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1. 发明申请

US20190062293A1 METAL-ORGANIC FRAMEWORKS FOR THE CONVERSION OF LIGNOCELLULOSIC DERIVATIVES TO RENEWABLE PLATFORM CHEMICALS 审中-公开
公开(公告)号：US20190062293A1
公开(公告)日：2019-02-28
申请号：US15539122
申请日：2015-12-17
申请人： Noppadon Sathitsuksanoh , Mark D. Allendorf , Anthe George , Robert Jansen , Kirsty Leong , Blake A. Simmons , Seema Singh , Philip Travisano, III
发明人： Noppadon Sathitsuksanoh , Mark D. Allendorf , Anthe George , Robert Jansen , Kirsty Leong , Blake A. Simmons , Seema Singh , Philip Travisano, III
IPC分类号： C07D307/50 , B01J31/16
摘要： Methods of processing lignocellulose using metal-organic frameworks (MOFs) to form renewable platform chemicals that may be used as initial feedstock are provided. Metal-organic frameworks react with Provide lignocellulosic derivative lignocellulosic derivatives such as glucose and fructose to form 5-hydroxymethyl furfural (HMF) with high yield and high selectivity for FIMF production.

2. 发明申请

US20110108738A1 DOPED LUMINESCENT MATERIALS AND PARTICLE DISCRIMINATION USING SAME 有权
标题翻译：使用相同的DOPED LUMINESCENT材料和颗粒识别
公开(公告)号：US20110108738A1
公开(公告)日：2011-05-12
申请号：US12943708
申请日：2010-11-10
申请人： F. Patrick Doty , Mark D. Allendorf , Patrick L. Feng
发明人： F. Patrick Doty , Mark D. Allendorf , Patrick L. Feng
IPC分类号： G01J1/58 , C09K11/06
CPC分类号： C09K11/06 , C09K2211/1029 , C09K2211/1074 , C09K2211/1092 , C09K2211/185 , G21K4/00
摘要： Doped luminescent materials are provided for converting excited triplet states to radiative hybrid states. The doped materials may be used to conduct pulse shape discrimination (PSD) using luminescence generated by harvested excited triplet states. The doped materials may also be used to detect particles using spectral shape discrimination (SSD).
摘要翻译：提供掺杂的发光材料用于将激发的三线态转换成辐射混合状态。掺杂材料可用于使用由收获的激发三线态产生的发光来进行脉冲形状鉴别（PSD）。掺杂材料也可以用于使用光谱形状鉴别（SSD）来检测颗粒。

3. 发明授权

US07027150B1 Apparatus for measuring the concentration of a species at a distance 有权
标题翻译：用于测量远处物种浓度的装置
公开(公告)号：US07027150B1
公开(公告)日：2006-04-11
申请号：US10877630
申请日：2004-06-24
申请人： Steven F. Rice , Mark D. Allendorf
发明人： Steven F. Rice , Mark D. Allendorf
IPC分类号： G01N21/64
CPC分类号： G01N21/718 , G01N21/6402 , G01N2021/6417
摘要： Corrosion of refractory silica brick and air quality issues due to particulate emissions are two important glass manufacturing issues that have been tied to sodium vapor and its transport throughout the melt tank. Knowledge of the relationship between tank operating conditions and tank atmosphere sodium levels are therefore important considerations in correcting corrosion and air quality issues. However, until recently direct quantitative measurements of sodium levels has been limited to extractive sampling methods followed by laboratory analysis. Excimer laser induced fragmentation (ELIF) fluorescence spectroscopy is a technique that permits the measurement of volatilized NaOH in high temperature environments on a timescale of less than one second. The development of this method and the construction of field-portable instrumentation for glass furnace applications are herein disclosed. The method is shown to be effective in full-scale industrial settings. Characteristics of the method are outlined, including equipment configuration, detection sensitivity, and calibration methodology.
摘要翻译：耐火硅砖的腐蚀和颗粒物排放引起的空气质量问题是两个重要的玻璃制造问题，这些问题与钠蒸汽及其在整个熔池中的运输有关。因此，了解油箱运行状况与油罐大气钠含量之间的关系是修正腐蚀和空气质量问题的重要考虑因素。然而，直到最近，钠水平的直接定量测量仅限于采样方法，然后进行实验室分析。准分子激光诱导碎裂（ELIF）荧光光谱法是允许在高温环境中测量挥发性NaOH的技术，其时间尺度小于1秒。本文公开了该方法的开发和用于玻璃熔炉应用的现场便携式仪器的构造。该方法显示在全面的工业环境中有效。概述了该方法的特点，包括设备配置，检测灵敏度和校准方法。

4. 发明授权

US08065904B1 Method and apparatus for detecting an analyte 有权
标题翻译：用于检测分析物的方法和装置
公开(公告)号：US08065904B1
公开(公告)日：2011-11-29
申请号：US12137635
申请日：2008-06-12
申请人： Mark D. Allendorf , Peter J. Hesketh
发明人： Mark D. Allendorf , Peter J. Hesketh
IPC分类号： G01N27/00 , G01N33/497
CPC分类号： G01N29/022
摘要： We describe the use of coordination polymers (CP) as coatings on microcantilevers for the detection of chemical analytes. CP exhibit changes in unit cell parameters upon adsorption of analytes, which will induce a stress in a static microcantilever upon which a CP layer is deposited. We also describe fabrication methods for depositing CP layers on surfaces.
摘要翻译：我们描述了使用配位聚合物（CP）作为微悬臂梁上的涂层来检测化学分析物。在吸附分析物时，CP显示单位电池参数的变化，这将在沉积CP层的静电微悬臂梁中引起应力。我们还描述了在表面上沉积CP层的制造方法。

5. 发明授权

US08853651B2 Doped luminescent materials and particle discrimination using same 有权
标题翻译：掺杂的发光材料和使用其的颗粒鉴别
公开(公告)号：US08853651B2
公开(公告)日：2014-10-07
申请号：US12943708
申请日：2010-11-10
申请人： F. Patrick Doty , Mark D. Allendorf , Patrick L. Feng
发明人： F. Patrick Doty , Mark D. Allendorf , Patrick L. Feng
IPC分类号： G01J1/58 , G21K4/00 , C09K11/06
CPC分类号： C09K11/06 , C09K2211/1029 , C09K2211/1074 , C09K2211/1092 , C09K2211/185 , G21K4/00
摘要： Doped luminescent materials are provided for converting excited triplet states to radiative hybrid states. The doped materials may be used to conduct pulse shape discrimination (PSD) using luminescence generated by harvested excited triplet states. The doped materials may also be used to detect particles using spectral shape discrimination (SSD).
摘要翻译：提供掺杂的发光材料用于将激发的三线态转换成辐射混合状态。掺杂材料可用于使用由收获的激发三线态产生的发光来进行脉冲形状鉴别（PSD）。掺杂材料也可以用于使用光谱形状鉴别（SSD）来检测颗粒。

6. 发明授权

US07985868B1 Hybrid metal organic scintillator materials system and particle detector 有权
标题翻译：混合金属有机闪烁体材料体系和粒子检测器
公开(公告)号：US07985868B1
公开(公告)日：2011-07-26
申请号：US11800136
申请日：2007-05-04
申请人： Christina A. Bauer , Mark D. Allendorf , F. Patrick Doty , Blake A. Simmons
发明人： Christina A. Bauer , Mark D. Allendorf , F. Patrick Doty , Blake A. Simmons
IPC分类号： C30B29/06
CPC分类号： C09K11/04 , C09K11/06 , C09K2211/1408 , C09K2211/188
摘要： We describe the preparation and characterization of two zinc hybrid luminescent structures based on the flexible and emissive linker molecule, trans-(4-R,4′-R′) stilbene, where R and R′ are mono- or poly-coordinating groups, which retain their luminescence within these solid materials. For example, reaction of trans-4,4′-stilbenedicarboxylic acid and zinc nitrate in the solvent dimethylformamide (DMF) yielded a dense 2-D network featuring zinc in both octahedral and tetrahedral coordination environments connected by trans-stilbene links. Similar reaction in diethylformamide (DEF) at higher temperatures resulted in a porous, 3-D framework structure consisting of two interpenetrating cubic lattices, each featuring basic to zinc carboxylate vertices joined by trans-stilbene, analogous to the isoreticular MOF (IRMOF) series. We demonstrate that the optical properties of both embodiments correlate directly with the local ligand environments observed in the crystal structures. We further demonstrate that these materials produce high luminescent response to proton radiation and high radiation tolerance relative to prior scintillators. These features can be used to create sophisticated scintillating detection sensors.
摘要翻译：我们描述了基于柔性和发射接头分子，反式（4-R，4'-R'）二苯乙烯的两种锌杂化发光结构的制备和表征，其中R和R'是单或多配位基团，其在这些固体材料中保持其发光。例如，反式-4,4'-二苯基二羧酸和硝酸锌在溶剂二甲基甲酰胺（DMF）中的反应产生了一个致密的2-D网络，其特征在于通过茋链接连接的八面体和四面体配位环境中的锌。在较高温度下，在二乙基甲酰胺（DEF）中类似的反应产生了一个多孔的3-D骨架结构，其由两个相互贯穿的立方晶格组成，每个都具有与反式二苯乙烯连接的羧酸锌顶点碱基，类似于折射率MOF（IRMOF）系列。我们证明两个实施方案的光学性质直接与在晶体结构中观察到的局部配体环境相关。我们进一步证明这些材料相对于以前的闪烁体产生对质子辐射的高发光响应和高辐射耐受性。这些功能可用于创建复杂的闪烁检测传感器。

7. 发明授权

US08904850B1 Materials, methods and devices to detect and quantify water vapor concentrations in an atmosphere 有权
标题翻译：用于检测和量化大气中水蒸气浓度的材料，方法和装置
公开(公告)号：US08904850B1
公开(公告)日：2014-12-09
申请号：US13253274
申请日：2011-10-05
申请人： Mark D. Allendorf , Alex L. Robinson
发明人： Mark D. Allendorf , Alex L. Robinson
IPC分类号： H01L41/113 , G01N29/02
CPC分类号： G01N29/022 , B82Y30/00 , G01N29/036 , G01N2291/0255 , G01N2291/0256 , G01N2291/0423 , G01N2291/0427
摘要： We have demonstrated that a surface acoustic wave (SAW) sensor coated with a nanoporous framework material (NFM) film can perform ultrasensitive water vapor detection at concentrations in air from 0.05 to 12,000 ppmv at 1 atmosphere pressure. The method is extendable to other MEMS-based sensors, such as microcantilevers, or to quartz crystal microbalance sensors. We identify a specific NFM that provides high sensitivity and selectivity to water vapor. However, our approach is generalizable to detection of other species using NFM to provide sensitivity and selectivity.
摘要翻译：我们已经证明，涂覆有纳米多孔骨架材料（NFM）膜的表面声波传感器（SAW）传感器可以在空气中的浓度为0.05至12,000ppmv，在1个大气压下进行超敏感水蒸气检测。该方法可扩展到其他基于MEMS的传感器，例如微悬臂梁或石英晶体微量天平传感器。我们识别出具有高水平的高灵敏度和选择性的特定NFM。然而，我们的方法可以概括为使用NFM检测其他物种以提供灵敏度和选择性。

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