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    • 3. 发明申请
    • METHOD FOR THE TREATMENT OF WASTE WATER FROM FLORFENICOL PRODUCTION
    • 从氟虫腈生产中处理废水的方法
    • US20090289007A1
    • 2009-11-26
    • US12373054
    • 2006-11-28
    • Hongqiang RenLili DingBingqing Xin
    • Hongqiang RenLili DingBingqing Xin
    • C02F9/14
    • C02F9/00C02F1/5236C02F1/66C02F1/78C02F3/286C02F2101/101C02F2101/16C02F2101/20C02F2103/343C02F2103/365Y10S210/915
    • A method for the treatment of waste water from florfenicol production is provided, which mainly comprises the steps as follows: adding iron chips or steel slag to waste water from a copper salt workshop, regulating the pH value, filtering, then adding limestone, lime or Ca(OH)2 and having a solid-liquid separation; blending the treated waste water and waste water from a splitting workshop, oxidizing the residual reductive matter by ozone and removing NH3-N by blowing; blending the treated water and waste water from esterifying or florfenicol workshops and diluting the blended water, adding phosphate and microelement, regulating the pH value, then having an anaerobic treatment in an anaerobic reactor; diluting the treated waste water, then having an aerobic treatment in an aerobic reactor. The method also can comprise the steps as follows: blending the waste water from all workshops, adding phosphate and microelement, regulating the pH value, blending the treated waste water with recycling anaerobic water and having a settling treatment, then having an anaerobic treatment in an anaerobic granular sludge bed reactor, diluting the treated waste water and having an aerobic treatment in a SBR.
    • 提供氟苯尼考生产废水处理方法,主要包括以下步骤:从铜盐车间向废水中加入铁屑或钢渣,调节pH值,过滤,然后加入石灰石,石灰或 Ca(OH)2,并具有固液分离; 将经处理的废水和分解车间的废水混合,通过臭氧氧化残留的还原物质,吹入除去NH3-N; 将经处理的水和废水从酯化或氟苯尼考车间混合,稀释混合水,加入磷酸盐和微量元素,调节pH值,然后在厌氧反应器中进行厌氧处理; 稀释经处理的废水,然后在需氧反应器中进行好氧处理。 该方法还可以包括以下步骤:混合所有车间的废水,加入磷酸盐和微量元素,调节pH值,将经处理的废水与循环的厌氧水混合并进行沉降处理,然后进行厌氧处理 厌氧颗粒污泥床反应器,稀释经处理的废水,并在SBR中进行有氧处理。
    • 6. 发明授权
    • Molecular sieve
    • 分子筛
    • US08709963B2
    • 2014-04-29
    • US13420600
    • 2012-03-14
    • Hongqiang RenTao ZhangLili Ding
    • Hongqiang RenTao ZhangLili Ding
    • B01J29/06B01J27/182
    • C02F1/281B01J20/18B01J20/28057B01J20/28064C01B37/00C01P2006/14C01P2006/16C02F2101/16
    • A molecular sieve including a basic skeleton of a molecular sieve and magnesium and phosphorus compounds as functional materials supported on the inner surface of the basic skeleton. A method of preparation of a modified molecular sieve including (1) dissolving a magnesium salt in water to obtain a magnesium salt solution; (2) dissolving phosphoric acid in water to obtain a phosphoric acid solution; (3) adding a molecular sieve to the magnesium salt solution, stirring, standing, drying for dehydration, and baking; and (4) adding a modified molecular sieve with supported magnesium compounds obtained from the step (3) to the phosphoric acid solution, stirring, standing, drying for dehydration, and baking to obtain a modified molecular sieve. The modified molecular sieve has high selectivity for ammonia nitrogen in wastewater.
    • 包括分子筛的基本骨架的分子筛和作为功能材料的镁和磷化合物被支撑在基本骨架的内表面上。 一种制备改性分子筛的方法,包括(1)将镁盐溶于水中以获得镁盐溶液; (2)将磷酸溶解在水中,得到磷酸溶液; (3)向镁盐溶液中加入分子筛,搅拌,静置,干燥脱水,烘烤; 和(4)将由步骤(3)获得的负载的镁化合物的改性分子筛加入到磷酸溶液中,搅拌,静置,干燥脱水,并烘烤得到改性分子筛。 改性分子筛对废水中的氨氮具有较高的选择性。
    • 7. 发明授权
    • Method for removing ammonia nitrogen in coking wastewater
    • 焦化废水中氨氮去除方法
    • US08329040B2
    • 2012-12-11
    • US12672095
    • 2008-07-25
    • Hongqiang RenLili DingTao Zhang
    • Hongqiang RenLili DingTao Zhang
    • B01D21/00C02F1/52
    • C02F1/5254C02F1/025C02F1/5236C02F1/66C02F9/00C02F11/10C02F11/121C02F2101/16C02F2103/16C02F2103/365
    • A new method for removing ammonia nitrogen in coking wastewater is disclosed in this invention. It comprises steps as follow: introducing coking wastewater into a reaction pool into which magnesium and phosphate are added; adding sodium hydroxide to regulate the PH of the mixture around 9.0-10.5; separating the supernatant and the precipitate after proper agitation and natural precipitation; dehydrating the precipitate and then adding alkaline fly ash, water to the dehydrated precipitate and stirring the mixture; decomposing the mixture with heating and absorbing the ammonia gas thereof produced with acidic solution. In consideration of high concentration of ammonia nitrogen in coking wastewater, this invention aims at quick and efficient treatment. The concentration of ammonia nitrogen in treated water meets the highest discharge standard stipulated in [China National] Integrated Wastewater Discharge Standard (GB8978-96). Meanwhile, this invention provides a new way for beneficial utilization of the alkaline fly ash as well. The chemicals adopted for wastewater precipitation in this invention can be recovered for recyclable use, which consequently cuts down the total cost of the wastewater treatment.
    • 在本发明中公开了一种在焦化废水中除去氨氮的新方法。 包括以下步骤:将焦化废水引入加入镁和磷酸盐的反应池中; 加入氢氧化钠调节混合物的PH值在9.0-10.5左右; 在适当搅拌和自然沉淀后分离上清液和沉淀物; 将沉淀物脱水,然后加入碱性飞灰,将水加入脱水沉淀中并搅拌混合物; 通过加热分解混合物并吸收其用酸性溶液产生的氨气。 考虑到焦化废水中高浓度的氨氮,本发明旨在快速有效地处理。 处理水中氨氮浓度符合“中国国家综合污水排放标准”(GB8978-96)规定的最高排放标准。 同时,本发明也提供了有益地利用碱性飞灰的新途径。 在本发明中用于废水沉淀的化学品可以回收用于可回收利用,因此降低了废水处理的总成本。