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    • 1. 发明授权
    • Easily dyeable polyester film and preparation thereof
    • 易染色聚酯薄膜及其制备方法
    • US06258921B1
    • 2001-07-10
    • US08989211
    • 1997-12-11
    • Sang Bong ParkKyung Heum HanJong Chan Park
    • Sang Bong ParkKyung Heum HanJong Chan Park
    • C08G6300
    • C08J5/18C08J2367/02Y10T428/13
    • A double-axis elongated polyester film for dyeing which simultaneously satisfies following formulas: 3.295≦NMD+NTD≦3.340  (1) Benzene plane orientation≦0.740  (2) Crystallinity (%)≦54  (3) 3≦Thermal shrinkage in machine direction(%)≦7  (4) 0≦Thermal shrinkage in transverse direction(%)≦3  (5) The polyester film is prepared by melt-extruding polyester chips and cooling the extrudate in a cooling drum to prepare a non-crystalline sheet; elongating said sheet at a temperature between 80 and 100° C. which is higher than glass transition temperature (Tg) to make 3.0 to 3.6 folds of length in machine direction to obtain single-axis elongated film; further elongating the film to 3.0-4.2 folds of length in transverse direction at 120-140° C.; thermally treating the obtained film in Tenter's thermal treatment zone at 210-240° C. with at least 5 stages; and rolling the double-axis elongated film obtained by releasing 0.01-10% of the film in machine and/or transverse direction. The film obtained above must satisfy both formulas (1) and (2).
    • 用于染色的双轴细长聚酯薄膜同时满足以下公式:聚酯薄膜通过熔融挤出聚酯切片并在挤出滚筒中冷却挤出物以制备非晶片; 在高于玻璃化转变温度(Tg)的80℃和100℃之间的温度下拉伸所述片材以使机器长度上的长度为3.0-3.6倍以获得单轴细长膜; 在120-140℃下,将膜长度进一步拉长至横向的3.0-4.2倍。 在Tenter的热处理区域中,在210-240℃下用至少5个阶段热处理得到的膜; 并轧制通过在机器和/或横向上释放0.01〜10%的膜而获得的双轴细长膜。 上述获得的膜必须满足式(1)和(2)。
    • 2. 发明授权
    • Method for preparing polyester films
    • 聚酯薄膜的制备方法
    • US6036905A
    • 2000-03-14
    • US29879
    • 1998-03-03
    • Sang Bong ParkKyung Heum HanGi Tak Gam
    • Sang Bong ParkKyung Heum HanGi Tak Gam
    • C08J5/18C08G63/20C08G63/78C08J9/18C08K5/098C08K5/10C08K5/12C08L67/02B32B11/18C08G63/12
    • C08J9/18C08G63/20C08G63/78C08K5/12C08J2367/02Y10S264/47
    • A method for preparing polyester films, which comprises addition of partially esterified trimellitate at any stage of the polymerization of polyester through direct esterification or ester interchange, the partially esterified trimellitates resulting from salt formation of partial esterified trimellitic acids which are prepared by partial esterification of aromatic tricarboxylic acids selected from trimellitic acid and trimellitic anhydride with alcohols selected from alkyl alcohols and alkylene alcohols. The polyester film prepared the composition has little voids by virtue of good affinity of the particles originating from the partially esterified trimellitates with polyester and thereby not easily broken when forming films. In addition, it is easy to control particle content and size. Further, fine protrusions can be repeatitively formed in the final films, with ease, giving high abrasion resistance and slip property to the film. Besides, the polyester films can be formed in high casting speed attributable to superior electrostatic adhesion.
    • PCT No.PCT / KR95 / 00176 Sec。 371日期1998年3月3日 102(e)1998年3月3日PCT 1995年12月27日PCT PCT。 公开号WO97 / 09371 日期1997年3月13日制备聚酯薄膜的方法,其包括通过直接酯化或酯交换在聚酯聚合的任何阶段添加部分酯化的偏苯三酸酯,由制备的部分酯化偏苯三酸的盐形成产生的部分酯化的偏苯三酸酯 通过选自偏苯三酸和偏苯三酸酐的芳族三羧酸与选自烷基醇和亚烷基醇的醇进行部分酯化反应。 由于部分酯化的偏苯三酸酯与聚酯的亲和性良好,因此制备该组合物的聚酯薄膜几乎没有空隙,因此在形成薄膜时不容易破裂。 另外,容易控制颗粒含量和尺寸。 此外,可以容易地在最终的膜中重复形成微细的突起,从而赋予膜高的耐磨性和滑动性。 此外,由于优异的静电粘合性,聚酯膜可以以高铸造速度形成。