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    • 1. 发明申请
    • FLUORINE-SUBSTITUTED BENZENE DERIVATIVES, LIQUID-CRYSTAL COMPOSITION, AND LIQUID-CRYSTAL DISPLAY ELEMENT
    • 氟取代的苯并噻吩衍生物,液晶组合物和液晶显示元件
    • WO1998023564A1
    • 1998-06-04
    • PCT/JP1997004331
    • 1997-11-27
    • CHISSO CORPORATIONKONDO, TomoyukiMIYAZAWA, KazutoshiTAKEUCHI, HiroyukiMATSUI, ShuichiHISATSUNE, YasusukeTAKESHITA, FusayukiNAKAGAWA, Etsuo
    • CHISSO CORPORATION
    • C07C25/18
    • C07C17/12C07C17/263C07C17/35C07C25/18C07C43/225C07C45/004C09K19/10C09K19/44C09K19/46C07C49/813
    • Liquid-crystalline compounds which have an extremeley high voltage retention, an extremely small temperature dependence of the retention, a low threshold voltage, and a large value of DELTA n; a liquid-crystal composition containing any of the liquid-crystal compounds; and a liquid-crystal display element containing the liquid-crystal composition. The compounds are represented by general formula (1), wherein R represents C1-20 alkyl, in which arbitrary non adjacent methylene groups (-CH2-) may have been replaced with oxygen atoms (-O-); Y1 to Y16 each independently represents hydrogen or fluorine, provided at least two of them are fluorine atoms and that at least two hydrogen atoms of each 1,4-phenylene group have not been replaced with fluorine atoms; X represents halogeno or C1-20 alkyl in which arbitrary non adjacent methylene groups may have been replaced with oxygen atoms and any hydrogen has optionally been replaced with fluorine; and Z1, Z2, and Z3 each independently represents -(CH2)2-, -(CH2)4-, -CH2O-, -OCH2-, -(CH2)3O-, -O(CH2)3- or a single bond; and each atom contained in this compound may have been replaced with an isotope thereof; provided when X is -OCF2CF2H, Z1 and Z3 are both single bonds, and Z2 is -(CH2)2-, then none of Y6, Y10, and Y12 is F, and none of Y1 to Y5, Y7 to Y9, Y11, and Y13 to Y16 is H; none of Y2, Y10, and Y12 is F, and none of Y1, Y3 to Y9, Y11, and Y13 to Y16 is H; or none of Y2, Y4, Y10, and Y12 is F and none of Y1, Y3, Y5 to Y9, Y11, and Y13 to Y16 is H.
    • 液晶化合物具有极高的保持电压,极低的保留温度依赖性,低阈值电压和较大的DELTA n值; 含有任何液晶化合物的液晶组合物; 和含有液晶组合物的液晶显示元件。 化合物由通式(1)表示,其中R代表C1-20烷基,其中任意的非相邻亚甲基(-CH 2 - )可以被氧原子(-O-)代替; Y1至Y16各自独立地表示氢或氟,其中至少两个为氟原子,并且每个1,4-亚苯基的至少两个氢原子未被氟原子替代; X表示卤代或C 1-20烷基,其中任意的非相邻亚甲基可能被氧原子取代,并且任选的氢任选被氟代替; 并且Z 1,Z 2和Z 3各自独立地表示 - (CH 2)2 - , - (CH 2)4 - , - CH 2 O - , - OCH 2 - , - (CH 2)3 O-,-O ; 并且该化合物中所含的每个原子可以被其同位素代替; 当X是-OCF 2 CF 2 H,Z 1和Z 3都是单键,Z 2是 - (CH 2)2)时,Y 6,Y 10和Y 12都不是F,Y 1,Y 5,Y 7,Y 9,Y 11, Y13〜Y16为H; Y2,Y10,Y12都不是F,Y1,Y3〜Y9,Y11,Y13〜Y16均不为H, 或者Y2,Y4,Y10和Y12都不为F,Y1,Y3,Y5〜Y9,Y11,Y13〜Y16都不为H.