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    • 1. 发明授权
    • Reference electrode including electrolyte containing optically-active material and automatic electrochemical potential correction apparatus using the same
    • 包括含有光学活性材料的电解质的参比电极和使用其的自动电化学电位校正装置
    • US08016992B2
    • 2011-09-13
    • US12470838
    • 2009-05-22
    • Jei-Won YeonIn-Kyu ChoiWon-Ho KimKyuseok Song
    • Jei-Won YeonIn-Kyu ChoiWon-Ho KimKyuseok Song
    • G01N27/333G01N27/26G01N21/01
    • G01N27/301
    • Disclosed herein is a reference electrode including an electrolyte containing an optically-active material, including: an electrode body provided at an end thereof with an electrolyte separation membrane and charged therein with an optically-active material and an electrolyte solution; an inner electrode disposed in the electrode body to be immersed in the electrolyte solution; and an absorbance measurement probe for transmitting light to the electrolyte solution and collecting reflected light waves, which is disposed in the electrode body to be immersed in the electrolyte solution. Since the concentration of an electrode reaction material, such as Cl−, in the electrolyte is calculated using the absorbance of the electrolyte solution containing the optically-active material, the change in potential of the reference electrode can be properly corrected even when the reference electrode is exposed to a test environment for a long period of time and thus the concentration of the electrolyte changes. Thus, the functions of the reference electrode can be maintained for a long period of time, thereby rapidly monitoring the abnormal states caused by damage to the reference electrode.
    • 本文公开了一种包括含有光学活性材料的电解质的参比电极,包括:电极体,其末端设置有电解质分离膜,并在其中装入光学活性材料和电解质溶液; 设置在所述电极体中以浸入所述电解质溶液中的内部电极; 以及用于将光透射到电解质溶液并收集被设置在电极体中以浸没在电解质溶液中的反射光波的吸光度测量探针。 由于使用含有光学活性物质的电解液的吸光度来计算电解质中的电极反应物质如Cl-的浓度,因此即使参考电极 长时间暴露于测试环境,因此电解质的浓度变化。 因此,可以长时间保持参考电极的功能,从而快速监视由参考电极损坏引起的异常状态。
    • 5. 发明申请
    • REFERENCE ELECTRODE HAVING SELF-CALIBRATION FUNCTION AND APPARATUS FOR AUTOMATICALLY CORRECTING ELECTROCHEMICAL POTENTIAL CORRECTION APPARATUS USING THE SAME
    • 具有自校准功能的参考电极和自动校正电化学电位校正装置的装置
    • US20100140088A1
    • 2010-06-10
    • US12330187
    • 2008-12-08
    • Jei-Won YEONIn-Kyu ChoiWon-Ho KimKyuseok Song
    • Jei-Won YEONIn-Kyu ChoiWon-Ho KimKyuseok Song
    • G01N27/416G01N27/30G01N27/26
    • G01N27/301
    • Disclosed herein is a reference electrode having a self-calibration function, which is used in electrochemical measurement and whose measurement accuracy can be maintained for a long period of time. Also disclosed is an apparatus for automatically correcting electrochemical potential using the reference electrode. The apparatus comprises: a reference electrode, comprising an external electrode body having an electrolyte membrane at one end thereof and an electrolyte solution filled therein, and at least two electrically isolated internal electrodes which are disposed in the external electrode body in such a manner that they are immersed in the electrolyte solution; and a reference potential calibrator for applying AC voltage to the internal electrodes to measure the electrical conductivity of the electrolyte solution of the electrolyte solution and output a correction signal about the change in the reference potential of the reference electrode. The reference electrode and the apparatus can suitably calibrate the change in the potential of the reference electrode by measuring the internal electrolyte of the reference electrode and calculating the concentration of the internal electrolyte, and thus the function of the reference electrode can be maintained for a long period of time.
    • 本文公开了具有自校正功能的参考电极,其用于电化学测量并且其测量精度可以长时间保持。 还公开了一种使用参考电极自动校正电化学电位的装置。 该装置包括:参考电极,包括在其一端具有电解质膜的外部电极体和填充有电解质溶液的外部电极体,以及至少两个电隔离的内部电极,其设置在外部电极体中, 浸入电解质溶液中; 以及用于向内部电极施加AC电压以测量电解质溶液的电解液的电导率并且输出关于参考电极的参考电位的变化的校正信号的参考电位校准器。 参考电极和设备可以通过测量参考电极的内部电解质并计算内部电解质的浓度来适当地校准参考电极的电位变化,因此参考电极的功能可以保持长时间 一段的时间。
    • 7. 发明申请
    • Device for On-Site Measurement of Concentration of Uranium in High Temperature Molten Salts
    • 用于现场测量高温熔盐中铀浓度的装置
    • US20120026495A1
    • 2012-02-02
    • US12977530
    • 2010-12-23
    • Yong Joon ParkSang Eun BaeYoung-Hwan ChoKyuseok Song
    • Yong Joon ParkSang Eun BaeYoung-Hwan ChoKyuseok Song
    • G01J3/28
    • G01N21/31G01N21/0303G01N21/8507G01N2021/8528G01N2201/0846G21C17/06
    • A device for on-site measurement of concentration of uranium in high temperature molten salts is provided. More particularly, to a device for on-site measurement of concentration of uranium in high temperature molten salts that can be directly applied to a pyroprocess for reusing spent nuclear fuel and determine concentration of uranium 3+ and 4+ chemical species using ultraviolet-visible light absorption spectrometry. The device includes first and second optical waveguides submerged in molten salts including uranium through a port formed at an upper side of a pyrochemical process apparatus; a lengthwise driver installed at the port to be operated to adjust a distance between the optical waveguides; a light source for supplying light to the second optical waveguide as any one of the optical waveguides; and a spectrometer connected to the first optical waveguide as the other one of the optical waveguides to analyze the light emitted from the second optical waveguide and introduced through the first optical waveguide via the molten salts.
    • 提供了用于现场测量高温熔盐中铀浓度的装置。 更具体地,涉及用于现场测量高温熔融盐中的铀浓度的装置,其可以直接应用于用于再利用乏核燃料的焦化过程并且使用紫外可见光确定铀3+和4+化学物质的浓度 吸收光谱法。 该装置包括浸没在熔融盐中的第一和第二光波导,包括通过形成在焦化工艺装置上侧的端口的铀; 安装在要操作的端口处的纵向驱动器,以调节光波导之间的距离; 用于向所述第二光波导提供光作为任何一个所述光波导的光源; 以及连接到第一光波导的光谱仪,作为另一个光波导,用于分析从第二光波导发射并经由熔融盐引入第一光波导的光。