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    • 3. 发明授权
    • Axi-symmetrical flow reactor for .sup.196 Hg photochemical enrichment
    • 轴对称流动反应器,196ppm光化学富集
    • US5012106A
    • 1991-04-30
    • US289639
    • 1988-12-23
    • Mark W. Grossman
    • Mark W. Grossman
    • B01D59/34
    • B01D59/34
    • The present invention is directed to an improved photochemical reactor useful for the isotopic enrichment of a predetermined isotope of mercury, especially, .sup.196 Hg. Specifically, two axi-symmetrical flow reactors were constructed according to the teachings of the present invention. These reactors improve the mixing of the reactants during the photochemical enrichment process, affording higher yields of the desired .sup.196 Hg product. Measurements of the variation of yield (Y) and enrichment factor (E) along the flow axis of these reactors indicates very substantial improvement in process uniformity compared to previously used photochemical reactor systems. In one preferred embodiment of the present invention, the photoreactor system was built such that the reactor chamber was removable from the system without disturbing the location of either the photochemical lamp or the filter employed therewith.
    • 本发明涉及一种改进的光化学反应器,其用于预定的同位素汞,特别是196Hg的同位素富集。 具体地,根据本发明的教导构造了两个轴对称流动反应器。 这些反应器在光化学富集过程中改善了反应物的混合,提供了更高的所需196Hg产物的产率。 与以前使用的光化学反应器系统相比,沿着这些反应器的流动轴线的产量(Y)和富集因子(E)变化的测量显示了工艺均匀性的显着改善。 在本发明的一个优选实施方案中,构建光反应器系统,使得反应器室可从系统中取出,而不会干扰光化学灯或使用的过滤器的位置。
    • 5. 发明授权
    • Method and apparatus for monitoring the flow of mercury in a system
    • 监测系统中汞流量的方法和装置
    • US4713547A
    • 1987-12-15
    • US816035
    • 1986-01-03
    • Mark W. Grossman
    • Mark W. Grossman
    • G01N21/31G01N21/85G01N21/59
    • G01N21/85G01N21/3103G01N2021/3107G01N2021/8578
    • An apparatus and method for monitoring the flow of mercury in a system. The equipment enables the entrainment of the mercury in a carrier gas e.g., an inert gas, which passes as mercury vapor between a pair of optically transparent windows. The attenuation of the emission is indicative of the quantity of mercury (and its isotopes) in the system. A 253.7 nm light is shone through one of the windows and the unabsorbed light is detected through the other window. The absorption of the 253.7 nm light is thereby measured whereby the quantity of mercury passing between the windows can be determined. The apparatus includes an in-line sensor for measuring the quantity of mercury. It includes a conduit together with a pair of apertures disposed in a face to face relationship and arranged on opposite sides of the conduit. A pair of optically transparent windows are disposed upon a pair of viewing tubes. A portion of each of the tubes is disposed inside of the conduit and within each of the apertures. The two windows are disposed in a face to face relationship on the ends of the viewing tubes and the entire assembly is hermetically sealed from the atmosphere whereby when 253.7 nm ultraviolet light is shone through one of the windows and detected through the other, the quantity of mercury which is passing by can be continuously monitored due to absorption which is indicated by attenuation of the amplitude of the observed emission.
    • 一种用于监测系统中汞流动的装置和方法。 该设备能够将汞夹带在诸如惰性气体的载体气体中,惰性气体在一对光学透明窗口之间以汞蒸汽的形式通过。 发射的衰减表明系统中汞(及其同位素)的数量。 通过其中一个窗口照射253.7nm的光,并且通过另一个窗口检测未吸收的光。 由此测量253.7nm光的吸收,由此可以确定在窗口之间通过的汞的量。 该装置包括用于测量汞量的在线传感器。 它包括一个导管和一对以面对面的关系设置的孔,并布置在导管的相对侧上。 一对光学透明的窗口设置在一对观察管上。 每个管的一部分设置在导管内部和每个孔内。 这两个窗口在观察管的端部以面对面的关系设置,并且整个组件与大气密封,由此当通过一个窗口照射253.7nm的紫外线并通过另一个窗口检测时, 可以通过由观察到的发射的振幅的衰减来表示的吸收来连续监测正在经过的汞。
    • 6. 发明授权
    • Obtaining accurate amounts of mercury from mercury compounds via
electrolytic methods
    • 通过电解方法从汞化合物中获得准确量的汞
    • US4678550A
    • 1987-07-07
    • US815146
    • 1985-12-31
    • Mark W. GrossmanWilliam A. George
    • Mark W. GrossmanWilliam A. George
    • C25C1/16C25C1/00
    • C25C1/16
    • A process for obtaining pre-determined, accurate rate amounts of mercury. In one embodiment, predetermined, precise amounts of Hg are separated from HgO and plated onto a cathode wire. The method for doing this involves dissolving a precise amount of HgO which corresponds to a pre-determined amount of Hg desired in an electrolyte solution comprised of glacial acetic acid and H.sub.2 O. The mercuric ions are then electrolytically reduced and plated onto a cathode producing the required pre-determined quantity of Hg. In another embodiment, pre-determined, precise amounts of Hg are obtained from Hg.sub.2 Cl.sub.2. The method for doing this involves dissolving a precise amount of Hg.sub.2 Cl.sub.2 in an electrolyte solution comprised of concentrated HCl and H.sub.2 O. The mercurous ions in solution are then electrolytically reduced and plated onto a cathode wire producing the required, pre-determined quantity of Hg.
    • 获得预定的准确率的汞量的方法。 在一个实施例中,将预定的精确量的Hg与HgO分离并镀在阴极线上。 这样做的方法包括将精确量的HgO溶解在对应于由冰醋酸和H 2 O组成的电解质溶液中所需的预定量的Hg。 然后将汞离子电解还原并镀在阴极上,产生所需的预定量的Hg。 在另一个实施方案中,从Hg 2 Cl 2获得预定的精确量的Hg。 这样做的方法包括将精确量的Hg2Cl2溶解在由浓HCl和H 2 O组成的电解质溶液中。 然后将溶液中的汞离子电解还原,并镀在阴极丝上,产生所需的预定量的Hg。
    • 7. 发明授权
    • Method of preparing mercury with an arbitrary isotopic distribution
    • 制备具有任意同位素分布的汞的方法
    • US4629543A
    • 1986-12-16
    • US815147
    • 1985-12-31
    • Mark W. GrossmanWilliam A. George
    • Mark W. GrossmanWilliam A. George
    • C25C1/16H01J61/20C25C1/00
    • C25C1/16H01J61/20
    • This invention provides for a process for preparing mercury with a predetermined, arbitrary, isotopic distribution. In one embodiment, different isotopic types of Hg.sub.2 Cl.sub.2, corresponding to the predetermined isotopic distribution of Hg desired, are placed in an electrolyte solution of HCl and H.sub.2 O. The resulting mercurous ions are then electrolytically plated onto a cathode wire producing mercury containing the predetermined isotopic distribution. In a similar fashion, Hg with a predetermined isotopic distribution is obtained from different isotopic types of HgO. In this embodiment, the HgO is dissolved in an electrolytic solution of glacial acetic acid and H.sub.2 O. The isotopic specific Hg is then electrolytically plated onto a cathode and then recovered.
    • 本发明提供了一种制备具有预定的,任意的同位素分布的汞的方法。 在一个实施方案中,对应于所需Hg的预定同位素分布的Hg2Cl2的不同同位素类型被放置在HCl和H 2 O的电解质溶液中。 然后将所得到的汞离子电解电镀到产生含有预定同位素分布的汞的阴极线上。 以类似的方式,从不同同位素类型的HgO获得具有预定同位素分布的Hg。 在该实施方案中,将HgO溶于冰醋酸和H 2 O的电解溶液中。 然后将同位素特异性Hg电解镀在阴极上,然后回收。