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    • 4. 发明申请
    • POLYMER COMPOSITION, PROCESS FOR PRODUCING THE POLYMER COMPOSITION, AND MOLDED ARTICLES FOR AUTOMOBILE EXTERIOR TRIM
    • 聚合物组合物,生产聚合物组合物的方法和用于汽车外部修剪的模制制品
    • WO2004104087A3
    • 2006-04-20
    • PCT/JP2004001604
    • 2004-02-13
    • MITSUI DU PONT POLYCHEMICALNAKATA KAZUYUKITAKEDA NORIHIKOMAEDA TOSHIYUKIWALSH DAVID JAMESBENDLER HERBERT VERNON
    • NAKATA KAZUYUKITAKEDA NORIHIKOMAEDA TOSHIYUKIWALSH DAVID JAMESBENDLER HERBERT VERNON
    • C08L23/08C08L23/12C08L23/14
    • C08L23/0846C08L23/12C08L23/142C08L2023/42C08L2666/06
    • The partially cross-linked polymer composition of the present invention is obtainable by dynamically heat-treating: 95 to 50 % by weight of a resin (A) comprising an ethylene copolymer containing 5 to 48 % by weight of units derived from at least one monomer selected from vinyl acetate, (meth)acrylic acid, (meth)acrylate ester, glycidyl (meth)acrylate and carbon monoxide, and 5 to 50 % by weight of a resin (B) having a melt viscosity (JAI 7-1991) at 180oC of over 10,000 mPa·Es and comprising a two or more-component propylene copolymer containing 0.1 to 20 % by mol of units derived from a-olefins other than propylene, or a blend of the two or more-component propylene copolymer and a propylene homopolymer in the presence of an organic peroxide (C) in an amount of from 0.001 to 4 parts by weight based on 100 parts by weight of the total amount of the resins (A) and (B). The invention can provide the polymer compositions having excellent fluidity and productivity, which allow to produce molded articles with heat resistance, adhesion with paint, tensile strength, flexibility, stress crack resistance, and RF weldability, such as molded articles for automobile exterior trim, and can provide the process for producing the polymer compositions.
    • 本发明的部分交联聚合物组合物可通过动态热处理获得:95至50重量%的包含乙烯共聚物的树脂(A),其含有5-48重量%的衍生自至少一种单体的单元 选自乙酸乙烯酯,(甲基)丙烯酸,(甲基)丙烯酸酯,(甲基)丙烯酸缩水甘油酯和一氧化碳,以及5〜50重量%的熔融粘度(JAI 7-1991)的树脂(B) 180℃,超过10,000mPa·Es,并且包含含有0.1至20摩尔%的来自除丙烯之外的α-烯烃的单元的两种或多种组分丙烯共聚物,或两种或多种组分丙烯共聚物与丙烯的共混物 在有机过氧化物(C)的存在下,基于100重量份的树脂(A)和(B)的总量,其量为0.001至4重量份。 本发明可以提供具有优异的流动性和生产率的聚合物组合物,其能够生产具有耐热性,与涂料粘附的模制品,拉伸强度,柔韧性,抗应力开裂性和RF可焊性,例如用于汽车外饰件的模制品,以及 可提供生产聚合物组合物的方法。