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1. 发明授权

US4342841A Polyamide polyurethane prepared by reaction of polyisocyanate with a 1,1-diamino ethylene 失效
标题翻译：通过多异氰酸酯与1,1-二氨基乙烯反应制备的聚酰胺聚氨酯
公开(公告)号：US4342841A
公开(公告)日：1982-08-03
申请号：US292871
申请日：1981-08-14
申请人： Louis M. Alberino , Dale F. Regelman
发明人： Louis M. Alberino , Dale F. Regelman
IPC分类号： C08G18/67 , C08G18/14
CPC分类号： C08G18/678 , C08G2120/00
摘要： Polyamide polyurethane polymers are disclosed that are derived from the reaction of (A) an organic polyisocyanate; (B) at least one organic polyol; and (C) a ketene-aminal having the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, and R.sub.4, when taken separately, are independently selected from the group consisting of lower alkyl, aralkyl, and cycloalkyl and, when taken together as R.sub.1 with R.sub.2 and R.sub.3 with R.sub.4 with the respective nitrogen atoms to which they are attached, represent independently heterocyclic groups having from 5 to 7 ring atoms, wherein the equivalent proportions of said polyol component (B) to said ketene-aminal component (C) fall within the range of about 1:4 to about 1:80 and the ratio of equivalents of said isocyanate to total equivalents of isocyanate reactive ingredients (B) plus (C) is within the range of about 0.95:1 to 6:1.The polymers find particular utility in the preparation of RIM parts which parts have essentially attained their optimum physical properties without the need of a thermal curing step.
摘要翻译：公开了衍生自（A）有机多异氰酸酯的反应的聚酰胺聚氨酯聚合物; （B）至少一种有机多元醇; 和（C）具有式“IMAGE”的乙烯酮 - 缩醛，其中R1，R2，R3和R4分别独立地选自低级烷基，芳烷基和环烷基，并且当作为R1 其中R 2和R 3与其与它们所连接的相应氮原子的R4独立地表示具有5至7个环原子的杂环基，其中所述多元醇组分（B）与所述烯酮 - 缩醛组分（C）的当量比例下降在约1:4至约1:80的范围内，所述异氰酸酯的当量与异氰酸酯反应性成分（B）加上（C）的总当量的比率在约0.95:1至6:1的范围内。该聚合物在制备RIM部件方面具有特别的用途，这些部件基本上达到其最佳物理性能，而不需要热固化步骤。

2. 发明授权

US4546114A Process for the preparation of polyurea elastomers 失效
标题翻译：制备聚脲弹性体的方法
公开(公告)号：US4546114A
公开(公告)日：1985-10-08
申请号：US664820
申请日：1984-10-25
申请人： Louis M. Alberino , Dale F. Regelman , Nancy P. Vespoli
发明人： Louis M. Alberino , Dale F. Regelman , Nancy P. Vespoli
IPC分类号： C08G18/65 , C08G18/14
CPC分类号： C08G18/6529 , C08G2120/00
摘要： An improved process for the reaction injection molding of high flexural modulus polyurea containing elastomers is disclosed. Elastomers of this type when prepared at the prior art molding temperatures are brittle and can shatter like glass while still in the mold. The same elastomers when molded at a temperature of from about 90.degree. to about 220.degree. C. are not at all brittle. These elastomers are also characterized by the other advantageous properties inherent in polyurea elastomers such as high tensile strength, high hardness, and good heat resistance.The improved RIM process finds particular utility in the preparation of auto parts such as panels, engine hoods, and the like.
摘要翻译：公开了用于高弯曲模量聚脲含有弹性体的反应注射成型的改进方法。当在现有技术的模制温度下制备时，这种类型的弹性体是脆性的，并且在仍然在模具中可能像玻璃一样粉碎。当在约90℃至220℃的温度下模制时，相同的弹性体完全不脆。这些弹性体的特征还在于聚脲弹性体固有的其他有利特性，例如高拉伸强度，高硬度和良好的耐热性。改进的RIM方法在制备诸如面板，发动机罩等的汽车部件中具有特别的用途。

3. 发明授权

US4338428A Novel polyamides from ketene-aminals 失效
标题翻译：来自乙烯酮的新型聚酰胺
公开(公告)号：US4338428A
公开(公告)日：1982-07-06
申请号：US292872
申请日：1981-08-14
申请人： Louis M. Alberino , Dale F. Regelman
发明人： Louis M. Alberino , Dale F. Regelman
IPC分类号： C08G18/67 , C08G18/32 , C08G18/38 , C08G69/08
CPC分类号： C08G18/678 , C08G2120/00
摘要： Novel polyketene-aminal polyamides are disclosed which have the following recurring unit ##STR1## wherein R is a divalent hydrocarbon radical, R.sub.1, R.sub.2, R.sub.3, and R.sub.4 when taken separately are independently selected from the group consisting of lower alkyl, aralkyl, and cycloalkyl, and when taken together as R.sub.1 with R.sub.2 and R.sub.3 with R.sub.4 with the respective nitrogen atoms to which they are attached represent independently a heterocyclic group having from 5 to 7 ring atoms.The polyamides are prepared by reacting together the appropriate diisocyanate [R(NCO).sub.2 ] and appropriate ketene-aminal to form the polymer directly without the evolution of any by-products or volatiles.The novel polymers are thermoplastic and can be formed or shaped using any of the techniques known to those skilled in the thermoplastic polymer art.
摘要翻译：公开了具有以下重复单元的新型聚烯酮 - 酰胺聚酰胺，其中R是二价烃基，R 1，R 2，R 3和R 4分开独立地选自低级烷基，芳烷基和环烷基并且当R 1和R 3与R 4与它们所连接的相应氮原子一起作为R 1独立地表示具有5至7个环原子的杂环基时。聚酰胺通过使合适的二异氰酸酯[R（NCO）2]和适当的乙烯酮 - 胺反应而直接形成聚合物而制备，而不会产生任何副产物或挥发物。新型聚合物是热塑性的并且可以使用热塑性聚合物领域的技术人员已知的任何技术形成或成型。

4. 发明授权

US4321333A Polyurethane prepared from polyisocyanate blend 失效
标题翻译：由聚异氰酸酯混合物制备的聚氨酯
公开(公告)号：US4321333A
公开(公告)日：1982-03-23
申请号：US254920
申请日：1981-04-16
申请人： Louis M. Alberino , Robert J. Lockwood
发明人： Louis M. Alberino , Robert J. Lockwood
IPC分类号： C08G18/10 , C08G18/12 , C08G18/32
CPC分类号： C08G18/10 , C08G18/12
摘要： Polyurethane polymers comprising the reaction product of an organic polyisocyanate (A), an organic polyol (B), & a difunctional extender (C) wherein the improvement comprises employing as the polyisocyanate (A) a composition comprising a bond of, (a) a prepolymer comprising the reaction product of methylenebis (phenyl isocyanate) with a polyol mixture comprising:(1) polyol having a molecular weight of at least 1,000, &(2) polyol having a molecular weight of about 115 to 300 & (b) a liquefied methylenebis (phenyl isocyanate). Also disclosed are blends of (a) & (b).
摘要翻译：包括有机多异氰酸酯（A），有机多元醇（B）和双功能增量剂（C）的反应产物的聚氨酯聚合物，其中改进包括使用作为多异氰酸酯（A）的组合物，其包含：（a）包含亚甲基双（苯基异氰酸酯）与多元醇混合物的反应产物的预聚物，其包含：（1）分子量为至少1,000的多元醇和（2）分子量为约115至300的多元醇，（b）液化的亚甲基双（苯基异氰酸酯）。还公开了（a）和（b）的共混物。

5. 发明授权

US4772658A Low viscosity copolymer polyisocyanates 失效
标题翻译：低粘度共聚物多异氰酸酯
公开(公告)号：US4772658A
公开(公告)日：1988-09-20
申请号：US121185
申请日：1987-11-16
申请人： Louis M. Alberino , John W. Reisch
发明人： Louis M. Alberino , John W. Reisch
IPC分类号： C08G18/70 , C08G18/72 , C08L35/04
CPC分类号： C08G18/728 , C08G18/708
摘要： Disclosed are novel polymer/polyisocyanate compositions. The compositions are prepared by the in-situ polymerization of at least one ethylenically unsaturated monomer in an organic polyisocyanate and in the presence of an adduct formed from the reaction of an excess of a carbodiimide-free polyisocyanate and a hydroxyl containing ethylenically unsaturated monomer.The graft polyisocyanates find particular utility in the making of molded polyurethane resins.
摘要翻译：公开了新型聚合物/多异氰酸酯组合物。通过至少一种烯属不饱和单体在有机多异氰酸酯中的原位聚合和在过量的不含碳二亚胺的多异氰酸酯和含羟基的烯属不饱和单体的反应形成的加合物的存在下制备组合物。接枝聚异氰酸酯在模塑聚氨酯树脂的制造中具有特别的用途。

6. 发明授权

US4143063A Preparation of carbodiimide-containing polyisocyanates 失效
标题翻译：含有碳酰亚胺的聚异氰酸酯的制备
公开(公告)号：US4143063A
公开(公告)日：1979-03-06
申请号：US894737
申请日：1978-04-10
申请人： Louis M. Alberino , Curtis P. Smith
发明人： Louis M. Alberino , Curtis P. Smith
IPC分类号： C08G18/00 , B01J31/00 , B01J31/06 , C07B61/00 , C07C67/00 , C07C241/00 , C07C265/14 , C07C267/00 , C08F8/42 , C08G18/02 , C08G18/79 , C07C119/055
CPC分类号： C08G18/797 , B01J31/069 , C08F8/42
摘要： A process is described for converting organic polyisocyanates to carbodiimide-containing polyisocyanates by heating said organic polyisocyanates in the presence of an organoarsine-substituted polystyrene carbodiimide-forming catalyst until a desired level of conversion is achieved, followed by separation of catalyst from product. It is thus possible to obtain a carbodiimide-containing polyisocyanate which is free from catalyst and hence free from the possibility that carbodiimide formation can continue on storage of the product. In a particular embodiment the process is employed to convert methylenebis(phenyl isocyanate), which is normally solid at ambient temperatures, to a storage stable liquid product. The polymeric catalysts employed in the process are characterized by a recurring unit of the formula: ##STR1## wherein R.sub.1 and R.sub.2 are hydrocarbyl, R.sub.3 is hydrogen, chloro or methyl, R.sub.4 is hydrogen or methyl and n is 0 or 1.

7. 发明授权

US4810444A Method for making mat-molded rim parts 失效
标题翻译：制作镶边轮辋部件的方法
公开(公告)号：US4810444A
公开(公告)日：1989-03-07
申请号：US59436
申请日：1987-06-08
申请人： Louis M. Alberino , Peter S. Carleton , Douglas P. Waszeciak
发明人： Louis M. Alberino , Peter S. Carleton , Douglas P. Waszeciak
IPC分类号： B29C45/00 , B29C33/00 , B29C39/42 , B29C43/10 , B29C43/36 , B29C45/14 , B29C45/34 , B29C45/56 , B29C67/24 , B29C70/48 , B29K75/00 , B29K105/06 , B29L9/00 , C08J5/04 , B29C43/04
CPC分类号： B29C33/0055 , B29C43/361 , B29C67/246 , B29C70/48 , B29C2043/3444 , B29C2043/3615 , B29C2043/5883 , B29C43/10 , B29K2075/00 , B29K2105/06
摘要： A process for the preparation of molded high strength composites comprising fibrous reinforcing material impregnated with a reaction injection molded polyisocyanurate resin. The process comprises first evacuating a mold containing the fibrous reinforcing material said mold equipped with means for accepting an overflow volume of the resin. The mold system is pressurized prior to gelation causing the overflow volume to be forced into a final volume. The molded composites have a high flexural moduli, good physical properties, low void content and smooth surface.

8. 发明授权

US4659747A Cyclohexanedimethanol/diamine mixtures as RIM extenders 失效
标题翻译：环己烷二甲醇/二胺混合物作为RIM增量剂
公开(公告)号：US4659747A
公开(公告)日：1987-04-21
申请号：US863621
申请日：1986-05-15
申请人： Louis M. Alberino , James R. Pritchard , Nancy P. Vespoli
发明人： Louis M. Alberino , James R. Pritchard , Nancy P. Vespoli
IPC分类号： C08G18/66 , C08G18/32 , C08G18/65 , C08G18/72 , C08G18/14
CPC分类号： C08G18/3237 , C08G18/3212 , C08G18/6529 , C08G2120/00
摘要： Polyurethane-polyurea polymers are disclosed that are derived from the reaction injection molding of organic polyisocyanates, optional high molecular weight active hydrogen containing compounds and extender mixtures comprising (i) aromatic diamines wherein at least one of the positions ortho to each amine group is substituted by a lower alkyl group and (ii) bis(hydroxyalkyl)cycloalkanes. The improved polymers have excellent resistance to high temperature conditions.
摘要翻译：公开了聚氨酯 - 聚脲聚合物，其衍生自有机多异氰酸酯，任选的高分子量活性氢化合物和增量剂混合物的反应注射成型，其包含（i）芳族二胺，其中每个胺基的邻位中的至少一个位置被低级烷基和（ii）双（羟基烷基）环烷烃。改进的聚合物具有优异的耐高温条件。

9. 发明授权

US4472341A Polyurethane process using polysiloxane mold release agents 失效
标题翻译：聚氨酯工艺采用聚硅氧烷脱模剂
公开(公告)号：US4472341A
公开(公告)日：1984-09-18
申请号：US510791
申请日：1983-07-05
申请人： Louis M. Alberino , Dale F. Regelman , George H. Temme
发明人： Louis M. Alberino , Dale F. Regelman , George H. Temme
IPC分类号： C08G18/00 , B29C33/64 , C08G18/08 , C08L75/00 , C08L75/04 , B28B1/24 , C08G18/14
CPC分类号： C08G18/08 , B29C33/64 , C08L75/04 , Y10S264/83
摘要： Disclosed is an improved process for the production of organic polyisocyanate based molded polymers prepared from at least one organic polyisocyanate and at least one polyol in the presence of an internal release agent wherein the improvement comprises employing as said agent a polysiloxane having at least one unit of the formula ##STR1## wherein R is selected from the group consisting of lower-alkyl and aryl, R.sup.1 is a divalent hydrocarbon radical, and R.sup.2 is selected from the group consisting of lower-alkoxy, aryloxy, particular hydroxyalkyleneoxy, alkoxyalkyleneoxy, amino, and hydroxyalkylamino radicals.The molding process can be repeated in many cycles before the molds require cleaning or treatment with release agent. The ease and rapidity with which the present process can be carried out makes it particularly suited to RIM production methods.
摘要翻译：公开了一种改进的制备由至少一种有机多异氰酸酯和至少一种多元醇在内部脱模剂存在下制备的有机多异氰酸酯基模制聚合物的方法，其中改进包括使用作为所述试剂的聚硅氧烷，所述聚硅氧烷具有至少一个单元其中R选自低级烷基和芳基，R1是二价烃基，R2选自低级烷氧基，芳氧基，特别是羟基亚烷基氧基，烷氧基亚烷基氧基，氨基和羟烷基氨基。在模具需要清洁或用脱模剂处理之前，可以在许多周期内重复模制过程。可以轻松快捷地实现本流程，使其特别适合RIM生产方式。

10. 发明授权

US4385133A Novel compositions and process 失效
标题翻译：新的组成和过程
公开(公告)号：US4385133A
公开(公告)日：1983-05-24
申请号：US385930
申请日：1982-06-07
申请人： Louis M. Alberino , Robert J. Lockwood
发明人： Louis M. Alberino , Robert J. Lockwood
IPC分类号： B29C45/46 , B29C43/00 , B29C45/00 , B29K75/00 , C08G18/00 , C08G18/48 , C08G18/65 , C08G18/66 , C08G18/14
CPC分类号： C08G18/4816 , C08G18/4812 , C08G18/6674 , C08G2120/00 , C08G2130/00 , Y10S521/914
摘要： Polyurethanes having a two phase morphology and characterized by high impact strength and, optionally, high modulus are obtained by reaction of 4,4'-methylenebis(phenyl isocyanate) and modified forms thereof with an aliphatic glycol extender and a blend of at least two polyoxypropylene-polyoxyethylene polyols both of which have average functionalities in the range of 2 to 4, one of which has a molecular weight in the range of about 3000 to 10,000 and contains at least 23 percent by weight of ethylene oxide residues and the other has a molecular weight in the range of about 750 to about 2000 and contains at least 45 percent by weight of ethylene oxide. The two or more such polyols are employed in proportions such that the aliphatic glycol extender is completely miscible with said polyols if blended together.
摘要翻译：具有两相形态并且特征在于高冲击强度和任选的高模量的聚氨酯通过4,4'-亚甲基双（苯基异氰酸酯）和其改性形式与脂族二醇增量剂和至少两种聚氧化丙烯的共混物聚氧乙烯多元醇均具有2至4的平均官能度，其中一个具有约3000至10,000的分子量，并且含有至少23重量％的环氧乙烷残基，另一个具有分子重量在约750至约2000的范围内，并且含有至少45重量％的环氧乙烷。两种或多种这样的多元醇的比例使用，使得如果将脂族二醇增量剂混合在一起，则与所述多元醇完全混溶。

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