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    • 1. 发明授权
    • Polymer and photoconductive element having a polymeric barrier layer
    • 具有聚合物阻挡层的聚合物和光电导元件
    • US06451956B2
    • 2002-09-17
    • US09877763
    • 2001-06-08
    • Louis J. SorrieroMarie B. O'ReganMichel F. Molaire
    • Louis J. SorrieroMarie B. O'ReganMichel F. Molaire
    • C08G7310
    • C08G73/16C08G73/1082C08G73/14G03G5/142
    • In a photoconductive element comprising a conductive support, e.g., an electrically conductive film, drum or belt on which a negatively chargeable photoconductive layer is formed, an electrical barrier layer is formed between the support and the photoconductive layer. The barrier layer provides a high energy barrier to the injection of positive charges but transports electrons under an applied electric field. The barrier layer of the invention transports charge by electronic rather than ionic mechanisms and, therefore, is not substantially affected by humidity changes. The barrier layer comprises a polyester-co-imide, polyesterionomer-co-imide or polyamide-co-imide having covalently bonded as repeating units in the polymer chain, aromatic tetracarboxylbisimide groups of the formula: wherein Ar1 and Ar2 represent, respectively, tetravalent and trivalent aromatic groups of 6 to 20 carbon atoms.
    • 在包含导电性支持体(例如形成有可带电电荷的光电导层的导电膜,鼓或带)的光电导元件中,在支撑体和光电导层之间形成电阻隔层。 阻挡层为注入正电荷提供了高能量势垒,但在施加的电场下传输电子。 本发明的阻挡层通过电子而不是离子机制传输电荷,因此基本上不受湿度变化的影响。 阻挡层包括在聚合物链中共价键合作为重复单元的聚酯 - 共 - 酰亚胺,聚酯共聚物 - 共 - 酰亚胺或聚酰胺 - 共 - 酰亚胺,下式的芳族四羧基双酰亚胺基团:其中Ar1和Ar2分别表示四价和 6-20个碳原子的三价芳族基团。
    • 3. 发明授权
    • Electronic device having electrodes and organic active regions and processes of forming the same
    • 具有电极和有机活性区域的电子器件及其形成方法
    • US08154700B2
    • 2012-04-10
    • US12344309
    • 2008-12-26
    • Shiva PrakashMarie B. O'ReganWilliam F. Feehery
    • Shiva PrakashMarie B. O'ReganWilliam F. Feehery
    • G02F1/1343
    • H01L51/56H01L27/3211H01L51/5012
    • An electronic device can include an electrode and an organic active region. In one aspect, the electronic device can include the electrode having a corresponding pitch and an organic active region adjacent to the electrode, wherein the organic active region has a width greater than the corresponding pitch. In another aspect, an electronic device can include a first set of electrodes oriented substantially along a direction and a second set of electrodes oriented substantially along the direction. The electronic device can also include a space between the first and second sets of the electrodes. The electronic device can still further include an organic active region overlying or underlying the first and second sets of electrodes and the space. In other aspects, processes of forming the electronic devices are also disclosed.
    • 电子器件可以包括电极和有机活性区域。 在一个方面中,电子器件可以包括具有相应间距的电极和与电极相邻的有机有源区,其中有机有源区具有大于相应间距的宽度。 在另一方面,电子设备可以包括基本上沿着方向定向的第一组电极和基本上沿该方向取向的第二组电极。 电子设备还可以包括在第一和第二组电极之间的空间。 电子设备还可以进一步包括覆盖第一和第二组电极和空间的有机活性区域。 在其他方面,还公开了形成电子设备的过程。
    • 6. 发明授权
    • Photoconductive elements having a polymeric barrier layer
    • 具有聚合物阻挡层的光导元件
    • US06866977B2
    • 2005-03-15
    • US10243702
    • 2002-09-14
    • Louis J. SorrieroMichel F. MolaireMarie B. O'ReganWayne T. FerrarDavid S. WeissJane Robin Cowdery
    • Louis J. SorrieroMichel F. MolaireMarie B. O'ReganWayne T. FerrarDavid S. WeissJane Robin Cowdery
    • C08G73/10C08G73/14C08G73/16G03G5/14G03G5/10
    • C08G73/16C08G73/1082C08G73/14G03G5/142
    • Disclosed are photoconductive elements including a conductive support, e.g., an electrically conductive film, drum, or belt, on which a negatively chargeable photoconductive layer is disposed. An electrical barrier layer is disposed between the conductive support and the photoconductive layer. The barrier layer provides a high energy barrier to the injection of positive charges, but transports electrons under an applied electric field. In embodiments, the barrier layer can transport charge by electronic mechanisms, and, is not substantially affected by humidity changes. The barrier layer includes a polyamide-co-imide having covalently bonded as repeat units in the polymer chain, aromatic tetracarbonylbisimide groups of the formula: wherein Ar1 and Ar2 respectively represent tetravalent or trivalent aromatic groups of 6 to about 20 carbon atoms, and X is O, C(CF3)2, S═O or SO2. The amount of aromatic tetracarbonylbisimide content in the polymer is selected such that the barrier layer can be coated onto the support as a relatively thick layer, which provides for enhanced performance as a photoconductor when used in an electrophotographic process.
    • 公开了包括导电性支持体(例如,导电膜,鼓或带)的光电导元件,其上设置有带负电的光导电层。 电阻挡层设置在导电支撑体和光电导层之间。 阻挡层为注入正电荷提供了高能量势垒,但在施加的电场下传输电子。 在实施例中,阻挡层可以通过电子机构输送电荷,并且基本上不受湿度变化的影响。 阻挡层包括在聚合物链中具有作为重复单元共价键合的聚酰胺 - 共 - 酰亚胺,下式的芳族四羰基双酰亚胺基团:其中Ar 1和Ar 2分别表示6至约20的四价或三价芳族基团 碳原子,X是O,C(CF 3)2,S = O或SO 2。 选择聚合物中芳族四羰基二酰亚胺含量的量使得阻挡层可以涂覆在载体上作为相对较厚的层,当用于电子照相方法时,这提供了作为光电导体的增强的性能。
    • 10. 发明授权
    • Photoconductive elements having a polymeric barrier layer
    • 具有聚合物阻挡层的光导元件
    • US06593046B2
    • 2003-07-15
    • US09954907
    • 2001-09-18
    • Louis J. SorrieroMichel F. MolaireMarie B. O'ReganWayne T. FerrarDavid S. WeissJane Robin Cowdery
    • Louis J. SorrieroMichel F. MolaireMarie B. O'ReganWayne T. FerrarDavid S. WeissJane Robin Cowdery
    • G03G510
    • C08G73/1082C08G73/14C08G73/16G03G5/142
    • Disclosed are photoconductive elements including a conductive support, e.g., an electrically conductive film, drum, or belt, on which a negatively chargeable photoconductive layer is disposed. An electrical barrier layer is disposed between the conductive support and the photoconductive layer. The barrier layer provides a high energy barrier to the injection of positive charges, but transports electrons under an applied electric field. In embodiments, the barrier layer can transport charge by electronic, or both electronic and ionic mechanisms, and, is not substantially affected by humidity changes. The barrier layer includes a polyester-co-imides, polyesterionomer-co-imides, or polyamide-co-imides having covalently bonded as repeat units in the polymer chain, aromatic tetracarbonylbisimide groups of the formula: wherein Ar1 and Ar2 respectively represent tetravalent or trivalent aromatic groups of 6 to about 20 carbon atoms, and X is O, C(CF3)2, S═O or SO2.
    • 公开了包括导电性支持体(例如,导电膜,鼓或带)的光电导元件,其上设置有带负电的光导电层。 电阻挡层设置在导电支撑体和光电导层之间。 阻挡层为注入正电荷提供了高能量势垒,但在施加的电场下传输电子。 在实施例中,阻挡层可以通过电子或电子和离子机制两者传输电荷,并且基本上不受湿度变化的影响。 阻挡层包括在聚合物链中共价键合作为重复单元的聚酯 - 共 - 酰亚胺,聚酯型聚异氰酸酯 - 共 - 酰亚胺或聚酰胺 - 共 - 酰亚胺,其中Ar 1和Ar 2分别表示四价或三价的芳族四羰基二酰亚胺基团 6至约20个碳原子的芳基,X是O,C(CF 3)2,S = O或SO 2。