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    • 1. 发明授权
    • Method for producing nanoparticle/block copolymer composites and devices containing the same
    • 制备纳米颗粒/嵌段共聚物复合材料的方法及其制备方法
    • US08535973B2
    • 2013-09-17
    • US12458232
    • 2009-07-06
    • Eun Joo JangKook Heon Char
    • Eun Joo JangKook Heon Char
    • H01L51/40
    • C09K11/02B82Y30/00C08J5/005C08J2387/00C09K11/025C09K11/565C09K11/883H01L33/502H01L51/426
    • A method for producing nanoparticle/block copolymer composites is provided. The method includes mixing nanoparticles having an organic ligand L and a block copolymer A-b-B having block repeating units A and B with different solubility parameters in a solvent S to form micelles by self-assembly. The solubility parameters of the organic ligand L, the block repeating units A and B of the block copolymer A-b-B and the solvent S satisfy the following inequalities: 29≦δS−δA  (1) δS−δB≦29  (2) |δL−δA|≦5 or |δL−δB|≦5  (3) in which δS, δA, δB and δL represent the solubility parameters of the solvent S, the block repeating unit A, the block repeating unit B and the ligand L, respectively. According to the method, the inherent electrical, magnetic, optical, chemical and mechanical properties of the nanoparticles can be maintained or improved without the need to modify the surface of the nanoparticles.
    • 提供了制备纳米颗粒/嵌段共聚物复合材料的方法。 该方法包括将具有有机配体L的纳米颗粒和具有不同溶解度参数的嵌段重复单元A和B的嵌段共聚物A-b-B混合在溶剂S中以通过自组装形成胶束。 有机配体L,嵌段共聚物AbB和溶剂S的嵌段重复单元A和B的溶解度参数满足以下不等式:29 @ delta-δA(1)δS-ΔB@ 29(2)|δL-ΔA |δ5或ΔL-ΔB| @ 5(3)其中δS,δA,δB和δL分别表示溶剂S,嵌段重复单元A,嵌段重复单元B和配体L的溶解度参数。 根据该方法,可以维持或改善纳米颗粒的固有电,磁,光学,化学和机械性能,而不需要改变纳米颗粒的表面。
    • 7. 发明申请
    • Method for producing nanoparticle/block copolymer composites
    • 制备纳米颗粒/嵌段共聚物复合材料的方法
    • US20100148156A1
    • 2010-06-17
    • US12458232
    • 2009-07-06
    • Eun Joo JangKook Heon Char
    • Eun Joo JangKook Heon Char
    • H01L51/30H01L51/40
    • C09K11/02B82Y30/00C08J5/005C08J2387/00C09K11/025C09K11/565C09K11/883H01L33/502H01L51/426
    • A method for producing nanoparticle/block copolymer composites is provided. The method includes mixing nanoparticles having an organic ligand L and a block copolymer A-b-B having block repeating units A and B with different solubility parameters in a solvent S to form micelles by self-assembly. The solubility parameters of the organic ligand L, the block repeating units A and B of the block copolymer A-b-B and the solvent S satisfy the following inequalities: 29≦δS−δA  (1) δS−δB≦29  (2) |δL−δA|≦5 or |δL−δB|≦5  (3) in which δS, δA, δB and δL represent the solubility parameters of the solvent S, the block repeating unit A, the block repeating unit B and the ligand L, respectively. According to the method, the inherent electrical, magnetic, optical, chemical and mechanical properties of the nanoparticles can be maintained or improved without the need to modify the surface of the nanoparticles.
    • 提供了制备纳米颗粒/嵌段共聚物复合材料的方法。 该方法包括将具有有机配体L的纳米颗粒和具有不同溶解度参数的嵌段重复单元A和B的嵌段共聚物A-b-B混合在溶剂S中以通过自组装形成胶束。 有机配体L,嵌段共聚物AbB和溶剂S的嵌段重复单元A和B的溶解度参数满足以下不等式:29≦̸δS-δA(1)δS-δB≦̸ 29(2)|δL-δA 其中δS,δA,δB和δL表示溶剂S的溶解度参数,嵌段重复单元A,嵌段重复单元B和配体L,其中δS,δA,δB和δL代表溶剂S的溶解度参数, 分别。 根据该方法,可以维持或改善纳米颗粒的固有电,磁,光学,化学和机械性能,而不需要改变纳米颗粒的表面。