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1. 发明公开

EP0915753A4 SILOXANE-MODIFIED ADHESIVE/ADHEREND SYSTEMS 失效
标题翻译：硅改性粘合剂/粘合剂表面SYSTEM
公开(公告)号：EP0915753A4
公开(公告)日：2001-04-25
申请号：EP97911949
申请日：1997-05-05
申请人： AMERON INT CORP , MOWRER NORMAN R , KANE JOHN F , HULL COLIN G
发明人： MOWRER NORMAN R , KANE JOHN F , HULL COLIN G
IPC分类号： B29C65/52 , B32B7/12 , B32B15/04 , B32B27/08 , C09J7/02 , C09J11/00 , C09J163/00 , C09J183/04 , C09J183/06 , C09J183/10
CPC分类号： B32B27/08 , B32B7/12 , B32B27/283 , B32B2383/00 , B32B2405/00 , C08L83/00 , C09J7/22 , C09J7/38 , C09J163/00 , C09J183/10 , Y10T428/31663
摘要： Adhesive/adherend systems of this invention comprise a siloxane-modified adhesive component and a siloxane-modified adherend component. The siloxane-modified adhesive component is prepared by combining an epoxy resin with an organosilane ingredient, a polysiloxane resin, an amine hardener, an organometallic catalyst, a base catalyst, and any thickener and extender pigment. The siloxane-modified adherend component is prepared using a polysiloxane resin and may also contain other resins such epoxy, phenolic, polyester, vinyl ester, polyurethane, polyamide, melamine, furan, acrylate, thermoplastic polyvinyl chloride, polyethylene, polycarbonate, ABS, polystyrene, ethylene vinyl acetate, polyvinyl acetate, polyamide, and polypropylene resins. When placed into contact with one another, the siloxane groups in the siloxane-modified adhesive and siloxane-modified adherend components form Si-O-Si bonds between themselves to form an attachment force that both occurs at ambient temperature within a reasonable amount of time, and that is greater than otherwise possible using adhesive/adherend systems having unmodified adhesive and/or adherend components.

2. 发明公开

EP0915753A1 SILOXANE-MODIFIED ADHESIVE/ADHEREND SYSTEMS 失效
标题翻译：硅氧烷改性剂KLEBSTOFF- /KLEBEFLÄCHE-SYSTEM
公开(公告)号：EP0915753A1
公开(公告)日：1999-05-19
申请号：EP97911949.0
申请日：1997-05-05
申请人： AMERON INTERNATIONAL CORPORATION , Mowrer, Norman R. , Kane, John F. , Hull, Colin G.
发明人： MOWRER, Norman R. , KANE, John F. , HULL, Colin G.
IPC分类号： B29C65 , B32B7 , B32B15 , B32B27 , C09J7 , C09J163 , C09J183
CPC分类号： B32B27/08 , B32B7/12 , B32B27/283 , B32B2383/00 , B32B2405/00 , C08L83/00 , C09J7/22 , C09J7/38 , C09J163/00 , C09J183/10 , Y10T428/31663
摘要： Adhesive/adherend systems of this invention comprise a siloxane-modified adhesive component and a siloxane-modified adherend component. The siloxane-modified adhesive component is prepared by combining an epoxy resin with an organosilane ingredient, a polysiloxane resin, an amine hardener, an organometallic catalyst, a base catalyst, and any thickener and extender pigment. The siloxane-modified adherend component is prepared using a polysiloxane resin and may also contain other resins such epoxy, phenolic, polyester, vinyl ester, polyurethane, polyamide, melamine, furan, acrylate, thermoplastic polyvinyl chloride, polyethylene, polycarbonate, ABS, polystyrene, ethylene vinyl acetate, polyvinyl acetate, polyamide, and polypropylene resins. When placed into contact with one another, the siloxane groups in the siloxane-modified adhesive and siloxane-modified adherend components form Si-O-Si bonds between themselves to form an attachment force that both occurs at ambient temperature within a reasonable amount of time, and that is greater than otherwise possible using adhesive/adherend systems having unmodified adhesive and/or adherend components.
摘要翻译：本发明的粘合剂/粘附体系包含硅氧烷改性的粘合剂组分和硅氧烷改性的粘合剂组分。通过将环氧树脂与有机硅烷成分，聚硅氧烷树脂，胺硬化剂，有机金属催化剂，碱催化剂和任何增稠剂和增量颜料组合而制备硅氧烷改性的粘合剂组分。使用聚硅氧烷树脂制备硅氧烷改性的被粘物成分，还可以含有环氧树脂，酚醛树脂，聚酯，乙烯基酯，聚氨酯，聚酰胺，三聚氰胺，呋喃，丙烯酸酯，热塑性聚氯乙烯，聚乙烯，聚碳酸酯，ABS，聚苯乙烯，乙烯醋酸乙烯酯，聚乙酸乙烯酯，聚酰胺和聚丙烯树脂。当彼此接触时，硅氧烷改性的粘合剂中的硅氧烷基团和硅氧烷改性的被粘物组分在它们之间形成Si-O-Si键，以形成两者都在合适的时间内在环境温度下发生的附着力，并且使用具有未改性粘合剂和/或被粘物组分的粘合剂/被粘物体系大于另外可能的情况。

3. 发明申请

WO1998032792A1 EPOXY-POLYSILOXANE POLYMER COMPOSITION 审中-公开
标题翻译：环氧聚硅氧烷聚合物组合物
公开(公告)号：WO1998032792A1
公开(公告)日：1998-07-30
申请号：PCT/US1997007594
申请日：1997-05-06
申请人： AMERON INTERNATIONAL CORPORATION , MOWRER, Norman, R. , FOSCANTE, Raymond, E. , ROJAS, J., Luis
发明人： AMERON INTERNATIONAL CORPORATION
IPC分类号： C08K03/20
CPC分类号： C08G59/4085 , C08G77/12 , C08G77/14 , C08G77/16 , C08G77/18 , C08G77/26 , C08G77/46 , C08G77/70 , C08L63/00 , C08L83/04 , C09D163/00 , C09D183/04 , C08L83/00 , C08L2666/14 , C08L2666/28
摘要： Epoxy-polysiloxane polymer compositions of this invention are prepared by combining a resin component with a hardener component. The resin component comprises a non-aromatic epoxy rein ingredient and a polysiloxyne ingredient. The hardener component comprises an amine and optionally an organotin catalyst. The composition can also include aggregates, pigments, and other additives depending on the particular end use. The composition is prepared using a sufficient amount of water to promote hydrolysis of the polysiloxane and the polycondensation of the silanols produced by such hydrolysis. In its cured form, the epoxy-polysiloxane composition exists as a uniformly dispersed arrangement of linear epoxy chain fragments that are cross-linked with a continuous polysiloxane polymer chain, thereby forming a non-interpenetrating polymer network chemical structure that has substantial advantages over conventional epoxy systems. Protective coatings formed from such compositions exhibit excellent weatherability in sunlight, and superior chemical and corrosion resistance after curing.
摘要翻译：本发明的环氧聚硅氧烷聚合物组合物通过将树脂组分与硬化剂组分组合来制备。树脂组分包括非芳族环氧树脂成分和聚硅氧烷成分。固化剂组分包括胺和任选的有机锡催化剂。组合物还可以包括聚集体，颜料和其它添加剂，这取决于具体的最终用途。使用足够量的水制备组合物以促进聚硅氧烷的水解和通过这种水解产生的硅烷醇的缩聚。在其固化形式中，环氧 - 聚硅氧烷组合物作为与连续聚硅氧烷聚合物链交联的线性环氧链片段的均匀分散布置存在，从而形成相对于常规环氧树脂具有显着优点的非互穿聚合物网络化学结构系统。由这种组合物形成的保护涂层在阳光下表现出优异的耐候性，并且在固化后具有优异的耐化学腐蚀性。

4. 发明申请

WO9855056A8 HALOGENATED RESIN COMPOSITIONS 审中-公开
标题翻译：羟基化树脂组合物
公开(公告)号：WO9855056A8
公开(公告)日：2000-02-17
申请号：PCT/US9810421
申请日：1998-05-21
申请人： AMERON INT CORP , MOWRER NORMAN R , LINZ RHONDA L , GASMENA ROLAND L , ESPINOZA RUDY , STANLEY CHRISTINE L , DHALIWAL PRITAM S
发明人： MOWRER NORMAN R , LINZ RHONDA L , GASMENA ROLAND L , ESPINOZA RUDY , STANLEY CHRISTINE L , DHALIWAL PRITAM S
IPC分类号： C08L83/08 , C08G77/24 , C08G77/385 , C08G77/42 , C08G77/442 , C08L83/04 , C08L83/10 , C08L101/00 , C09D183/04 , C09D183/10 , A61F5/44
CPC分类号： C08G77/442 , C08G77/42
摘要： Halogenated resin compositions are prepared without using halogen acids by combining at least one silicone intermediate, with an optional silane, an organic halogen-containing ingredient having functional groups selected from the group consisting of hydroxy, amine, and carboxyl groups, and a resin selected from the group consisting of hydroxy- and epoxy-functional resins. One or more amine curing agent and/or catalyst selected from the group consisting of organometallic compounds, acids, bases and mixtures thereof can optionally be added to facilitate ambient temperature curing of the resulting composition. The combined ingredients undergo hydrolysis reactions to form a halogenated organooxysilane that condenses to form a cross-linked halogenated polysiloxane composition. The resin also reacts with the condensing halogenated organooxysilane to introduce itself into the cross-linked halogenated polysiloxane and, thereby forming the halogenated polysiloxane resin composition. The composition is prepare without using an inorganic halogen acid, and is fully-cured at ambient temperature by exposure to atmospheric moisture to form a protective film, or alternatively a composite (10), having improved properties of chemical, abrasion, corrosion, weather, flame, and ultraviolet resistance.
摘要翻译：通过将至少一种硅氧烷中间体与任选的硅烷，含有选自羟基，胺和羧基的官能团的有机含卤素成分和选自羟基，胺和羧基的树脂组合而制备卤化树脂组合物，由羟基和环氧官能树脂组成的组。可以任选地加入一种或多种选自有机金属化合物，酸，碱和其混合物的胺固化剂和/或催化剂以促进所得组合物的环境温度固化。组合的成分经历水解反应以形成冷凝形成交联卤代聚硅氧烷组合物的卤代有机氧基硅烷。树脂也与缩合的卤代有机氧基硅烷反应，将其自身引入到交联的卤代聚硅氧烷中，从而形成卤化聚硅氧烷树脂组合物。组合物是在不使用无机卤酸的情况下制备的，并且在环境温度下通过暴露于大气中的水分而完全固化以形成保护膜，或者复合材料（10），其具有改善的化学，耐磨，腐蚀，天气，火焰和耐紫外线性。

5. 发明申请

WO2012100140A1 ONE COMPONENT POLYSILOXANE COATING COMPOSITIONS AND RELATED COATED SUBSTRATES 审中-公开
标题翻译：一种组分聚硅氧烷涂料组合物和相关涂层基材
公开(公告)号：WO2012100140A1
公开(公告)日：2012-07-26
申请号：PCT/US2012/021994
申请日：2012-01-20
申请人： PPG INDUSTRIES OHIO, INC. , MOWRER, Norman, R. , MCCARTHY, James, E.
发明人： MOWRER, Norman, R. , MCCARTHY, James, E.
IPC分类号： C09D183/04
CPC分类号： C09D183/04 , C08G77/16 , C08G77/18
摘要： Disclosed are one-component low temperature, moisture curable, storage stable coating compositions that include a silanol-functional silicone; an alkoxy-functional silicone; a flexibilizer comprising a reaction product of two or more reactants; and a curing agent selected from amines, aminosilanes, ketimines, aldimines, and combinations thereof. Also disclosed are substrates at least partially coated with a coating deposited from such a composition and methods for coating substrates with such compositions.
摘要翻译：公开了单组分低温，湿固化，储存稳定的涂料组合物，其包括硅烷醇官能的硅氧烷; 烷氧基官能的硅氧烷; 包含两种或更多种反应物的反应产物的增韧剂; 和选自胺，氨基硅烷，酮亚胺，醛亚胺及其组合的固化剂。还公开了至少部分地涂覆有由这种组合物沉积的涂层的基材和用这种组合物涂布基材的方法。

6. 发明申请

WO2010135730A3 ONE-COMPONENT EPOXY COATING COMPOSITIONS 审中-公开
标题翻译：单组分环氧涂料组合物
公开(公告)号：WO2010135730A3
公开(公告)日：2011-01-13
申请号：PCT/US2010035915
申请日：2010-05-24
申请人： PPG IND OHIO INC , MOWRER NORMAN R , SHETH KAMLESH
发明人： MOWRER NORMAN R , SHETH KAMLESH
IPC分类号： C09D163/00 , C08G59/40 , C09D183/04
CPC分类号： C08G59/4042 , C08G77/14 , C08G77/16 , C08G2650/50 , C09D163/00 , C09D183/04 , C08L83/00 , C08L2666/22
摘要： Disclosed are high solids, one-component, storage stable coating compositions that include an epoxy resin comprising more than one 1,2-epoxy groups per molecule; a hydrocarbon compound having a softening point of from 50°C to 140°C; an alkoxy-functional and/or silanol-functional silicone; and a ketimine curing agent comprising a reaction product of reactants comprising a polyalkyldiamine component and a ketone component. Also disclosed are substrates at least partially coated with a coating deposited from such composition and methods for coating substrates with such compositions.
摘要翻译：公开了高固体，单组分，储存稳定的涂料组合物，其包括每分子包含多于一个1,2-环氧基团的环氧树脂; 软化点为50℃至140℃的烃化合物; 烷氧基官能和/或硅烷醇官能的硅氧烷; 和酮亚胺固化剂，其包含包含聚烷基二胺组分和酮组分的反应物的反应产物。还公开了至少部分地涂覆有由这种组合物沉积的涂层的基材和用这种组合物涂布基材的方法。

7. 发明申请

WO1996033238A1 PHENOLIC RESIN COMPOSITIONS WITH IMPROVED IMPACT RESISTANCE 审中-公开
标题翻译：酚醛树脂组合物具有改善的耐冲击性
公开(公告)号：WO1996033238A1
公开(公告)日：1996-10-24
申请号：PCT/US1996005454
申请日：1996-04-19
申请人： AMERON INTERNATIONAL, INC. , KANE, John, F. , MOWRER, Norman, R.
发明人： AMERON INTERNATIONAL, INC.
IPC分类号： C08L61/10
CPC分类号： F16D69/025 , C08G77/42 , C08L61/06 , C08L83/04 , Y10S525/903 , C08L83/00
摘要： Phenolic siloxane composition are prepared by 1) combining phenol with an aldehyde and an alkoxy or silanol-functional silicone intermediate, 2) combining a phenolic novolac resin with a formaldehyde donor and an alkoxy or silanol-functional silicone intermediate or 3) combining a phenolic resole resin with an alkoxy or silanol-functional silicone intermediate. Catalysts to facilitate the formation of a phenolic resin, the condensation of the phenolic resin and the hydrolysis and/or condensation of the silicone intermediate can optionally be added. The resulting composition comprises an IPN of siloxane polymers and phenolic polymers and has flame, heat and chemical resistance equal to or exceeding conventional phenolic resins and improved impact resistance, tensile strength, flexural modulus and density.
摘要翻译：酚醛硅氧烷组合物通过以下方法制备：1）将酚与醛和烷氧基或硅烷醇官能的硅氧烷中间体结合，2）将酚醛清漆树脂与甲醛供体和烷氧基或硅烷醇官能的硅氧烷中间体组合，或3）将酚醛树脂具有烷氧基或硅烷醇官能的硅氧烷中间体的树脂。可以任选地加入促进酚醛树脂形成的催化剂，酚醛树脂的缩合和硅氧烷中间体的水解和/或缩合。所得组合物包含硅氧烷聚合物和酚醛聚合物的IPN，并且具有等于或超过常规酚醛树脂的火焰，耐热和耐化学腐蚀性，以及改善的耐冲击性，拉伸强度，弯曲模量和密度。

8. 发明申请

WO2010135730A2 ONE-COMPONENT EPOXY COATING COMPOSITIONS 审中-公开
标题翻译：单组分环氧涂料组合物
公开(公告)号：WO2010135730A2
公开(公告)日：2010-11-25
申请号：PCT/US2010/035915
申请日：2010-05-24
申请人： PPG INDUSTRIES OHIO, INC. , MOWRER, Norman, R. , SHETH, Kamlesh
发明人： MOWRER, Norman, R. , SHETH, Kamlesh
IPC分类号： C09D163/00 , C09D183/04 , C08G59/40
CPC分类号： C08G59/4042 , C08G77/14 , C08G77/16 , C08G2650/50 , C09D163/00 , C09D183/04 , C08L83/00 , C08L2666/22
摘要： Disclosed are high solids, one-component, storage stable coating compositions that include an epoxy resin comprising more than one 1,2-epoxy groups per molecule; a hydrocarbon compound having a softening point of from 50°C to 140°C; an alkoxy-functional and/or silanol-functional silicone; and a ketimine curing agent comprising a reaction product of reactants comprising a polyalkyldiamine component and a ketone component. Also disclosed are substrates at least partially coated with a coating deposited from such composition and methods for coating substrates with such compositions.
摘要翻译：公开了高固体，单组分，储存稳定的涂料组合物，其包括每分子包含多于一个1,2-环氧基团的环氧树脂; 软化点为50℃至140℃的烃化合物; 烷氧基官能和/或硅烷醇官能的硅氧烷; 和酮亚胺固化剂，其包含包含聚烷基二胺组分和酮组分的反应物的反应产物。还公开了至少部分地涂覆有由这种组合物沉积的涂层的基材和用这种组合物涂布基材的方法。

9. 发明申请

WO2006031891A3 FAST-CURING MODIFIED SILOXANE COMPOSITIONS 审中-公开
标题翻译：快速固化改性硅氧烷组合物
公开(公告)号：WO2006031891A3
公开(公告)日：2006-05-11
申请号：PCT/US2005032755
申请日：2005-09-13
申请人： AMERON INT CORP , GOMMANS LOUIE HERMAN , MOWRER NORMAN R , SAKUGAWA HARUJI , BAVIN MICHAEL NORMAN , CHU SHU YI , CONSTABLE KAREN TISHA
发明人： GOMMANS LOUIE HERMAN , MOWRER NORMAN R , SAKUGAWA HARUJI , BAVIN MICHAEL NORMAN , CHU SHU YI , CONSTABLE KAREN TISHA
IPC分类号： C08K5/09
CPC分类号： C08L83/10 , C08K5/0025 , C08K5/544 , C08L33/14 , C08L63/00 , C09D183/04 , C09D183/06 , C08L2666/14 , C08L2666/04
摘要： Fast-curing modified siloxane compositions comprise; (1) an alkoxy- or silanol-functional silicone intermediate, (2) at least one amine reactive ingredient selected from the group consisting of acetoacetate-functional ingredients, acrylate-functional ingredients, and mixtures thereof, (3) an epoxy-functional ingredient, (4) a curing agent selected from the group consisting of amines, aminosilanes, ketimines, aldimines and mixtures thereof, and (5) water. Other ingredients useful in forming fast-curing modified siloxane compositions of this invention include silanes, organometallic catalysts, solvents, pigments, fillers and modifying agents. The above-identified ingredients are combined and reacted to form a fully cured protective film comprising a cross-linked enamine polysiloxane and/or acrylate polysiloxane chemical structure in a reduced amount of time when compared to conventional epoxy siloxane compositions.
摘要翻译：快速固化的改性硅氧烷组合物包含：（1）烷氧基或硅烷醇官能有机硅中间体，（2）至少一种选自乙酰乙酸酯官能成分，丙烯酸酯官能成分及其混合物的胺反应性成分，（3）环氧官能成分（4）选自胺，氨基硅烷，酮亚胺，醛亚胺及其混合物的固化剂，和（5）水。可用于形成本发明的快速固化改性硅氧烷组合物的其它成分包括硅烷，有机金属催化剂，溶剂，颜料，填料和改性剂。与常规环氧硅氧烷组合物相比，上述成分组合并反应以形成包含交联的烯胺聚硅氧烷和/或丙烯酸酯聚硅氧烷化学结构的完全固化的保护膜，与传统的环氧硅氧烷组合物相比，所述保护膜的使用时间减少。

10. 发明申请

WO2006031891A2 FAST-CURING MODIFIED SILOXANE COMPOSITIONS 审中-公开
标题翻译：快速固化改性硅氧烷组合物
公开(公告)号：WO2006031891A2
公开(公告)日：2006-03-23
申请号：PCT/US2005/032755
申请日：2005-09-13
申请人： AMERON INTERNATIONAL CORPORATION , GOMMANS, Louie, Herman , MOWRER, Norman, R. , SAKUGAWA, Haruji , BAVIN, Michael, Norman , CHU, Shu, Yi , CONSTABLE, Karen, Tisha
发明人： GOMMANS, Louie, Herman , MOWRER, Norman, R. , SAKUGAWA, Haruji , BAVIN, Michael, Norman , CHU, Shu, Yi , CONSTABLE, Karen, Tisha
IPC分类号： C08K5/09
CPC分类号： C08L83/10 , C08K5/0025 , C08K5/544 , C08L33/14 , C08L63/00 , C09D183/04 , C09D183/06 , C08L2666/14 , C08L2666/04
摘要： Fast-curing modified siloxane compositions comprise; (1) an alkoxy- or silanol-functional silicone intermediate, (2) at least one amine reactive ingredient selected from the group consisting of acetoacetate-functional ingredients, acrylate-functional ingredients, and mixtures thereof, (3) an epoxy-functional ingredient, (4) a curing agent selected from the group consisting of amines, aminosilanes, ketimines, aldimines and mixtures thereof, and (5) water. Other ingredients useful in forming fast-curing modified siloxane compositions of this invention include silanes, organometallic catalysts, solvents, pigments, fillers and modifying agents. The above-identified ingredients are combined and reacted to form a fully cured protective film comprising a cross-linked enamine polysiloxane and/or acrylate polysiloxane chemical structure in a reduced amount of time when compared to conventional epoxy siloxane compositions.
摘要翻译：快速固化的改性硅氧烷组合物包含：（1）烷氧基或硅烷醇官能的硅氧烷中间体，（2）至少一种选自乙酰乙酸酯官能的成分，丙烯酸酯官能的成分及其混合物的胺活性成分，（3）环氧官能的成分，（4）选自胺，氨基硅烷，酮亚胺，醛亚胺及其混合物的固化剂，和（5）水。用于形成本发明的快速固化改性硅氧烷组合物的其它成分包括硅烷，有机金属催化剂，溶剂，颜料，填料和改性剂。当与常规环氧硅氧烷组合物相比时，将上述成分组合并反应以形成包含交联的烯胺聚硅氧烷和/或丙烯酸酯聚硅氧烷化学结构的完全固化的保护膜，所述化学结构在减少的时间内。

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