3 and not more than 45 kg/m3 and a wet heat compression set of not more than 15%, and preferably has a hardness change ratio, as determined in a repeated compression test, of not more than 15%. This foam can be obtained by the process of the invention. The process of the invention is a process for producing a flexible polyurethane cold cure molded foam obtained from a polyol and/or a polymer polyol containing dispersed polymer microparticles obtained by radical polymerizing a compound having an unsaturated bond in the polyol, water, a catalyst and a polyisocyanate, wherein the polyol is a polyol synthesized by the use of a catalyst containing at least one compound selected from the group consisting of a compound having a nitrogen-phosphorus double bond, cesium hydroxide and rubidium hydroxide. The foam of the invention has a low density and is excellent in durability, particularly in hardness change ratio in a repeated compression test and wet heat compression set. According to the process of the invention, such a foam can be obtained.
摘要翻译：本发明的高耐久性柔性聚氨酯冷固化模塑泡沫体的总密度不低于35kg / m 3且不大于45kg / m 3，湿热压缩永久变形不大于15％，优选具有在重复压缩试验中确定的硬度变化率不大于15％。该泡沫可通过本发明的方法获得。本发明的方法是一种制备由多元醇得到的软质聚氨酯冷固化模塑泡沫体的方法和/或包含通过在多元醇，水，催化剂中自由基聚合具有不饱和键而获得的分散的聚合物微粒的聚合物多元醇，多异氰酸酯，其中所述多元醇是通过使用含有至少一种选自具有氮 - 磷双键的化合物，氢氧化铯和氢氧化铷的化合物的催化剂合成的多元醇。本发明的泡沫体的密度低，耐久性优异，特别是在重复压缩试验和湿热压缩成形中的硬度变化率方面。根据本发明的方法，可以获得这样的泡沫。

10. 发明授权

US6063825A Flexible polyurethane foam with high durability 有权
标题翻译：柔性聚氨酯泡沫具有高耐久性
公开(公告)号：US6063825A
公开(公告)日：2000-05-16
申请号：US136307
申请日：1998-08-19
申请人： Masahiro Isobe , Kazuhiko Ohkubo , Seijiro Sakai , Usaji Takaki , Tadahito Nobori , Tsukuru Izukawa , Satoshi Yamasaki
发明人： Masahiro Isobe , Kazuhiko Ohkubo , Seijiro Sakai , Usaji Takaki , Tadahito Nobori , Tsukuru Izukawa , Satoshi Yamasaki
IPC分类号： C08G18/40 , C08G18/63 , C08G18/66 , C08G65/26 , C08L71/02 , C08J9/00 , C08F8/30 , C08G18/00 , C08K3/20 , C08L75/00
CPC分类号： C08G65/2672 , C08G18/4072 , C08G18/632 , C08G18/667 , C08L71/02 , C08G2101/0008 , C08G2101/0058 , C08G2101/0083
摘要： A flexible polyurethane foam prepared by reacting polyisocyanate with polyol and/or polymer polyol containing dispersed polymer microparticles obtained by polymerizing an unsaturated compound, water, catalyst, surfactant and, when needed, crosslinking agent and other auxiliary agents, wherein a portion or the whole of the polyol and/or the polymer polyol is prepared in the presence of a compound having a nitrogen-phosphorus double bond as a catalyst, have excellent wet compression set, fatigue by constant-load pounding and dynamic durability.
摘要翻译：一种柔性聚氨酯泡沫，其通过使多异氰酸酯与多元醇和/或聚合物多元醇反应制备，所述多元醇和/或聚合物多元醇含有通过聚合不饱和化合物，水，催化剂，表面活性剂和（如果需要的话）交联剂和其它助剂而获得的分散的聚合物微粒，在具有氮磷双键作为催化剂的化合物的存在下制备多元醇和/或聚合物多元醇，具有优异的湿压缩永久变形，通过恒定负荷冲击的疲劳和动态耐久性。

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