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    • 3. 发明授权
    • Low cost high performance electrode for energy storage devices and systems and method of making same
    • 用于储能装置和系统的低成本高性能电极及其制造方法
    • US09236599B2
    • 2016-01-12
    • US13780502
    • 2013-02-28
    • Linda Zhong
    • Linda Zhong
    • H01G13/00H01M4/04H01G11/38H01G11/06H01G11/28H01M4/139H01G11/46H01G11/50H01M4/88
    • H01M4/043H01G11/06H01G11/28H01G11/38H01G11/46H01G11/50H01G13/00H01M4/0404H01M4/139H01M4/88Y02E60/122Y02E60/13
    • The present invention is directed to a low cost, high performance electrode for energy storage devices and energy storage systems and a method for making same is disclosed, where a flexible binder is mixed with partial active and conductive materials in the electrode formulation and activated by mixing with a minimum amount of solvent it is then mixed with the remaining active and conductive materials and the binder is uniformly deposited on to the active and conductive particles by high speed mixing. The active and conductive particles deposited with activated binder particles are then pressed together to form free standing electrode film. High performance and low cost products, such as free standing electrode films, laminated electrodes, ultracapacitors, lithium-ion capacitors, batteries, fuel cells and hybrid cells which are the combination of the above devices, and the energy storage system or the system blocks, such as modules, can be manufactured using this process.
    • 本发明涉及用于储能装置和储能系统的低成本,高性能的电极及其制造方法,其中柔性粘结剂与电极配方中的部分活性和导电材料混合并通过混合活化 用最少量的溶剂将其与剩余的活性和导电材料混合,并且粘合剂通过高速混合均匀地沉积到活性和导电颗粒上。 然后将沉积有活性粘合剂颗粒的活性和导电颗粒压在一起以形成自由电极膜。 作为上述装置的组合的诸如独立电极膜,层叠电极,超级电容器,锂离子电容器,电池,燃料电池和混合电池的高性能和低成本的产品以及能量存储系统或系统块, 例如模块,可以使用这个过程来制造。
    • 7. 发明申请
    • DENSIFICATION OF COMPRESSIBLE LAYERS DURING ELECTRODE LAMINATION
    • 电极层压时可压电层的扩散
    • US20080266753A1
    • 2008-10-30
    • US12122383
    • 2008-05-16
    • Porter MitchellXiaomei XiLinda Zhong
    • Porter MitchellXiaomei XiLinda Zhong
    • H01G9/00H01M6/00
    • H01G11/86H01G11/28H01G11/30H01G11/38Y02E60/13Y10T29/41Y10T29/43Y10T29/49112Y10T29/49114Y10T29/49115Y10T29/49155
    • A compressible and deformable layer is densified and laminated to a layer of a material that is relatively resistant to stretching. The densification and bonding take place in a single step. As used in fabrication of electrodes, for example, electrodes for double layer capacitors, a deformable and compressible active electrode film is manufactured from activated carbon, conductive carbon, and a polymer. The electrode film may be bonded directly to a collector. Alternatively, a collector may be coated with a wet adhesive layer. The adhesive layer is subsequently dried onto the foil. The dried adhesive and foil combination may be manufactured as a product for later sale or use, and may be stored as such on a storage roll or other storage device. The active electrode film is overlayed on the metal foil, and processed in a laminating device, such as a calender. Lamination both densifies the active electrode film and bonds the film to the metal foil. Spreading of the active electrode film in the plane parallel to the plane of the metal foil is reduced or eliminated during lamination, because of the adhesion between the film and the foil.
    • 可压缩和可变形层被致密化并层压到相对抗拉伸的材料层上。 致密化和粘合发生在一个步骤。 如用于制造电极时,例如,用于双层电容器的电极,可变形和可压缩的有源电极膜由活性炭,导电碳和聚合物制成。 电极膜可以直接结合到集电体。 或者,收集器可以涂覆有湿粘合剂层。 随后将粘合剂层干燥到箔上。 干燥的粘合剂和箔组合可以作为产品制造以供以后出售或使用,并且可以原样存储在存储卷或其他存储装置上。 将活性电极膜覆盖在金属箔上,并在诸如压延机的层压装置中加工。 层压将致密化活性电极膜并将膜粘合到金属箔上。 由于膜和箔之间的粘合,层压时活性电极膜在平行于金属箔的平面的平面上的扩展被减少或消除。
    • 9. 发明申请
    • ELECTROCHEMICAL DOUBLE LAYER CAPACITOR
    • 电化学双层电容器
    • US20080106850A1
    • 2008-05-08
    • US11971188
    • 2008-01-08
    • Linda ZhongXiaomei XiBin Zou
    • Linda ZhongXiaomei XiBin Zou
    • H01G9/155
    • H01G9/02H01G11/26H01G11/28H01G11/32H01G11/38H01M4/0404H01M4/621H01M4/96Y02E60/13
    • Active electrode material, such as fibrillized blend of activated carbon, polymer, and conductive carbon, is pretreated by immersion in a sealing coating. After the active electrode material is dried, the coating seals micropores of the activated carbon or another porous material, thus preventing exposure of water molecules or other impurities trapped in the micropores to outside agents. At the same time, the sealing coating does not seal most mesapores of the porous material, allowing exposure of the mesapores' surface area to the outside agents. The pretreated active electrode material is used for making electrodes or electrode assemblies of electrical energy storage devices. For example, the electrodes may be immersed in an electrolyte to construct electrochemical double layer capacitors. Pretreatment with the sealing coating reduces the number of water molecules interacting with the electrolyte, enhancing the breakdown voltage of the capacitors.
    • 通过浸渍在密封涂层中预处理活性电极材料,例如活性炭,聚合物和导电碳的原纤化混合物。 在活性电极材料干燥之后,涂层密封活性炭的微孔或另一种多孔材料,从而防止水分子或其它杂质捕获到外部试剂中。 同时,密封涂层不会密封多孔材料的大多数介质,允许将介孔表面积暴露于外部试剂。 预处理的活性电极材料用于制造电能存储装置的电极或电极组件。 例如,电极可以浸入电解质中以构成电化学双层电容器。 用密封涂层进行预处理减少了与电解质相互作用的水分子数量,提高了电容器的击穿电压。