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    • 1. 发明授权
    • Molded articles of plastics having improved surface characteristics and
process for producing the same
    • 具有改进的表面特性的塑料模制品及其制造方法
    • US3968309A
    • 1976-07-06
    • US526727
    • 1974-11-25
    • Makoto MatsuoTakao SuzukiKeisuke YoshiharaTuneo IkedaKunio Chikanishi
    • Makoto MatsuoTakao SuzukiKeisuke YoshiharaTuneo IkedaKunio Chikanishi
    • B29C45/00B29D11/00C08J7/04B32B27/30
    • C08J7/047B29C45/0001B29D11/00865C08J2433/00Y10S428/918Y10T428/31Y10T428/31855Y10T428/31928Y10T428/31935
    • A molded article of plastic having on its surface a cured film of a coating material comprising at least 30% by weight of at least one polyfunctional compound selected from the group consisting of poly-methacryloyloxy compounds having a molecular weight of 250 to 800 and containing at least three methacryloyloxy groups in the molecule and poly-acryloyloxy compounds having a molecular weight of 250 to 800 and containing at least three acryloyloxy groups in the molecule, and optionally 0.01 to 5% by weight of a fluorine-containing surfactant and 0.01 to 5% by weight of a carbonyl compound as photosensitizer has improved surface characteristics, particularly a high surface hardness, a high surface smoothness, high heat resistance, high abrasion resistance and a minimized optical distortion. Said molded article of plastic having improved surface characteristics can be prepared by coating the molded substrate of plastic with said coating material to a thickness of 1 to 50.mu. and then subjecting the coated article to a light of 2,000 to 8,000 A in an inert atmosphere to cure the coating material.
    • 一种塑料模制品,其表面上具有包含至少30重量%的至少一种多官能化合物的涂层材料的固化膜,所述多官能化合物选自分子量为250至800的聚甲基丙烯酰氧基化合物,并且含有 分子中至少有三个甲基丙烯酰氧基和分子量为250-800的聚丙烯酰氧基化合物,并且在分子中含有至少三个丙烯酰氧基,和任选地0.01至5重量%的含氟表面活性剂和0.01至5重量% 作为光敏剂的羰基化合物具有改善的表面特性,特别是高表面硬度,高表面平滑性,高耐热性,高耐磨性和最小化的光学变形。 具有改善的表面特性的所述塑料模塑制品可以通过用所述涂层材料涂覆塑料模塑基材至1至50微米的厚度来制备,然后在惰性气氛中对涂覆的制品进行2,000至8,000A的光照, 固化涂料。