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    • 3. 发明授权
    • Melt phase polyarylate process
    • 熔融相多芳基化工艺
    • US5070176A
    • 1991-12-03
    • US586181
    • 1990-09-21
    • Marc A. Strand
    • Marc A. Strand
    • C08G63/19C08G63/78C08G63/87
    • C08G63/19C08G63/78C08G63/87
    • Disclosed is a process for preparation of a polyarylate having a degree of polymerization of at least 50 by polymerizing an admixture comprised of 4-dialkylaminopyridine, an acid anhydride, bisphenol-A and a mixture of isophthalic acid and terephthalic acid by the steps of(1) subjecting the admixture to a pressure in the range of 500 to 1400 mm of Hg and a temperature in the range of 20.degree. to 150.degree. C. while maintaining a degree of polymerization of substantially 1.0,(2) subjecting the admixture to a pressure in the range of 500 to 1400 mm of Hg and a temperature in the range of 285.degree. to 350.degree. C. to achieve a degree of polymerization in the range of 2 to 7,(3) subjecting the admixture to a pressure in the range of 100 to 400 mm of Hg and a temperature in the range of 285.degree. to 350.degree. C. to achieve a degree of polymerization in the range of 7 to 15,(4) subjecting the admixture to a pressure in the range of 100 to 400 mm of Hg and a temperature in the range of 330.degree. to 400.degree. C. to achieve a degree of polymerization in the range of 7 to 15, and(5) subjecting the admixture to a pressure in the range of 10 to 75 mm of Hg and a temperature in the range of 330.degree. to 400.degree. C. to achieve an degree of polymerization of at least 50.
    • 公开了通过以下步骤制备聚合度为至少为50的多芳基化合物的方法:通过使(4-甲氧基苯基)丙烯酸酯与聚对苯二甲酸和对苯二甲酸的混合物聚合由4-二烷基氨基吡啶,酸酐,双酚A和间苯二甲酸的混合物组成的混合物 )使混合物的压力范围为500〜1400mm Hg,温度为20〜150℃,同时保持基本上为1.0的聚合度,(2)使混合物受压 在500至1400mm Hg的范围内,温度在285至350℃的范围内,以达到2至7范围内的聚合度,(3)将混合物的压力范围 为100〜400mm Hg,温度为285〜350℃,聚合度达到7〜15,(4)将混合物的压力范围为100〜 400毫米汞柱,温度在330度到400度之间 以达到7〜15范围内的聚合度,(5)将混合物的压力范围为10〜75mm Hg,温度在330〜400℃ 达到至少50的聚合度。