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1. 发明授权

US09243124B2 Use of esters as coalescing agents 有权
标题翻译：使用酯作为聚结剂
公开(公告)号：US09243124B2
公开(公告)日：2016-01-26
申请号：US13988466
申请日：2011-08-10
申请人： Markus Scherer , Edda Bergmann , Sascha Oestreich , Miriam Becherer , Harald Frommelius
发明人： Markus Scherer , Edda Bergmann , Sascha Oestreich , Miriam Becherer , Harald Frommelius
IPC分类号： C08K5/101 , C09D5/02 , C09D7/06 , C09D133/08
CPC分类号： C08K5/101 , C09D5/024 , C09D7/47 , C09D133/08
摘要： The invention relates to esters, the acid component of which is a monocarboxylic acid having 8 to 12 C atoms and the alcohol component of which is selected from the group of the pentanols, wherein said esters are excellently suited as coalescing agents.
摘要翻译：本发明涉及酯，其酸组分是具有8至12个碳原子的单羧酸，其醇组分选自戊醇，其中所述酯非常适合作为聚结剂。

2. 发明授权

US09080124B2 Use of graft polymers 有权
标题翻译：接枝聚合物的使用
公开(公告)号：US09080124B2
公开(公告)日：2015-07-14
申请号：US11572181
申请日：2005-06-23
申请人： Markus Scherer , Klaus Hedrich , Alexander Dardin , Michael Mueller , Torsten Stoehr , Boris Eisenberg
发明人： Markus Scherer , Klaus Hedrich , Alexander Dardin , Michael Mueller , Torsten Stoehr , Boris Eisenberg
IPC分类号： C10M149/10 , C10M149/02 , C08L51/06 , C10M161/00
CPC分类号： C10M149/10 , C08L51/06 , C10M149/02 , C10M161/00 , C10M2209/084 , C10M2217/02 , C10M2217/028 , C10N2220/021 , C10N2220/022 , C10N2230/02 , C10N2230/04 , C10N2230/06 , C10N2230/43 , C10N2240/04 , C10N2240/08 , C10N2240/10
摘要： The invention relates to the use of graft polymers obtained by polymerization in two stages. In a first stage, at least one graft basis is produced by radically polymerizing a monomer composition A) containing 0 to 40 percent by weight of one or several ethylenically unsaturated ester compounds of formula (I), wherein R represents hydrogen or methyl, R1 represents a linear or branched alkyl radical comprising 1 to 5 carbon atoms, R2 and R3 independently represent hydrogen or a group of formula —COOR′, wherein R′ represents hydrogen or an alkyl group comprising 1 to 5 carbon atoms, 60 to 100 percent by weight of one or several ethylenically unsaturated ester compounds of formula (II), wherein R represents hydrogen or methyl, R4 represents a linear or branched alkyl radical comprising 6 to 40 carbon atoms, R5 and R6 independently represent hydrogen or a group of formula —COOR′, wherein R′ represents hydrogen or an alkyl group comprising 6 to 40 carbon atoms, and 0 to 40 percent by weight of comonomers, the percentages being relative to the weight of monomer composition A). In a second stage, a monomer composition B) containing 20 to 100 percent by weight of at least one monomer that comprises at least one nitrogen-containing group is grafted onto the graft basis in order to reduce wear in lubricant oil compositions. Said graft polymer comprises a maximum of 200 ppm of sulfur while the weight ratio between monomer composition A) and monomer composition B) ranges between 99.7:0.3 and 80:20.
摘要翻译：本发明涉及通过两步聚合获得的接枝聚合物的用途。在第一阶段中，通过自由基聚合含有0至40重量％的一种或多种式（I）的烯属不饱和酯化合物，其中R表示氢或甲基，R1表示包含1至5个碳原子的直链或支链烷基，R2和R3独立地表示氢或式-COOR'的基团，其中R'表示氢或包含1至5个碳原子的烷基，60至100重量％的一种或几种式（II）的烯键式不饱和酯化合物，其中R表示氢或甲基，R4表示包含6至40个碳原子的直链或支链烷基，R5和R6独立地表示氢或式-COOR' ，其中R'表示氢或含有6至40个碳原子的烷基和0至40重量％的共聚单体，其百分数相对于单体组合物的重量在A上）。在第二阶段中，将包含20至100重量％的至少一种包含至少一个含氮基团的单体的单体组合物B）接枝到接枝基上以减少润滑油组合物中的磨损。所述接枝聚合物包含最多200ppm的硫，而单体组合物A）和单体组合物B）之间的重量比在99.7:0.3和80:20之间。

3. 发明授权

US08779075B2 Use of nonionic surfactants as emulsifiers for emulsion polymerization (III) 失效
标题翻译：非离子表面活性剂用作乳液聚合乳化剂（III）
公开(公告)号：US08779075B2
公开(公告)日：2014-07-15
申请号：US13259846
申请日：2010-03-13
申请人： Markus Scherer , Thomas Schliwka , Katharina Hömberg , Uwe Held , Thomas Mausberg , Ronald Klagge
发明人： Markus Scherer , Thomas Schliwka , Katharina Hömberg , Uwe Held , Thomas Mausberg , Ronald Klagge
IPC分类号： C08F2/30
CPC分类号： C08F2/30
摘要： The invention relates to the use of aqueous solutions of nonionic surfactants as gel phase free emulsion systems for emulsion polymerization. The nonionic surfactants are chosen from the group (a) of the addition products from 1 to 40 mol ethylene and/or propylene oxide per mol of allyl alcohol, and (b) of the addition products from 1 to 40 mol ethylene and/or propylene oxide per mol of allyl alcohol, wherein the OH-group of said addition products is end-capped in the sense that it is substituted by a group OR, wherein R is an alkyl group with 1 to 20 C-atoms, which can be saturated or unsaturated, straight chained or branched.
摘要翻译：本发明涉及非离子表面活性剂的水溶液用作乳液聚合的无凝胶相乳液体系。非离子表面活性剂选自单体摩尔量为1至40mol乙烯和/或环氧丙烷/ mol烯丙醇的加成产物组（a），和（b）1-40mol乙烯和/或丙烯的加成产物氧化物/摩尔烯丙醇，其中所述加成产物的OH基在被基团OR取代的意义上被封端，其中R是具有1至20个C原子的烷基，其可以是饱和的或不饱和的，直链或支链的。

4. 发明授权

US08580287B2 Oil-based agrochemical compositions with increased viscosity 有权
标题翻译：具有粘度增加的油基农药组合物
公开(公告)号：US08580287B2
公开(公告)日：2013-11-12
申请号：US13201721
申请日：2010-02-06
申请人： Stéphanie Merlet , William Lamarca , Ludwig Schieferstein , Markus Scherer , Peter Bene
发明人： Stéphanie Merlet , William Lamarca , Ludwig Schieferstein , Markus Scherer , Peter Bene
IPC分类号： A01N25/00
CPC分类号： A01N25/02 , A01N25/04
摘要： Suggested are oil-based agrochemical compositions with increased viscosity, comprising (a) biocides, (b) hydrophobic carriers, and (c) polymers selected from the group consisting of poly(meth)acrylates, polymaleates and polyfumarates.
摘要翻译：建议是具有增加粘度的油基农药组合物，其包含（a）杀生物剂，（b）疏水载体和（c）选自聚（甲基）丙烯酸酯，聚马来酸酯和聚富马酸酯的聚合物。

5. 发明申请

US20130245175A1 Use Of Esters As Coalescing Agents 有权
标题翻译：使用酯类作为聚结剂
公开(公告)号：US20130245175A1
公开(公告)日：2013-09-19
申请号：US13988466
申请日：2010-11-25
申请人： Markus Scherer , Edda Bergmann , Sascha Oestreich , Miriam Becherer , Harald Frommelius
发明人： Markus Scherer , Edda Bergmann , Sascha Oestreich , Miriam Becherer , Harald Frommelius
IPC分类号： C08K5/101 , C09D133/08
CPC分类号： C08K5/101 , C09D5/024 , C09D7/47 , C09D133/08
摘要： The invention relates to esters, the acid component of which is a monocarboxylic acid having 8 to 12 C atoms and the alcohol component of which is selected from the group of the pentanols, wherein said esters are excellently suited as coalescing agents.
摘要翻译：本发明涉及酯，其酸组分是具有8至12个碳原子的单羧酸，其醇组分选自戊醇，其中所述酯非常适合作为聚结剂。

6. 发明申请

US20120220508A1 Lubricant Compositions 有权
标题翻译：润滑油组合物
公开(公告)号：US20120220508A1
公开(公告)日：2012-08-30
申请号：US13497574
申请日：2010-09-15
申请人： Ronny Rinklieb , Dirk Rettemeyer , Markus Scherer
发明人： Ronny Rinklieb , Dirk Rettemeyer , Markus Scherer
IPC分类号： C10M137/10
CPC分类号： C10M169/04 , C10M2207/2805 , C10M2207/2825 , C10M2207/2835 , C10M2207/2855 , C10M2223/047 , C10N2230/06 , C10N2240/08 , C10N2240/12 , C10N2240/30
摘要： Suggested is a method for enhancing energy efficiency of engines by applying to said engines a lubricant composition containing (A) carboxylic esters derived from the reaction of mono-, di- and/or poly alcohols with mono- and/or dicarboxylic acids, together with an additive blend (B) comprising at least two different additives (a) and (b) together, whereby compound (a) is selected from dithiophosphates, and compound (b) is selected from alkylated phosphorothionates, on condition that the total amount of the additive blend (B) is below 0.1 wt %, calculated on the weight of the whole composition.
摘要翻译：建议通过向所述发动机施加含有（A）衍生自单醇，二醇和/或多醇与单酸和/或二羧酸的反应的羧酸酯的润滑剂组合物，连同包含至少两种不同添加剂（a）和（b）的添加剂共混物（B），其中化合物（a）选自二硫代磷酸酯，化合物（b）选自烷基化硫代磷酸酯，条件是添加剂共混物（B）的含量低于0.1重量％，按整个组合物的重量计算。

7. 发明授权

US08142681B2 Aqueous surfactant compositions with a low pour point 有权
标题翻译：具有低倾点的水性表面活性剂组合物
公开(公告)号：US08142681B2
公开(公告)日：2012-03-27
申请号：US12469117
申请日：2009-05-20
申请人： Ronald Klagge , Markus Scherer , Thomas Schliwka , Katharina Hömberg , Uwe Held , Thomas Mausberg
发明人： Ronald Klagge , Markus Scherer , Thomas Schliwka , Katharina Hömberg , Uwe Held , Thomas Mausberg
IPC分类号： C09K3/00 , C08F2/22
CPC分类号： B01F17/0021 , B01F17/0085 , C08F2/24
摘要： Surfactant compositions which comprise (i) 10 to 90% by weight of one or more compounds selected from the group (a) to (e), and (ii) 10 to 90% by weight of water, based on the composition, are disclosed, where the compounds (a) to (e) are defined as follows: (a) addition products of ethylene oxide and/or propylene oxide with allyl alcohol, (b) addition products of ethylene oxide and/or propylene oxide with allyl alcohol, terminally capped with C1-20 alkyl, (c) compounds of the formula R1—O—X—R2, where X is 1 to 40 ethylene oxide and/or propylene oxide units and where R1 and R2 independently are C1-20 alkyl, excluding allyl, (d) compounds of the formula R3—O—X—H, where X is 1 to 40 ethylene oxide and/or propylene oxide units and where R3 is C1-20 alkyl, excluding allyl, (e) compounds of the formula H—O—X—H, where X is 1 to 40 ethylene oxide and/or propylene oxide units. The surfactant compositions are liquid and pourable at 20° C., with a pour point below 0° C., and are useful as emulsifiers in emulsion polymerization.
摘要翻译：公开了表面活性剂组合物，其包含（i）10至90重量％的一种或多种选自组（a）至（e）的化合物和（ii）10至90重量％的水，基于组合物其中化合物（a）至（e）定义如下：（a）环氧乙烷和/或环氧丙烷与烯丙醇的加成产物，（b）环氧乙烷和/或环氧丙烷与烯丙醇的加成产物，末端用C 1-20烷基封端，（c）式R 1 -O-X-R 2化合物，其中X为1至40个环氧乙烷和/或环氧丙烷单元，并且其中R 1和R 2各自为C 1-20烷基，不包括烯丙基，（d）式R 3 -O-X-H的化合物，其中X为1至40个环氧乙烷和/或环氧丙烷单元，其中R 3为C 1-20烷基，不包括烯丙基，（e）式 H-O-X-H，其中X为1至40个环氧乙烷和/或环氧丙烷单元。表面活性剂组合物是液体并且在20℃下倾倒，倾点低于0℃，并且可用作乳液聚合中的乳化剂。

8. 发明申请

US20110301037A1 Oil-Based Agrochemical Compositions With Increased Viscosity 有权
标题翻译：油基农药组合物粘度增加
公开(公告)号：US20110301037A1
公开(公告)日：2011-12-08
申请号：US13201721
申请日：2010-02-06
申请人： Stéphanie Merlet , William Lamarca , Ludwig Schieferstein , Markus Scherer , Peter Bene
发明人： Stéphanie Merlet , William Lamarca , Ludwig Schieferstein , Markus Scherer , Peter Bene
IPC分类号： A01N25/02 , A01P3/00 , A01P7/04 , A01N25/30 , A01P13/00
CPC分类号： A01N25/02 , A01N25/04
摘要： Suggested are oil-based agrochemical compositions with increased viscosity, comprising (a) biocides, (b) hydrophobic carriers, and (c) polymers selected from the group consisting of poly(meth)acrylates, polymaleates and polyfumarates.
摘要翻译：建议是具有增加粘度的油基农药组合物，其包含（a）杀生物剂，（b）疏水载体和（c）选自聚（甲基）丙烯酸酯，聚马来酸酯和聚富马酸酯的聚合物。

9. 发明申请

US20060247436A1 Process for preparing acylphosphanes and derivatives thereof 有权
标题翻译：制备酰基磷烷及其衍生物的方法
公开(公告)号：US20060247436A1
公开(公告)日：2006-11-02
申请号：US10564711
申请日：2004-07-09
申请人： Reinhard Sommerlade , Souad Boulmaaz , Jean-Pierre Wolf , Jens Geier , Hansjorg Grutzmacher , Markus Scherer , Hartmut Schonberg , Daniel Stein , Peter Murer , Stephan Burkhardt
发明人： Reinhard Sommerlade , Souad Boulmaaz , Jean-Pierre Wolf , Jens Geier , Hansjorg Grutzmacher , Markus Scherer , Hartmut Schonberg , Daniel Stein , Peter Murer , Stephan Burkhardt
IPC分类号： C07F9/6533 , C07F9/06 , C07F9/547
CPC分类号： C07F9/5036 , C07F9/5337
摘要： The present invention relates to a new, selective process for the preparation of mono- and bisacylphosphanes of formula (I) n and m are each independently of the other 1 or 2; R1, if n=1, is e.g. phenyl R1, if n=2, is e.g. C1-C18alkylene or phenylene; R2 is e.g. C1-C18alkyl, phenyl or substituted phenyl; R3 is e.g. C1-C18alkyl, by (I) reacting a phosphorous halide of formula IIa or a phosphorous halide oxide of formula (IIb) or a phosphorous halide sulfide of formula (IIc) with an alkali metal in a solvent in the presence of a proton source; (2) subsequent reaction with m acid halides of formula (III) An oxidation step may follow to obtain mono- and bisacylphosphane oxides or mono-and bisacylphosphane sulfides.
摘要翻译：本发明涉及制备式（I）的单 - 和双酰基磷烷的新的选择性方法，n和m各自独立地为1或2; 如果n = 1，则为R 1。苯基R 1，如果n = 2，则为例如。 C 1 -C 18亚烷基或亚苯基; R 2是例如。 C 1 -C 18烷基，苯基或取代的苯基; R 3是例如。通过（I）使式IIa的卤化磷或式（IIb）的卤化磷氧化物或式（IIb）的卤化磷化物或式（Ⅳ） IIc）与碱金属在溶剂中在质子源存在下反应; （2）随后与式（III）的酰卤反应可以进行氧化步骤以获得单酰基和双酰基氧化膦或单酰基和双酰基磷烷硫化物。

10. 发明申请

US20050245406A1 Lubricating grease with high water resistance 有权
标题翻译：润滑脂具有高耐水性
公开(公告)号：US20050245406A1
公开(公告)日：2005-11-03
申请号：US10834861
申请日：2004-04-30
申请人： Markus Scherer , Matthias Fischer , Michael Mueller , Bernard Kinker , Alexandra Pauker
发明人： Markus Scherer , Matthias Fischer , Michael Mueller , Bernard Kinker , Alexandra Pauker
IPC分类号： C10M145/14 , C10M151/02 , C10M153/02 , C10M169/00 , C10M169/06 , C10N50/10
CPC分类号： C10M169/06 , C10M145/14 , C10M169/00 , C10M2203/1006 , C10M2207/1285 , C10M2207/144 , C10M2209/084 , C10M2215/064 , C10N2220/021 , C10N2230/26 , C10N2250/10
摘要： The present invention relates to lubricating greases comprising at least one thickening agent and at least one lubricating oil, wherein the lubricating grease contains at least one polymeric structure improver that can be obtained by polymerization of monomer compositions, which are composed of a) 0 to 40 wt %, relative to the weight of the monomer compositions for synthesis of the polymeric structure improvers, of at least one (meth)acrylate of formula (I) in which R represents hydrogen or methyl, R1 denotes a straight-chain or branched alkyl moiety having 1 to 5 carbon atoms, b) 40 to 99.99 wt %, relative to the weight of the monomer compositions for synthesis of the polymeric structure improvers, of at least one (meth)acrylate of formula (II) in which R represents hydrogen or methyl, R2 denotes a straight-chain or branched alkyl moiety having 6 to 30 carbon atoms, c) 0.01 to 20 wt %, relative to the weight of the monomer compositions for synthesis of the polymeric structure improvers, of monomers containing acid groups or salts thereof, d) 0 to 59.99 wt %, relative to the weight of the monomer compositions for synthesis of the polymeric structure improvers, of comonomer.
摘要翻译：本发明涉及包含至少一种增稠剂和至少一种润滑油的润滑脂，其中润滑脂含有至少一种聚合物结构改进剂，其可通过单体组合物的聚合获得，所述聚合物结构改进剂由以下组成：a）0至40 至少一种式（I）的（甲基）丙烯酸酯，其中R表示氢或甲基，R 1表示相对于合成聚合物结构改进剂的单体组合物的重量，wt％表示至少一种式（甲基）丙烯酸酯（具有1-5个碳原子的直链或支链烷基部分，b）相对于合成聚合物结构改进剂的单体组合物的重量为40-99.99重量％ II），其中R表示氢或甲基，R 2表示具有6至30个碳原子的直链或支链烷基部分，c）相对于单体重量为0.01至20重量％用于合成聚合物的组合物含有酸基团或其盐的单体的ric结构改进剂，d）相对于用于合成聚合物结构改进剂的单体组合物的重量，共聚单体为0至59.99重量％。

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