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    • 1. 发明申请
    • RANDOM ETHYLENE/ALKYL ACRYLATE COPOLYMERS, COMPOUNDS AND ELASTOMERIC COMPOSITIONS THEREOF WITH IMPROVED LOW TEMPERATURE PROPERTIES
    • 随机乙烯/丙烯酸烯丙酯共聚物,其化合物和弹性体组合物具有改善的低温特性
    • WO2005010059A1
    • 2005-02-03
    • PCT/US2004/023669
    • 2004-07-22
    • E.I. DUPONT DE NEMOURS AND COMPANYWU, Yun-TaiSTEWART, Mark, AaronMITCHELL, David, JohnMCBRIDE, Edward
    • WU, Yun-TaiSTEWART, Mark, AaronMITCHELL, David, JohnMCBRIDE, Edward
    • C08F10/02
    • C08L33/08C08F220/12
    • Disclosed are random copolymers derived from ethylene and at least two different alkyl acrylate comonomers, with or without an acid cure site-containing comonomer. In particular, disclosed are copolymers derived from copolymerization of (a) from 10 to 50 weight % of ethylene; (b) from 5 to 55 weight % of a first alkyl acrylate; (b) from 15 to 80 weight % of a second alkyl acrylate; and (d) from 0 to 7 weight % of a monoalkyl ester of 1,4-butene-dioic acid. Such copolymers exhibit lower glass transition temperatures (Tg) relative to previous ethylene copolymers comprising a single alkyl acrylate comonomer and maintain the good heat and fluid resistance when employed to produce cured elastomeric compositions as well as the improved low temperature properties. This invention also provides compounded compositions comprising these copolymers, and cured compositions (i.e., vulcanizates) as well as rubber articles formed from these compounded compositions, such as hoses, dampers, seals, gaskets, constant velocity joint (CVJ) boots and shaft boots.
    • 公开了衍生自乙烯和至少两种不同的丙烯酸烷基酯共聚单体的无规共聚物,具有或不具有含酸固化位点的共聚单体。 特别地,公开了衍生自(a)10至50重量%的乙烯的共聚合的共聚物; (b)5至55重量%的第一丙烯酸烷基酯; (b)15至80重量%的第二丙烯酸烷基酯; 和(d)0至7重量%的1,4-丁二烯酸的单烷基酯。 这种共聚物相对于包含单一烷基丙烯酸酯共聚单体的先前乙烯共聚物显示较低的玻璃化转变温度(Tg),并且当用于产生固化的弹性体组合物以及改进的低温性能时,保持良好的耐热和耐流体性。 本发明还提供了包含这些共聚物和固化的组合物(即硫化橡胶)的复合组合物以及由这些复合组合物形成的橡胶制品,例如软管,阻尼器,密封件,垫圈,等速万向节(CVJ)靴和轴靴。
    • 2. 发明申请
    • POLYPROPYLENE-BASED HOT-MELT ADHESIVE
    • 基于聚丙烯的热熔胶
    • WO1995024449A1
    • 1995-09-14
    • PCT/CA1995000132
    • 1995-03-10
    • DUPONT CANADA INC.ARTHURS, Trevor, CurtisKELLY, Peter, YatesBRYCE, Wayne, FrederickMITCHELL, David, John
    • DUPONT CANADA INC.
    • C09J123/10
    • C09J123/10C08L2666/24C09J151/06
    • An adhesive composition comprising a melt blend of: (a) 50-95 % by weight of polypropylene that has been grafted with 0-5 %, especially at least 0.1 % by weight, of at least one ethylenically-unsaturated carboxylic acid or anhydride, or derivative thereof; and (b) 5-50 % by weight of at least one copolymer of ethylene and at least one comonomer selected from carbon monoxide, vinyl acetate, alkyl acrylates, alkyl methacrylates, in which the alkyl group has 1-4 carbon atoms, acrylic acid and methacrylic acid, and ethylene/propylene/diene copolymers, said copolymer having been grafted with 0-5 % by weight of at least one ethylenically-unsaturated carboxylic acid or anhydride, or derivative thereof. The adhesive composition has a melt viscosity suitable for use as a hot melt adhesive.
    • 一种粘合剂组合物,其包含以下熔融共混物:(a)50-95重量%的已经用0-5%,特别是至少0.1重量%的至少一种烯属不饱和羧酸或酸酐接枝的聚丙烯, 或其衍生物; 和(b)5-50重量%的乙烯和至少一种选自一氧化碳,乙酸乙烯酯,丙烯酸烷基酯,甲基丙烯酸烷基酯,其中烷基具有1-4个碳原子的共聚单体的共聚物的至少一种共聚物,丙烯酸 和甲基丙烯酸和乙烯/丙烯/二烯共聚物,所述共聚物已经接枝有0-5重量%的至少一种烯键式不饱和羧酸或酸酐或其衍生物。 粘合剂组合物具有适合用作热熔粘合剂的熔融粘度。