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    • 3. 发明授权
    • Hydrocarbon solvent treatment of bituminous materials
    • 烃类溶剂处理沥青材料
    • US4125459A
    • 1978-11-14
    • US861858
    • 1977-12-19
    • Leo Garwin
    • Leo Garwin
    • C10C3/08C10G1/04
    • C10G1/04C10C3/08
    • This invention relates to the production of oils of specified higher quality at the same yield or to the production of a higher yield of oils of the same quality from a bituminous material by a combination of propane and pentane deasphalting than would otherwise be obtainable by utilizing either propane or pentane deasphalting processes alone. This is effected by subjecting the bituminous material first to a pentane deasphalting process to produce a light fraction containing resins and oils, followed by a propane deasphalting process on the resin-oil fraction previously obtained and the recycle of at least a portion of the resins fraction back to the pentane deasphalting process. Alternatively, this is effected by subjecting the bituminous material first to a propane deasphalting process to produce a heavy fraction containing asphaltenes and resins, followed by a pentane deasphalting process on the asphaltene-resin fraction previously obtained and recycle of at least a portion of the resins fraction back to the propane deasphalting process. The oil thus produced is obtained in higher quality at the same yield or in higher yield at the same quality by virtue of the ability to cut deeper into the residuum than otherwise would be possible.
    • 本发明涉及通过丙烷和戊烷脱沥青的组合,以相同的产率生产具有较高质量的油,或者从沥青材料生产具有相同质量的较高产量的油,而不是通过使用丙烯和戊烷脱沥青 丙烷或戊烷脱沥青工艺。 这是通过将沥青材料首先进行戊烷脱沥青方法来生产含有树脂和油的轻馏分,然后在先前获得的树脂 - 油馏分上进行丙烷脱沥青方法和至少部分树脂馏分 回到戊烷脱沥青工艺。 或者,这是通过使沥青材料首先进行丙烷脱沥青方法来生产含有沥青质和树脂的重馏分,然后在先前获得的沥青质 - 树脂馏分上进行戊烷脱沥青方法,并再循环至少一部分树脂 馏分回到丙烷脱沥青工艺。 这样生产的油以相同的产量或以相同质量的较高产量获得,凭借能够比其它方式更深入切削残渣的能力。
    • 5. 发明授权
    • Process for vis-breaking asphaltenes
    • 破坏沥青质的过程
    • US4389302A
    • 1983-06-21
    • US263977
    • 1981-05-15
    • Leo GarwinRoger A. Baldwin
    • Leo GarwinRoger A. Baldwin
    • C10G9/00C10G55/04C10G9/14
    • C10G9/007C10G2300/107
    • A process for producing additional liquid products from a heavy hydrocarbon material by vis-breaking of a separated asphaltene-containing fraction under controlled conditions of temperature and pressure. The asphaltene-containing fraction is obtained by contacting the heavy hydrocarbon material with a first solvent under elevated temperature and pressure conditions to separate the asphaltenes as a heavy phase from the remainder of the heavy hydrocarbon material. The products of the vis-breaking operation comprise distillable and substantially nondistillable liquid products in association with a residue including organometallic compounds. The distillable and substantially nondistillable liquid products then are separated from the residue. The distillable products can be separated by distillation. The nondistillable products are separated from the residue employing a second solvent maintained under elevated temperature and pressure conditions and then recovered as a liquid phase product.
    • 一种通过在温度和压力的受控条件下分离含沥青烯馏分的破坏来从重质烃材料生产另外的液体产物的方法。 通过在高温和高压条件下使重质烃物质与第一溶剂接触,将沥青质作为重质相与剩余的重质烃材料分离。 相关破坏操作的产品包括与包括有机金属化合物在内的残余物相关的可蒸馏和基本不可释放的液体产物。 然后从残余物中分离出可蒸馏且基本不可释放的液体产物。 蒸馏产物可通过蒸馏分离。 使用在升高的温度和压力条件下保持的第二溶剂将不可重复产物与残余物分离,然后作为液相产物回收。