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1. 发明授权

US5759963A Use of acetals 失效
标题翻译：使用缩醛
公开(公告)号：US5759963A
公开(公告)日：1998-06-02
申请号：US116483
申请日：1993-09-03
申请人： Martin Hille , Heinz Wittkus , Bernd Windhausen , Hans Jurgen Scholz , Frank Weinelt
发明人： Martin Hille , Heinz Wittkus , Bernd Windhausen , Hans Jurgen Scholz , Frank Weinelt
IPC分类号： C04B40/00 , C09K8/26 , C09K8/34 , C09K8/36 , C09K8/54 , C10M105/18 , C10M105/20 , C10M129/16 , C10M129/24 , C10N30/00 , C10N40/00 , C10N40/04 , C10N40/08 , C10N40/20 , C10N40/25 , C10N40/30 , C09K7/02
CPC分类号： C09K8/26 , C09K8/34 , C10M105/18 , C10M105/20 , C10M129/16 , C10M129/24 , C10M2207/04 , C10N2240/06 , C10N2240/08 , C10N2240/10 , C10N2240/101 , C10N2240/102 , C10N2240/103 , C10N2240/104 , C10N2240/106 , C10N2240/40 , C10N2240/401 , Y10S507/905
摘要： Acetals are used as a mineral oil substitute, oil component or base oil in invert-emulsion drilling muds, emulsion drilling muds, engine oils, gearbox oils, lubricating oils and also metal-working fluids, coolants, cooling lubricants and hydraulic fluids. As compared with conventional mineral oils, acetals show good biodegradability and are less toxic.
摘要翻译：缩醛用作反相乳液钻井泥浆，乳液钻井泥浆，发动机油，变速箱油，润滑油以及金属加工液，冷却剂，冷却润滑剂和液压油中的矿物油替代物，油组分或基础油。与常规矿物油相比，缩醛显示出良好的生物降解性，毒性较小。

2. 发明授权

US4357245A Water-soluble copolymer and its preparation 失效
标题翻译：水溶性共聚物及其制备方法
公开(公告)号：US4357245A
公开(公告)日：1982-11-02
申请号：US297237
申请日：1981-08-28
申请人： Friedrich Engelhardt , Ulrich Riegel , Martin Hille , Heinz Wittkus
发明人： Friedrich Engelhardt , Ulrich Riegel , Martin Hille , Heinz Wittkus
IPC分类号： C09K8/02 , C08F20/00 , C08F20/52 , C08F26/00 , C08F220/56 , C08F220/58 , C08F226/02 , C08F228/02 , C09K8/03 , C09K8/04 , C09K8/24 , C09K7/02
CPC分类号： C08F220/58 , C09K8/24
摘要： Outstandingly suitable drilling mud additives are water soluble copolymers consisting essentially of a random distribution of(a) 5 to 95% by weight of units of the formula ##STR1## (b) 5 to 95% by weight of units of the formula ##STR2## and (c) 0 to 80% by weight of units of the formula ##STR3## wherein R.sup.1 and R.sup.2 are the same or different and each is hydrogen methyl or ethyl; andX.sup..sym. is a cation.
摘要翻译：非常合适的钻井泥浆添加剂是水溶性共聚物，其基本上由以下组成的随机分布组成：（a）5至95重量％的式（b）单元：（b）5-95重量％和（c）0至80重量％的式“IMAGE”的单元，其中R 1和R 2相同或不同，各自为氢甲基或乙基; 而X（+）是阳离子。

3. 发明授权

US4341716A Polyether polyamines, the salts thereof, process for their manufacture and their use 失效
标题翻译：聚醚多胺及其盐的制备方法及其用途
公开(公告)号：US4341716A
公开(公告)日：1982-07-27
申请号：US189671
申请日：1980-09-22
申请人： Helmut Diery , Wolfgang Wagemann , Joachim Weide , Reinhold Deubel , Martin Hille
发明人： Helmut Diery , Wolfgang Wagemann , Joachim Weide , Reinhold Deubel , Martin Hille
IPC分类号： C08G65/26 , C09B67/46 , C23F11/14 , D06P1/607 , C07C93/04 , C07C89/02 , C07C91/10 , C07C91/12 , C07C143/68 , C07F9/09
CPC分类号： C23F11/142 , C08G65/2624 , C09B67/0089 , D06P1/6076 , Y10S516/07
摘要： Polyether polyamines of the formula 1 ##STR1## in which R.sub.1 and R.sub.2 are identical or different and denote C.sub.8 -C.sub.30 -alkyl, -2-hydroxyalkyl or -alkenyl or C.sub.8 -C.sub.24 -alkoxypropyl, m and n are 2 or 3, R.sub.3 is hydrogen or methyl and the sum of o+p+q+r is an integer from 4 to 600, process for their manufacture and their use as dispersing agents, corrosion inhibitors, demulsifiers and acid retarders.
摘要翻译：式1的聚醚多胺其中R 1和R 2相同或不同，表示C 8 -C 30 - 烷基，-2-羟基烷基或 - 烯基或C 8 -C 24烷氧基丙基，m和n为2或3，R 3为氢或甲基，o + p + q + r的和为4〜600的整数，其制造方法及其作为分散剂，腐蚀抑制剂，破乳剂和酸缓凝剂的用途。

4. 发明授权

US4339459A Guanidinium compounds and their use as microbiocidal agents 失效
标题翻译：胍化合物及其作为杀微生物剂的用途
公开(公告)号：US4339459A
公开(公告)日：1982-07-13
申请号：US216164
申请日：1980-12-15
申请人： Helmut Diery , Wolfgang Wagemann , Hans-Walter Bucking , Martin Hille , Karl H. Wallhausser
发明人： Helmut Diery , Wolfgang Wagemann , Hans-Walter Bucking , Martin Hille , Karl H. Wallhausser
IPC分类号： A01N47/44 , C07C67/00 , C07C239/00 , C07C279/04 , C07C279/12 , A61K31/205 , C07C129/12
CPC分类号： C07C279/12 , A01N47/44
摘要： Guanidiunium salts of the formula 1 ##STR1## in which R.sub.1 and R.sub.2 are identical or different and denote alkyl, 2-hydroxyalkyl or alkenyl each having from 8 to 18 carbon atoms, or C.sub.8 -C.sub.18 alkoxypropyl, m and n are 2 or 3, a is a number from 1 to 4 and A denotes an anion, process for their manufacture and their use as microbiocidal agents.
摘要翻译：其中R1和R2相同或不同并且表示具有8至18个碳原子的烷基，2-羟基烷基或烯基或C8-C18烷氧基丙基，m和n的式1的胍基鎓盐为2或3，a 是1至4的数，A表示阴离子，其制造方法及其作为杀微生物剂的用途。

5. 发明授权

US4309523A Water-soluble copolymer of acrylamidomethylpropanesulfonic acids salts 失效
标题翻译：丙烯酰胺基甲基丙磺酸盐的水溶性共聚物
公开(公告)号：US4309523A
公开(公告)日：1982-01-05
申请号：US174731
申请日：1980-08-01
申请人： Friedrich Engelhardt , Ulrich Riegel , Martin Hille , Heinz Wittkus
发明人： Friedrich Engelhardt , Ulrich Riegel , Martin Hille , Heinz Wittkus
IPC分类号： C09K8/02 , C08F20/00 , C08F20/52 , C08F26/00 , C08F220/56 , C08F220/58 , C08F226/02 , C08F228/02 , C09K8/03 , C09K8/04 , C09K8/24
CPC分类号： C08F220/58 , C09K8/24
摘要： Outstandingly suitable drilling mud additives are water soluble copolymers consisting essentially of a random distribution of(a) 5 to 95% by weight of units of the formula ##STR1## (b) 5 to 95% by weight of units of the formula ##STR2## and (c) 0 to 80% by weight of units of the formula ##STR3## wherein R.sup.1 and R.sup.2 are the same or different and each is hydrogen, methyl or ethyl; and X.sup..sym. is a cation.
摘要翻译：非常合适的钻井泥浆添加剂是水溶性共聚物，其基本上由以下组成的随机分布组成：（a）5至95重量％的式（b）单元：（b）5-95重量％和（c）0至80重量％的式“IMAGE”的单元，其中R 1和R 2相同或不同，各自为氢，甲基或乙基; 而X（+）是阳离子。

6. 发明授权

US5510436A Water-soluble copolymers useful in drilling fluids 失效
标题翻译：用于钻井液的水溶性共聚物
公开(公告)号：US5510436A
公开(公告)日：1996-04-23
申请号：US260037
申请日：1994-06-15
申请人： Martin Hille , Heinz Wittkus , Jurgen Tonhauser , Fritz Engelhardt , Ulrich Riegel
发明人： Martin Hille , Heinz Wittkus , Jurgen Tonhauser , Fritz Engelhardt , Ulrich Riegel
IPC分类号： C04B24/16 , C08F20/52 , C08F26/02 , C08F26/10 , C08F220/58 , C08F226/04 , C08F226/10 , C08L33/24 , C08L33/26 , C08L39/00 , C08L39/02 , C09D17/00 , C09K8/04 , C09K8/24 , C09K8/46 , C09K8/487 , C08F228/02
CPC分类号： C04B24/163 , C04B24/16 , C04B24/2652 , C08F220/58 , C08F226/04 , C09D17/001 , C09K8/24 , C09K8/46 , C09K8/487
摘要： The water-soluble copolymer comprises 5-90% by weight of groups of the formula ##STR1## in which R.sup.1 is hydrogen or methyl, R.sup.2 is C.sub.2 -C.sub.10 -alkylene, and Me is ammonium or an alkali metal, 5-90% by weight of groups of the formula--CH.dbd.CH--CH.sub.2 --N.sup.+ R.sup.3 R.sup.4 --CH.sub.2 --CH.dbd.CH-- X.sup.- IIin which X is a halogen, R.sup.3 and R.sup.4, independently of one another, are C.sub.1 -C.sub.6 -alkyl, 0-60% by weight of groups of the formula ##STR2## in which R.sup.5 and R.sup.6 together are a propylene group which with inclusion of the radical ##STR3## forms a pyrrolidone radical, and 0-30% by weight of groups of the formula--CHR.sup.7 --CHR.sup.8 -- IVin which R.sup.7 is hydrogen or methyl and R.sup.8 is CONH.sub.2, CON(CH.sub.3).sub.2, cyano, SO.sub.3 H, SO.sub.3 Me, C.sub.6 H.sub.4 SO.sub.3 H, C.sub.6 H.sub.4 SO.sub.3 Me, CH.sub.2 SO.sub.3 H, CH.sub.2 SO.sub.3 Me, COOH, COOMe, or carboxy-C.sub.1 -C.sub.15 --alkyl, and Me is an ammonium cation or an alkali metal cation, and the order of components I to IV can be as desired.The copolymer is used as water-binding additive for suspensions of solids, preferably for cement slurries, gypsum slurries, mortars, drilling muds or pigment suspensions, or as water-binding additive for aqueous salt solutions.
摘要翻译：水溶性共聚物包含5-90重量％的式I的基团，其中R 1是氢或甲基，R 2是C 2 -C 10 - 亚烷基，Me是铵或碱金属，5-90％的式-CH = CH-CH 2 -N + R 3 -CH 4 -CH = CH-X-II的基团，其中X是卤素，R 3和R 4彼此独立地是C 1 -C 6 - 烷基， 0-60重量％的其中R 5和R 6一起是含有基团“IMAGE”的丙烯基团的式“IMAGE”III形成吡咯烷酮基团，和0-30重量％的其中R 7是氢或甲基，R 8是CONH 2，CON（CH 3）2，氰基，SO 3 H，SO 3 Me，C 6 H 4 SO 3 H，C 6 H 4 SO 3 Me，CH 2 SO 3 H，CH 2 SO 3 Me，COOH，COOMe或羧基-C 1 -C 15 - 烷基，Me是铵阳离子或碱金属阳离子，组分I至IV的顺序可以根据需要进行。该共聚物用作固体悬浮液的水结合添加剂，优选用于水泥浆料，石膏浆料，砂浆，钻井泥浆或颜料悬浮液，或作为盐水溶液的水结合添加剂。

7. 发明授权

US5039450A Process for the separation of crude oil emulsions of the water-in-oil type 失效
标题翻译：分离油包水型原油乳液的方法
公开(公告)号：US5039450A
公开(公告)日：1991-08-13
申请号：US324189
申请日：1989-03-16
申请人： Rainer Kupfer , Willibald Bose , Martin Hille , Roland Bohm , Friedrich Staiss
发明人： Rainer Kupfer , Willibald Bose , Martin Hille , Roland Bohm , Friedrich Staiss
IPC分类号： B01D17/04 , B01D17/05 , C10G33/04
CPC分类号： C10G33/04 , B01D17/047
摘要： A process for the separation of crude oil emulsions of the water-in-oil typeIn the novel process addition products made from certain ethylene oxide/propylene oxide block polymers and certain polyglycidyl ethers of phenol/formaldehyde condensation products are added to the crude oil emulsions.
摘要翻译：一种油包水型原油乳液的分离方法将由某些环氧乙烷/环氧丙烷嵌段聚合物制备的新工艺加成产物和某些苯酚/甲醛缩合产物的多缩水甘油醚加入原油乳液。

8. 发明授权

US4885111A Branched, quaternary polyoxyalkylene copolyesters, a process for their preparation, and their use 失效
标题翻译：分支的季节聚氧化烯共聚酯，它们的制备方法及其用途
公开(公告)号：US4885111A
公开(公告)日：1989-12-05
申请号：US119823
申请日：1987-11-12
申请人： Wllibald Bose , Manfred Hofinger , Martin Hille , Roland Bohm , Friedrich Staiss
发明人： Wllibald Bose , Manfred Hofinger , Martin Hille , Roland Bohm , Friedrich Staiss
IPC分类号： C08G63/68 , B01D17/05 , C08G63/66 , C08G63/685 , C09K8/54 , C10G29/20 , C10G33/04
CPC分类号： C23F11/145 , C08G63/685 , C09K8/54 , C10G33/04 , C23F11/143 , C23F11/173
摘要： Branched, quaternary polyoxyalkylene copolyesters are described which are prepared by esterifying an oxyalkylated primary fatty amine and an at least trihydric oxyalkylated alkanol or an oxyalkylated polyamine using a dicarboxylic acid or a dicarboxylic anhydride with polycondensation, and quaternizing the esterification product obtained using ethylene oxide or propylene oxide in the presence of a mineral acid or carboxylic acid. The novel, branched, quaternary polyoxyalkylene copolyesters are used as demulsifiers and corrosion inhibitors in the processing of crude oil emulsions.
摘要翻译：描述了分支的季节聚氧化烯共聚酯，其通过使用二羧酸或二羧酸酐进行缩聚酯化烷氧基化伯脂肪胺和至少三元烷氧基化链烷醇或烷氧基化多胺而制备，并使用环氧乙烷或丙烯酸酯化的酯化产物季铵化氧化物在无机酸或羧酸存在下进行。在处理原油乳液时，新型支链季聚氧化烯共聚酯用作破乳剂和腐蚀抑制剂。

9. 发明授权

US5607618A Use of a water-soluble copolymers based on acrylamidoalkylenesulfonic acid as a detergent additive 失效
标题翻译：使用基于丙烯酰氨基烷基磺酸的水溶性共聚物作为洗涤剂添加剂
公开(公告)号：US5607618A
公开(公告)日：1997-03-04
申请号：US109229
申请日：1993-08-19
申请人： Werner Antwerpen , Martin Hille , Gerd Reinhardt
发明人： Werner Antwerpen , Martin Hille , Gerd Reinhardt
IPC分类号： C11D3/00 , C11D3/37 , C11D1/18
CPC分类号： C11D3/378 , C11D3/0021
摘要： The present invention relates to the the use of water-soluble copolymers based on acrylamidoalkylenesulfonic acid, vinylacetamide and, if appropriate, other monomers, comprising5-90% by weight of structural units of the formula ##STR1## in which R.sup.1 is hydrogen or methyl,R.sup.2 is C.sub.2 -C.sub.10 -alkylene, preferably C.sub.2 -C.sub.6 -alkylene, particularly preferably C.sub.4 -alkylene, andMe is ammonium or an alkali metal ion,5-95% by weight of structural units of the formula ##STR2## in which R.sup.3 and R.sup.4 independently of one another are hydrogen, methyl or ethyl, or R.sup.3 and R.sup.4 together are a propylene group which, including a radical ##STR3## form a pyrrolidone radical, 0-90% by weight of structural units of the formula ##STR4## in which X is a halogen, preferably chloride,R.sup.5 and R.sup.6 independently of one another are C.sub.1 -C.sub.6 -alkyl, prefrably C.sub.1 -C.sub.3 -alkyl, in particular methyl or ethyl, and0-90% by weight of structural units of the formula --CHR.sup.7 -CHR.sup.8 --in whichR.sup.7 is hydrogen or methyl andR.sup.8 is CONH.sub.2, CON(CH.sub.3).sub.2, cyano, SO.sub.3 H, SO.sub.3 Me, C.sub.6 H.sub.4 SO.sub.3 H, C.sub.6 H.sub.4 SO.sub.3 Me, CH.sub.2 SO.sub.3 H, CH.sub.2 SO.sub.3 Mr, COOH, COOMe or an ester group COOR, in which R is C.sub.1 -C.sub.15 -alkyl, preferably C.sub.1 -C.sub.8 -alkyl,as a detergent additive for preventing reabsorption of detached dyestuffs and dyestuff degradation products.
摘要翻译：本发明涉及使用基于丙烯酰氨基烷基磺酸，乙烯基乙酰胺和适当的其它单体的水溶性共聚物，其包含5-90重量％的式（I）的结构单元，其中R 1是氢或甲基，R 2是C 2 -C 10亚烷基，优选C 2 -C 6亚烷基，特别优选C 4亚烷基，Me是铵或碱金属离子，5-95重量％下式结构单元：（II），其中R 3和R 4彼此独立地是氢，甲基或乙基，或者R 3和R 4一起是丙烯基团，其包括基团形成吡咯烷酮基团，0-90重量％的结构单元其中X是卤素，优选氯，R 5和R 6彼此独立的式（III）的化合物是C 1 -C 6烷基，优选C 1 -C 3 - 烷基，特别是甲基或乙基，以及0-90 重量％的式-CHR7-CHR8的结构单元，其中R 7是氢或甲基，R 8是CONH 2，CON（CH 3）2，氰基，SO 3 H，SO 3 Me，C 6 H 4 SO 3 H，C 6 H 4 SO 3 Me，CH 2 SO 3 H，CH 2 SO 3 Mr，COOH，COOMe或酯基COOR，其中R是C 1 -C 15烷基，优选C 1 -C 8烷基，分离染料和染料降解产物的再吸收。

10. 发明授权

US4734523A Oxalkylated polyester-amines, a process for their preparation and their use 失效
标题翻译：烷基化聚酯胺，其制备方法及其应用
公开(公告)号：US4734523A
公开(公告)日：1988-03-29
申请号：US889316
申请日：1986-07-23
申请人： Manfred Hofinger , Willibald Bose , Martin Hille , Roland Bohm , Friedrich Staiss
发明人： Manfred Hofinger , Willibald Bose , Martin Hille , Roland Bohm , Friedrich Staiss
IPC分类号： C08G63/00 , B01D17/00 , B01D17/04 , B01D17/05 , C08G63/68 , C08G63/685 , C10G33/04
CPC分类号： C10G33/04 , C08G63/6856
摘要： Oxalkylated polyester-amines which are prepared by esterifying, with polycondensation, an oxalkylated primary fatty amine with a diol and with a dicarboxylic acid, are described. These polyester-amines are used as demulsifiers for breaking crude oil emulsions.
摘要翻译：描述了通过缩聚烷氧基烷基化的伯脂肪胺与二醇和二羧酸酯化制备的烷基化聚酯 - 胺。这些聚酯胺用作破乳剂用于破碎原油乳液。

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