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    • 7. 发明授权
    • Powder coating comprising acetone oxime blocked diisocyanate and
polyester
    • 包含丙酮肟封端二异氰酸酯和聚酯的粉末涂料
    • US4997900A
    • 1991-03-05
    • US290157
    • 1988-12-27
    • Larry F. Brinkman
    • Larry F. Brinkman
    • C08G18/28C08G18/76C08G18/80C09D5/03C09D5/46C09D175/00C09J175/00
    • C08G18/8006C08G18/286C08G18/765C08G18/8077C08G2150/20
    • In accordance with the present invention, a blocked isocyanate composition which is useful as a curing agent for powder coatings is prepared from the reaction of tetramethylxylene diisocyanate and acetone oxime. In a preferred embodiment, a polyol is reacted with the isocyanate to provide a prepolymer with urethane linkages wherein the isocyanate groups of the prepolymer are substantially blocked with acetone oxime. The blocked isocyanate composition of the present invention can be used as a curing agent for powder coatings, adhesives and high solid coatings which are cured by baking. The blocked isocyanate composition of the invention can be used as a cross-linking agent for a hydroxy-containing polyester, a hydroxy-containing acrylic or methacrylic polymer or any other active hydrogen containing polymer.
    • 根据本发明,由四甲基二甲苯二异氰酸酯和丙酮肟的反应制备可用作粉末涂料固化剂的封端异氰酸酯组合物。 在优选的实施方案中,多元醇与异氰酸酯反应以提供具有氨基甲酸酯键的预聚物,其中预聚物的异氰酸酯基团基本上用丙酮肟封闭。 本发明的封端异氰酸酯组合物可用作通过烘烤固化的粉末涂料,粘合剂和高固体涂料的固化剂。 本发明的封端异氰酸酯组合物可用作含羟基的聚酯,含羟基的丙烯酸或甲基丙烯酸聚合物或任何其它含活性氢的聚合物的交联剂。