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1. 发明授权

US06953868B2 Oxyfunctionalization of polyolefins 有权
标题翻译：聚烯烃的氧官能化
公开(公告)号：US06953868B2
公开(公告)日：2005-10-11
申请号：US10831869
申请日：2004-04-26
申请人： Nicole K. Boaen , Marc A. Hillmyer , Stephen F. Hahn
发明人： Nicole K. Boaen , Marc A. Hillmyer , Stephen F. Hahn
IPC分类号： C08F8/06 , C07C31/18 , C08F138/00
CPC分类号： C08C19/02 , C08F8/06 , C08F210/16
摘要： The present invention is a method for oxyfunctionalizing, that is, introducing oxygen functionality to, a polyolefin such as polypropylene and poly(ethylene-alt-propylene). The polyolefin is contacted with an oxygen source such as a persulfate and catalytic amounts of a metal porphyrin complex under mild conditions to yield an oxyfunctionalized polymer that has a polydispersity that is very similar to that of the starting polymer.
摘要翻译：本发明是一种氧化官能化方法，即将聚氧乙烯（聚丙烯）和聚（亚乙基 - 高级 - 丙烯）等聚烯烃引入氧官能度。聚烯烃在温和条件下与氧源如过硫酸盐和催化量的金属卟啉络合物接触，得到具有与起始聚合物非常相似的多分散性的氧化官能化聚合物。

2. 发明授权

US09980503B2 Chewing gums and gum bases comprising multi-block copolymers 有权
公开(公告)号：US09980503B2
公开(公告)日：2018-05-29
申请号：US14003998
申请日：2012-03-09
申请人： Leslie D. Morgret , Michael S. Haas , Marc A. Hillmyer , Wilhelm Risse , Frank S. Bates , Mark T Martello , Sangwoo Lee
发明人： Leslie D. Morgret , Michael S. Haas , Marc A. Hillmyer , Wilhelm Risse , Frank S. Bates , Mark T Martello , Sangwoo Lee
IPC分类号： A23G4/08 , C08G63/66 , C08G81/00 , A23G4/12
CPC分类号： A23G4/08 , A23G4/123 , C08G63/66 , C08G81/00 , C12C12/00
摘要： Chewing gums and chewing gum bases which are cud-forming and chewable at mouth temperature contains a multi-block copolymer having at least two repeating sequences of at least two different polymeric blocks having at least three monomer units each. The multi-block copolymer optionally includes linking units and may be formulated to have non-covalent crosslinking between the copolymer chains. The multi-block copolymer is optionally plasticized with a compatible di-block copolymer to function as an elastomer system in the gum base. Characteristics of the multi-block copolymers can be selected to produce gum bases and chewing gums having desired properties. In some cases, chewed cuds formed from the gum bases may exhibit improved removability from environmental surfaces to which they may become undesirably attached.

3. 发明授权

US07714097B2 Polymer synthesis from macrocycles 有权
标题翻译：大分子合成聚合物
公开(公告)号：US07714097B2
公开(公告)日：2010-05-11
申请号：US11545092
申请日：2006-10-06
申请人： Donghui Zhang , William B. Tolman , Marc A. Hillmyer
发明人： Donghui Zhang , William B. Tolman , Marc A. Hillmyer
IPC分类号： C08G63/78 , C08G63/82 , C08G63/91
CPC分类号： C08G65/22 , C08G63/08 , C08G63/823
摘要： A synthetic route is provided to prepare poly(ω-hydroxycarboxylic acid) polymers via the ring-opening polymerization of ω-hydroxycarboxylic acid cyclic oligomers. The cyclic oligomers can be prepared directly from biorenewable sources, such as 3-hydroxypropionic acid. The method can be used to prepare high molecular weight polymers from the cyclic oligomers. Good molecular weight control can be obtained for both solution state and melt polymerizations.
摘要翻译：提供合成途径以通过ω-羟基羧酸环状低聚物的开环聚合制备聚（ω-羟基羧酸）聚合物。环状低聚物可以直接从生物可再生来源例如3-羟基丙酸制备。该方法可用于从环状低聚物制备高分子量聚合物。对于溶液状态和熔融聚合都可以获得良好的分子量控制。

4. 发明授权

US5880231A Synthesis of telechelic polymers using ruthenium and osmium carbene complexes 失效
标题翻译：使用钌和咔唑络合物合成遥爪聚合物
公开(公告)号：US5880231A
公开(公告)日：1999-03-09
申请号：US548445
申请日：1995-10-26
申请人： Robert H. Grubbs , SonBinh T. Nguyen , Marc A. Hillmyer
发明人： Robert H. Grubbs , SonBinh T. Nguyen , Marc A. Hillmyer
IPC分类号： B01J23/46 , B01J31/22 , C07C51/353 , C07C67/475 , C07F15/00 , C08F4/80 , C08F8/50 , C08F10/00 , C08F32/00 , C08F210/02 , C08G61/08 , C08G61/12 , C08F32/04
CPC分类号： B01J31/2265 , B01J31/24 , B01J31/2404 , C07C51/353 , C07C67/333 , C07C67/475 , C07F15/002 , C07F15/0046 , C08C19/08 , C08F10/00 , C08F32/00 , C08F8/50 , C08G61/08 , C08G61/128 , B01J2231/14 , B01J2231/543 , B01J23/462 , B01J23/466 , B01J2531/821 , B01J2531/825 , C07C2101/10 , C08C2019/09 , C08F210/02 , Y10S525/938
摘要： Disclosed are ruthenium and osmium carbene compounds which are stable in the presence of a variety of functional groups and which can be used to catalyze olefin metathesis reactions on unstrained cyclic and acyclic olefins. Specifically, the present invention relates to carbene compounds of the formula ##STR1## wherein: M is Os or Ru; R and R.sup.1 are independently selected from hydrogen and functional groups C.sub.2 -C.sub.20 alkenyl, C.sub.2 -C.sub.20 alkynyl, C.sub.1 -C.sub.20 alkyl, aryl, C.sub.1 -C.sub.20 carboxylate, C.sub.2 -C.sub.20 alkoxy, C.sub.2 -C.sub.20 alkenyloxy, C.sub.2 -C.sub.20 alkynyloxy, aryloxy, C.sub.2 -C.sub.20 alkoxycarbonyl, C.sub.1 -C.sub.20 alkylthio, C.sub.1 -C.sub.20 alkylsulfonyl or C.sub.1 -C.sub.20 alkylsulfinyl; each optionally substituted with C.sub.1 -C.sub.5 alkyl, a halogen, C.sub.1 -C.sub.5 alkoxy or with a phenyl group optionally substituted with a halogen, C.sub.1 -C.sub.5 alkyl or C.sub.1 -C.sub.5 alkoxy; X and X.sup.1 are independently selected from any anionic ligand; and L and L.sup.1 are each trialkyl phosphine ligands where at least one of the alkyl groups on the phosphine is a secondary alkyl or a cycloalkyl. A broad array of metathesis reactions are enabled including ring-opening metathesis polymerization of cyclic olefins, ring closing metathesis of acyclic dienes, cross metathesis involving at least one acyclic or unstrained cyclic olefin, and depolymerization of unsaturated polymers.
摘要翻译：公开了在各种官能团存在下稳定的钌和咔咔啉化合物，其可用于在未应变的环状和无环烯烃上催化烯烃复分解反应。具体地说，本发明涉及下式的卡宾化合物：其中：M是Os或Ru; R和R 1独立地选自氢和官能团C 2 -C 20烯基，C 2 -C 20炔基，C 1 -C 20烷基，芳基，C 1 -C 20羧酸酯，C 2 -C 20烷氧基，C 2 -C 20链烯氧基，C 2 -C 20炔氧基，芳氧基， C 2 -C 20烷氧基羰基，C 1 -C 20烷硫基，C 1 -C 20烷基磺酰基或C 1 -C 20烷基亚磺酰基; 每个任选被C 1 -C 5烷基，卤素，C 1 -C 5烷氧基或任选被卤素，C 1 -C 5烷基或C 1 -C 5烷氧基取代的苯基取代; X和X 1独立地选自任何阴离子配体; L和L1各自为三烷基膦配体，其中膦上的至少一个烷基是仲烷基或环烷基。复分解反应的范围广泛，包括环烯烃的开环易位聚合，无环二烯的闭环复分解，涉及至少一个无环或非应变的环烯烃的交叉复分解，以及不饱和聚合物的解聚。

5. 发明授权

US5290895A Polymerized dienes prepared by step propagation, condensation type polymerization of acyclic dienes 失效
标题翻译：通过步进增殖制备的聚合二烯，无环二烯的缩合型聚合
公开(公告)号：US5290895A
公开(公告)日：1994-03-01
申请号：US982059
申请日：1992-11-25
申请人： Kenneth B. Wagener , James M. Boncella , Robert P. Duttweiler , Marc A. Hillmyer , Jan G. Nel
发明人： Kenneth B. Wagener , James M. Boncella , Robert P. Duttweiler , Marc A. Hillmyer , Jan G. Nel
IPC分类号： C08F36/20 , C08G61/04
CPC分类号： C08F36/20
摘要： Novel polymerized dienes prepared by the step propagation, condensation type polymerization of acyclic dienes employing Lewis acid-free metal alkylidene complexes as catalysts.
摘要翻译：通过步进增殖制备的新型聚合二烯，使用不含路易斯酸的金属亚烷基络合物作为催化剂的无环二烯的缩合型聚合。

6. 发明申请

US20160229863A1 ISOSORBIDE-BASED POLYMETHACRYLATES 有权
标题翻译：异构体基聚异丁烯酸酯
公开(公告)号：US20160229863A1
公开(公告)日：2016-08-11
申请号：US15019777
申请日：2016-02-09
申请人： Marc A. Hillmyer , Theresa Reineke , James Gallagher
发明人： Marc A. Hillmyer , Theresa Reineke , James Gallagher
IPC分类号： C07D493/04 , C08F122/10
CPC分类号： C07D493/04 , C08F120/28 , C08F220/28 , C08F293/00 , C08F2438/03 , C08F2220/283 , C08F2220/1825
摘要： A monomer comprises the structure wherein R1 comprises H or a substituted hydrocarbyl or unsubstituted hydrocarbyl, and wherein R2 comprises H, a halide, or a substituted or unsubstituted (C1-C4) hydrocarbyl. A method comprises (a) reacting a dianhydrohexitol precursor having the structure with an acyl-group containing compound having the structure wherein R1 comprises H or a substituted hydrocarbyl or unsubstituted hydrocarbyl, and X comprises a halide, a hydroxyl group, or an acyl group to form an acylated dianhydrohexitol ester intermediate having the structure and (b) reacting the acylated dianhydrohexitol ester intermediate with an acrylic-based compound having the structure wherein R2 comprises H, a halide, or a substituted or unsubstituted (C1-C4) hydrocarbyl, and Y comprises a halide, a hydroxyl group, or an acyl group, to form a dianhydrohexitol-based monomer having the structure
摘要翻译：单体包括其中R 1包含H或取代的烃基或未取代烃基的结构，并且其中R 2包含H，卤化物或取代或未取代的（C 1 -C 4）烃基。一种方法包括（a）使具有结构的二脱水己糖醇前体与含酰基的化合物反应，其中R 1包含H或取代的烃基或未取代烃基，X包括卤化物，羟基或酰基，形成具有以下结构的酰化二氢己糖醇中间体和（b）使酰化的二氢己糖醇中间体与具有以下结构的丙烯酸类化合物反应：其中R2包含H，卤化物或取代或未取代的（C1-C4）烃基，Y 包括卤化物，羟基或酰基，以形成具有该结构的二脱水己糖醇单体

7. 发明申请

US20160194276A1 CATALYTIC ESTER DECARBONYLATION 有权
标题翻译：催化酯脱氮
公开(公告)号：US20160194276A1
公开(公告)日：2016-07-07
申请号：US14990308
申请日：2016-01-07
申请人： William Baker Tolman , Marc A. Hillmyer , Alex John , Levi Thomas Hogan
发明人： William Baker Tolman , Marc A. Hillmyer , Alex John , Levi Thomas Hogan
IPC分类号： C07C253/30 , B01J27/13 , B01J31/24 , C07C67/32 , C07C1/32
CPC分类号： C07C253/30 , B01J23/44 , B01J23/755 , B01J27/128 , B01J27/13 , B01J2531/824 , C07C1/207 , C07C17/361 , C07C67/317 , C07C67/32 , C07C201/12 , C07C2527/13 , C07C2531/24 , Y02P20/52 , C07C69/54 , C07C255/08 , C07C15/46 , C07C15/44 , C07C11/167 , C07C11/02 , C07C11/12 , C07C15/52 , C07C205/06 , C07C15/50 , C07C15/58 , C07C25/28
摘要： A process of preparing olefins of the formula (I) is described herein: with R1 being a substituted or unsubstituted (C1-C30)hydrocarbyl, and R2 being a substituted or unsubstituted (C1-C20)hydrocarbyl. The process includes reacting a compound of formula (II) wherein Ar is chosen from in the presence of a palladium-based catalyst and an organic solvent.A process of preparing olefins of the formula (III) is also described: with R3 being a substituted or unsubstituted (C1-C30)hydrocarbyl, R4 being a substituted or unsubstituted (C1-C20)hydrocarbyl, and R5 being a substituted or unsubstituted (C1-C30) hydrocarbyl. The process includes reacting a compound of formula (IV) wherein Ar is chosen from with a compound of formula (V) wherein Ar is chosen from in the presence of a palladium-based catalyst and an organic solvent.
摘要翻译：本文描述了制备式（I）烯烃的方法：其中R 1为取代或未取代的（C 1 -C 30）烃基，R 2为取代或未取代的（C 1 -C 20）烃基。该方法包括使式（II）化合物与其中Ar在钯基催化剂和有机溶剂存在下反应。还描述了制备式（III）的烯烃的方法：其中R3是取代或未取代的（C1-C30）烃基，R4是取代或未取代的（C1-C20）烃基，R5是取代或未取代的（ C1-C30）烃基。该方法包括使其中Ar选自与式（Ⅴ）化合物的式（Ⅳ）化合物反应，其中Ar选自钯基催化剂和有机溶剂。

8. 发明申请

US20140161931A1 CHEWING GUMS AND GUM BASES COMPRISING MULTI-BLOCK COPOLYMERS 有权
标题翻译：包括多嵌段共聚物的CHEWING GUMS和GUM BASES
公开(公告)号：US20140161931A1
公开(公告)日：2014-06-12
申请号：US14003998
申请日：2012-03-09
申请人： Leslie D. Morget , Michael S. Haas , Marc A. Hillmyer , Wilhelm Risse , Frank S. Bates , Mark T Martello , Sangwoo Lee
发明人： Leslie D. Morget , Michael S. Haas , Marc A. Hillmyer , Wilhelm Risse , Frank S. Bates , Mark T Martello , Sangwoo Lee
IPC分类号： A23G4/08
CPC分类号： A23G4/08 , A23G4/123 , C08G63/66 , C08G81/00 , C12C12/00
摘要： Chewing gums and chewing gum bases which are cud-forming and chewable at mouth temperature contains a multi-block copolymer having at least two repeating sequences of at least two different polymeric blocks having at least three monomer units each. The multi-block copolymer optionally includes linking units and may be formulated to have non-covalent crosslinking between the copolymer chains. The multi-block copolymer is optionally plasticized with a compatible di-block copolymer to function as an elastomer system in the gum base. Characteristics of the multi-block copolymers can be selected to produce gum bases and chewing gums having desired properties. In some cases, chewed cuds formed from the gum bases may exhibit improved removability from environmental surfaces to which they may become undesirably attached.
摘要翻译：咀嚼口香糖和口香糖咀嚼口香糖基质含有多嵌段共聚物，其具有至少两个具有至少三个单体单元的至少两个不同聚合物嵌段的重复序列。多嵌段共聚物任选地包括连接单元，并且可以配制成在共聚物链之间具有非共价交联。多嵌段共聚物任选地用相容的二嵌段共聚物增塑，用作胶基中的弹性体体系。可以选择多嵌段共聚物的特性来生产具有所需性质的胶基和口香糖。在一些情况下，由胶基形成的咀嚼嚼可以表现出从它们可能变得不期望地附着的环境表面的改进的可除去性。

9. 发明授权

US5849851A Romp of functionalized cyclic olefins using ruthenium and osmium carbene complexes 失效
标题翻译：使用钌和咔咔啉络合物对官能化环烯烃进行反应
公开(公告)号：US5849851A
公开(公告)日：1998-12-15
申请号：US969969
申请日：1997-11-13
申请人： Robert H. Grubbs , Sonbinh T. Nguyen , Marc A. Hillmyer
发明人： Robert H. Grubbs , Sonbinh T. Nguyen , Marc A. Hillmyer
IPC分类号： B01J23/46 , B01J31/22 , C07C51/353 , C07C67/475 , C07F15/00 , C08F4/80 , C08F8/50 , C08F10/00 , C08F32/00 , C08F210/02 , C08G61/08 , C08G61/12
CPC分类号： B01J31/2265 , B01J31/24 , B01J31/2404 , C07C51/353 , C07C67/333 , C07C67/475 , C07F15/002 , C07F15/0046 , C08C19/08 , C08F10/00 , C08F32/00 , C08F8/50 , C08G61/08 , C08G61/128 , B01J2231/14 , B01J2231/543 , B01J23/462 , B01J23/466 , B01J2531/821 , B01J2531/825 , C07C2101/10 , C08C2019/09 , C08F210/02 , Y10S525/938
摘要： Disclosed are ruthenium and osmium carbene compounds which are stable in the presence of a variety of functional groups and which can be used to catalyze olefin metathesis reactions on unstrained cyclic and acyclic olefins. Specifically, the present invention relates to carbene compounds of the formula ##STR1## wherein: M is Os or Ru; R and R.sup.1 are independently selected from hydrogen and functional groups C.sub.2 -C.sub.20 alkenyl, C.sub.2 -C.sub.20 alkynyl, C.sub.1 -C.sub.20 alkyl, aryl, C.sub.1 -C.sub.20 carboxylate, C.sub.2 -C.sub.20 alkoxy, C.sub.2 -C.sub.20 alkenyloxy, C.sub.2 -C.sub.20 alkynyloxy, aryloxy, C.sub.2 -C.sub.20 alkoxycarbonyl, C.sub.1 -C.sub.20 alkylthio, C.sub.1 -C.sub.20 alkylsulfonyl or C.sub.1 -C.sub.20 alkylsulfinyl; each optionally substituted with C.sub.1 -C.sub.5 alkyl, a halogen, C.sub.1 -C.sub.5 alkoxy or with a phenyl group optionally substituted with a halogen, C.sub.1 -C.sub.5 alkyl or C.sub.1 -C.sub.5 alkoxy; X and X.sup.1 are independently selected from any anionic ligand; and L and L.sup.1 are each trialkyl phosphine ligands where at least one of the alkyl groups on the phosphine is a secondary alkyl or a cycloalkyl. A broad array of metathesis reactions are enabled including ring-opening metathesis polymerization of cyclic olefins, ring closing metathesis of acyclic dienes, cross metathesis involving at least one acyclic or unstrained cyclic olefin, and depolymerization of unsaturated polymers.
摘要翻译：公开了在各种官能团存在下稳定的钌和咔咔啉化合物，其可用于在未应变的环状和无环烯烃上催化烯烃复分解反应。具体地说，本发明涉及下式的卡宾化合物：其中：M是Os或Ru; R和R 1独立地选自氢和官能团C 2 -C 20烯基，C 2 -C 20炔基，C 1 -C 20烷基，芳基，C 1 -C 20羧酸酯，C 2 -C 20烷氧基，C 2 -C 20链烯氧基，C 2 -C 20炔氧基，芳氧基， C 2 -C 20烷氧基羰基，C 1 -C 20烷硫基，C 1 -C 20烷基磺酰基或C 1 -C 20烷基亚磺酰基; 每个任选被C 1 -C 5烷基，卤素，C 1 -C 5烷氧基或任选被卤素，C 1 -C 5烷基或C 1 -C 5烷氧基取代的苯基取代; X和X 1独立地选自任何阴离子配体; L和L1各自为三烷基膦配体，其中膦上的至少一个烷基是仲烷基或环烷基。复分解反应的范围广泛，包括环烯烃的开环易位聚合，无环二烯的闭环复分解，涉及至少一个无环或非应变的环烯烃的交叉复分解，以及不饱和聚合物的解聚。

10. 发明授权

US06991852B2 Silica-based materials and methods 有权
公开(公告)号：US06991852B2
公开(公告)日：2006-01-31
申请号：US10385904
申请日：2003-03-11
申请人： Peter W. Carr , Marc A. Hillmyer , Huqun Liu , Hao Luo , Lianjia Ma , Brian C. Trammell
发明人： Peter W. Carr , Marc A. Hillmyer , Huqun Liu , Hao Luo , Lianjia Ma , Brian C. Trammell
IPC分类号： B32B9/04
CPC分类号： B82Y30/00 , B01D15/322 , B01D15/325 , B01D15/361 , B01D15/3833 , B01J20/28097 , B01J20/286 , B01J20/287 , B01J20/3204 , B01J20/3219 , B01J20/3227 , B01J20/327 , B01J20/3272 , B01J20/3282 , B32B9/04 , B82Y40/00 , C01P2006/10 , C09C1/3081 , Y10T428/2962 , Y10T428/2995 , Y10T428/2998 , Y10T428/31612 , Y10T428/31663
摘要： A silica-based material that includes a silica-based substrate and a polymerized organic material disposed thereon. The polymerized organic material is made from reactive organic moieties bonded to the silica-based substrate.

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