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    • 2. 发明授权
    • Recovery process in a pulp mill
    • 纸浆厂的回收过程
    • US5980717A
    • 1999-11-09
    • US999430
    • 1997-12-29
    • Roland PudasMagnus LinstenRoy Hammer-OlsenBjorn SvedinIngrid Velander
    • Roland PudasMagnus LinstenRoy Hammer-OlsenBjorn SvedinIngrid Velander
    • D21C11/00D21C11/06B01D59/42
    • D21C11/066D21C11/005
    • A substantial and increasing problem with the pulping chemical recovery system, is the presence of chloride and potassium in the spent liquor entering the recovery boiler. Chloride and potassium increase the stickiness of carryover deposits and dust particles to the recovery boiler tubes, which accelerate fouling and plugging in the upper part of the recovery boiler. The present invention relates to a process by which the content of potassium ions in a recovery system for pulping chemicals can be reduced. The process comprises bringing spent liquor to a recovery boiler, burning said spent liquor, collecting precipitator dust formed, forming a solution by dissolving the precipitator dust in a liquid, where the solution of precipitator dust is subjected to a treatment with an inorganic ion exchange material in order to remove at least a part of the potassium therein.
    • 制浆化学回收系统的一个重大和日益严重的问题是进入回收锅炉的废液中存在氯化物和钾。 氯化钾和钾离子增加了回收沉积物和灰尘颗粒对回收锅炉管的粘性,加速了回收锅炉上部的结垢和堵塞。 本发明涉及一种可以减少用于制浆化学品的回收系统中的钾离子含量的方法。 该方法包括将废液倒入回收锅炉中,燃烧废液,收集除尘器灰尘,通过将除尘器粉尘溶解在液体中形成溶液,将沉淀粉尘的溶液用无机离子交换材料进行处理 以除去其中至少一部分钾。
    • 4. 发明授权
    • Process for treating oxygen delignified pulp using an organic peracid or
salt, complexing agent and peroxide bleach sequence
    • 使用有机过酸或盐,络合剂和过氧化物漂白剂序列处理氧脱木素的方法
    • US5785812A
    • 1998-07-28
    • US436243
    • 1995-05-17
    • Magnus LinstenJiri BastaAnn-Sofie Hallstrom
    • Magnus LinstenJiri BastaAnn-Sofie Hallstrom
    • D21C20060101D21C9/10D21C9/153D21C9/16
    • D21C9/153D21C9/1042D21C9/1057D21C9/163D21C9/166
    • A process for delignifying and bleaching lignocellulose-containing pulp, in which the pulp is delignified with a peracid or a salt thereof, treated with a complexing agent, and subsequently bleached with a chlorine-free bleaching agent. Suitably delignification is carried out with the strongly oxidizing peracetic acid, giving a considerable increase in brightness and a considerable reduction of the kappa number after bleaching with a chlorine-free bleaching agent comprising at least one of a peroxide-containing compound, ozone or sodium dithionite, or optional sequences or mixtures thereof. The brightness increasing effect is highly selective, i.e. the viscosity of the pulp is maintained to a comparatively great extent. Both the delignification and the treatment with a complexing agent are advantageously carried out at a close to neutral pH, thus minimizing the need of pH adjustment and making it possible to use spent bleach liquor internally, e.g. for washing the pulp. By final bleaching with ozone and hydrogen peroxide it is possible to produce softwood pulps having a brightness exceeding 90% ISO, and to remove practically all lignin in the pulp while maintaining sufficient pulp strength.
    • PCT No.PCT / SE93 / 01019 Sec。 371日期1995年5月17日 102(e)日期1995年5月17日PCT 1993年11月25日PCT公布。 第WO94 / 12721号公报 日期1994年6月9日一种用于脱木素纤维素的纸浆脱木素和脱色的方法,其中用络合剂处理纸浆与过酸或其盐脱木质,随后用无氯漂白剂漂白。 用强氧化性过乙酸进行合适的脱木质素,可以显着提高亮度,并且用含有过氧化物的化合物,臭氧或连二亚硫酸钠中的至少一种的无氯漂白剂漂白后显着降低卡伯值 ,或任选的序列或其混合物。 亮度增加效果是高选择性的,即纸浆的粘度保持在较大程度上。 螯合剂的脱木质素和处理都有利地在接近中性pH下进行,从而最小化pH调节的需要,并且可以在内部使用废漂白液,例如, 用于清洗纸浆。 通过用臭氧和过氧化氢进行最终漂白,可以生产亮度超过90%ISO的软木纸浆,并且几乎除去纸浆中的所有木质素,同时保持足够的纸浆强度。