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1. 发明申请

US20080051600A1 PROCESS FOR PRODUCING TRANS-1, 4-CYCLOHEXANEDICARBOXYLIC ACID 有权
标题翻译：生产转-1,4-环己基二羧酸的方法
公开(公告)号：US20080051600A1
公开(公告)日：2008-02-28
申请号：US11924161
申请日：2007-10-25
申请人： Koetsu ENDOU , Hirofumi Nakamura , Shinichi Tanaka
发明人： Koetsu ENDOU , Hirofumi Nakamura , Shinichi Tanaka
IPC分类号： C07C61/08
CPC分类号： C07C51/353 , C07C51/363 , C07C2601/14 , C07C61/09
摘要： A subject for the invention is to obtain trans-1,4-cyclohexanedicarboxylic acid (t-CHDA) in a high concentration by efficiently isomerizing cis-1,4-cyclohexanedicarboxylic acid (c-CHDA) by a simple method. The invention provides: (1) a process for producing t-CHDA which comprises heating crude CHDA to 180° C. or higher in an inert atmosphere and causing the t-CHDA formed by isomerization to precipitate in the molten c-CHDA while holding the crude CHDA at a temperature in the range of not lower than 180° C. and less than the melting point of t-CHDA; (2) a process for producing t-CHDA, wherein crude CHDA which is powdery or granular is heat-treated at a temperature of not lower than the melting point of c-CHDA and lower than the melting point of t-CHDA to thereby isomerize the cis isomer to the trans isomer while maintaining the powdery or granular state; (3) a process for producing t-CHDA, wherein crude CHDA is held at a temperature of not lower than the melting point of c-CHDA and lower than the melting point of t-CHDA in an inert atmosphere while maintaining flowing to thereby obtain powdery or granular t-CHDA; and (4) a process for purifying crude CHDA in which crude CHDA obtained through the step of hydrogenating TPA or the like is heated in an atmosphere of an inert gas to volatilize and remove impurities.
摘要翻译：本发明的目的是通过简单的方法有效地使顺式-1,4-环己烷二羧酸（c-CHDA）异构化，以高浓度获得反式-1,4-环己烷二羧酸（t-CHDA）。本发明提供：（1）一种生产t-CHDA的方法，其包括在惰性气氛中将粗CHDA加热至180℃或更高，并使通过异构化形成的t-CHDA在熔融的c-CHDA中沉淀，同时保持原料CHDA在不低于180℃且小于t-CHDA的熔点的温度范围内; （2）生产t-CHDA的方法，其中将粉末状或粒状的粗CHDA在不低于c-CHDA的熔点并低于t-CHDA的熔点的温度下进行热处理，从而异构化顺式异构体反式异构体，同时保持粉状或颗粒状态; （3）生产t-CHDA的方法，其中将粗CHDA保持在不低于c-CHDA的熔点并低于在惰性气氛中的t-CHDA的熔点的温度，同时保持流动，从而获得粉状或颗粒状t-CHDA; （4）一种纯化粗制CHDA的方法，其中通过氢化TPA等步骤得到的粗CHDA在惰性气体气氛中加热，挥发除去杂质。

2. 发明授权

US06294703B1 Process for the manufacture of cycloalkyldimethanol 有权
标题翻译：制备环烷基二甲醇的方法
公开(公告)号：US06294703B1
公开(公告)日：2001-09-25
申请号：US09337521
申请日：1999-06-22
申请人： Yoshinori Hara , Koetsu Endou , Hiroko Takahashi
发明人： Yoshinori Hara , Koetsu Endou , Hiroko Takahashi
IPC分类号： C07C3113
CPC分类号： B01J23/96 , C07C29/149 , C07C2601/14 , C12C11/02 , Y02P20/584 , C07C31/276
摘要： A process for making cycloalkyldimethanol, includes hydrogenating at least one cycloalkyldicarboxylic acid and/or an alkyl ester thereof with a catalyst, to produce a cycloalkyldimethanol, where the catalyst contains ruthenium, tin and platinum. Also, a method for regenerating a used catalyst, includes contacting the used catalyst with a base, where the catalyst includes ruthenium, tin and platinum.
摘要翻译：制备环烷基二甲醇的方法包括用催化剂将至少一种环烷基二羧酸和/或其烷基酯氢化，生成环烷基二甲醇，其中催化剂含有钌，锡和铂。而且，再生所用催化剂的方法包括将所用催化剂与碱接触，其中催化剂包括钌，锡和铂。

3. 发明授权

US07595423B2 Process for producing trans-1,4-cyclohexanedicarboxylic acid 有权
标题翻译：反式-1,4-环己烷二羧酸的制备方法
公开(公告)号：US07595423B2
公开(公告)日：2009-09-29
申请号：US11924161
申请日：2007-10-25
申请人： Koetsu Endou , Hirofumi Nakamura , Shinichi Tanaka
发明人： Koetsu Endou , Hirofumi Nakamura , Shinichi Tanaka
IPC分类号： C07C61/00
CPC分类号： C07C51/353 , C07C51/363 , C07C2601/14 , C07C61/09
摘要： A subject for the invention is to obtain trans-1,4-cyclohexanedicarboxylic acid (t-CHDA) in a high concentration by efficiently isomerizing cis-1,4-cyclohexanedicarboxylic acid (c-CHDA) by a simple method. The invention provides: (1) a process for producing t-CHDA which comprises heating crude CHDA to 180° C. or higher in an inert atmosphere and causing the t-CHDA formed by isomerization to precipitate in the molten c-CHDA while holding the crude CHDA at a temperature in the range of not lower than 180° C. and less than the melting point of t-CHDA; (2) a process for producing t-CHDA, wherein crude CHDA which is powdery or granular is heat-treated at a temperature of not lower than the melting point of c-CHDA and lower than the melting point of t-CHDA to thereby isomerize the cis isomer to the trans isomer while maintaining the powdery or granular state; (3) a process for producing t-CHDA, wherein crude CHDA is held at a temperature of not lower than the melting point of c-CHDA and lower than the melting point of t-CHDA in an inert atmosphere while maintaining flowing to thereby obtain powdery or granular t-CHDA; and (4) a process for purifying crude CHDA in which crude CHDA obtained through the step of hydrogenating TPA or the like is heated in an atmosphere of an inert gas to volatilize and remove impurities.
摘要翻译：本发明的目的是通过简单的方法有效地使顺式-1,4-环己烷二羧酸（c-CHDA）异构化，以高浓度获得反式-1,4-环己烷二羧酸（t-CHDA）。本发明提供：（1）一种生产t-CHDA的方法，其包括在惰性气氛中将粗CHDA加热至180℃或更高，并使通过异构化形成的t-CHDA在熔融的c-CHDA中沉淀，同时保持原料CHDA在不低于180℃且小于t-CHDA的熔点的温度范围内; （2）生产t-CHDA的方法，其中将粉末状或粒状的粗CHDA在不低于c-CHDA的熔点并低于t-CHDA的熔点的温度下进行热处理，从而异构化顺式异构体反式异构体，同时保持粉状或颗粒状态; （3）生产t-CHDA的方法，其中将粗CHDA保持在不低于c-CHDA的熔点并低于在惰性气氛中的t-CHDA的熔点的温度，同时保持流动，从而获得粉状或颗粒状t-CHDA; （4）一种纯化粗制CHDA的方法，其中通过氢化TPA等步骤得到的粗CHDA在惰性气体气氛中加热，挥发除去杂质。

4. 发明申请

US20050014973A1 Process for producing trans-1,4-cyclohexanedicarboxylic acid 有权
标题翻译：反式-1,4-环己烷二羧酸的制备方法
公开(公告)号：US20050014973A1
公开(公告)日：2005-01-20
申请号：US10831156
申请日：2004-04-26
申请人： Koetsu Endou , Hirofumi Nakamura , Shinichi Tanaka
发明人： Koetsu Endou , Hirofumi Nakamura , Shinichi Tanaka
IPC分类号： C07C51/353 , C07C51/363 , C07C61/24
CPC分类号： C07C51/353 , C07C51/363 , C07C2601/14 , C07C61/09
摘要： A subject for the invention is to obtain trans-1,4-cyclohexanedicarboxylic acid (t-CHDA) in a high concentration by efficiently isomerizing cis-1,4-cyclohexanedicarboxylic acid (c-CHDA) by a simple method. The invention provides: (1) a process for producing t-CHDA which comprises heating crude CHDA to 180° C. or higher in an inert atmosphere and causing the t-CHDA formed by isomerization to precipitate in the molten c-CHDA while holding the crude CHDA at a temperature in the range of not lower than 180° C. and less than the melting point of t-CHDA; (2) a process for producing t-CHDA, wherein crude CHDA which is powdery or granular is heat-treated at a temperature of not lower than the melting point of c-CHDA and lower than the melting point of t-CHDA to thereby isomerize the cis isomer to the trans isomer while maintaining the powdery or granular state; (3) a process for producing t-CHDA, wherein crude CHDA is held at a temperature of not lower than the melting point of c-CHDA and lower than the melting point of t-CHDA in an inert atmosphere while maintaining flowing to thereby obtain powdery or granular t-CHDA; and (4) a process for purifying crude CHDA in which crude CHDA obtained through the step of hydrogenating TPA or the like is heated in an atmosphere of an inert gas to volatilize and remove impurities.
摘要翻译：本发明的目的是通过简单的方法有效地使顺式-1,4-环己烷二羧酸（c-CHDA）异构化，以高浓度获得反式-1,4-环己烷二羧酸（t-CHDA）。本发明提供：（1）一种生产t-CHDA的方法，其包括在惰性气氛中将粗CHDA加热至180℃或更高，并使通过异构化形成的t-CHDA在熔融的c-CHDA中沉淀，同时保持原料CHDA在不低于180℃且小于t-CHDA的熔点的温度范围内; （2）生产t-CHDA的方法，其中将粉末状或粒状的粗CHDA在不低于c-CHDA的熔点并低于t-CHDA的熔点的温度下进行热处理，从而异构化顺式异构体反式异构体，同时保持粉状或颗粒状态; （3）生产t-CHDA的方法，其中将粗CHDA保持在不低于c-CHDA的熔点并低于在惰性气氛中的t-CHDA的熔点的温度，同时保持流动，从而获得粉状或颗粒状t-CHDA; （4）一种纯化粗制CHDA的方法，其中通过氢化TPA等步骤得到的粗CHDA在惰性气体气氛中加热，挥发除去杂质。

5. 发明授权

US5969194A Process for preparing 1, 6-hexanediol 失效
标题翻译：制备1,6-己二醇的方法
公开(公告)号：US5969194A
公开(公告)日：1999-10-19
申请号：US034334
申请日：1998-03-04
申请人： Yoshinori Hara , Koetsu Endou , Seijiro Nishimura
发明人： Yoshinori Hara , Koetsu Endou , Seijiro Nishimura
IPC分类号： C07C29/149 , C07C27/10 , C07C31/18
CPC分类号： C07C29/149
摘要： A process for preparing 1,6-hexanediol comprising hydrogenating a starting material containing at least one compound selected from the group consisting of adipic acid, .epsilon.-hydroxycaproic acid, .epsilon.-caprolactone and oligomers of .epsilon.-caprolactone, preferably a substance recovered from a reaction mixture resulting from liquid phase oxidization of cyclohexane for the production of cyclohexanol and cyclohexanone, in a liquid phase in the presence of a solid catalyst containing ruthenium and tin.
摘要翻译：一种制备1,6-己二醇的方法，包括将含有至少一种选自己二酸，ε-羟基己酸，ε-己内酯和ε-己内酯的低聚物的起始材料氢化，优选从反应回收的物质在含有钌和锡的固体催化剂的存在下，在液相中由环己烷的液相氧化产生环己醇和环己酮的混合物。

6. 发明授权

US07420086B2 Process for producing trans-1,4-cyclohexanedicarboxylic acid 有权
标题翻译：反式-1,4-环己烷二羧酸的制备方法
公开(公告)号：US07420086B2
公开(公告)日：2008-09-02
申请号：US10831156
申请日：2004-04-26
申请人： Koetsu Endou , Hirofumi Nakamura , Shinichi Tanaka
发明人： Koetsu Endou , Hirofumi Nakamura , Shinichi Tanaka
IPC分类号： C07C61/00
CPC分类号： C07C51/353 , C07C51/363 , C07C2601/14 , C07C61/09
摘要： A subject for the invention is to obtain trans-1,4-cyclohexanedicarboxylic acid (t-CHDA) in a high concentration by efficiently isomerizing cis-1,4-cyclohexanedicarboxylic acid (c-CHDA) by a simple method. The invention provides: (1) a process for producing t-CHDA which comprises heating crude CHDA to 180° C. or higher in an inert atmosphere and causing the t-CHDA formed by isomerization to precipitate in the molten c-CHDA while holding the crude CHDA at a temperature in the range of not lower than 180° C. and less than the melting point of t-CHDA; (2) a process for producing t-CHDA, wherein crude CHDA which is powdery or granular is heat-treated at a temperature of not lower than the melting point of c-CHDA and lower than the melting point of t-CHDA to thereby isomerize the cis isomer to the trans isomer while maintaining the powdery or granular state; (3) a process for producing t-CHDA, wherein crude CHDA is held at a temperature of not lower than the melting point of c-CHDA and lower than the melting point of t-CHDA in an inert atmosphere while maintaining flowing to thereby obtain powdery or granular t-CHDA; and (4) a process for purifying crude CHDA in which crude CHDA obtained through the step of hydrogenating TPA or the like is heated in an atmosphere of an inert gas to volatilize and remove impurities.
摘要翻译：本发明的目的是通过简单的方法有效地使顺式-1,4-环己烷二羧酸（c-CHDA）异构化，以高浓度获得反式-1,4-环己烷二羧酸（t-CHDA）。本发明提供：（1）一种生产t-CHDA的方法，其包括在惰性气氛中将粗CHDA加热至180℃或更高，并使通过异构化形成的t-CHDA在熔融的c-CHDA中沉淀，同时保持原料CHDA在不低于180℃且小于t-CHDA的熔点的温度范围内; （2）生产t-CHDA的方法，其中将粉末状或粒状的粗CHDA在不低于c-CHDA的熔点并低于t-CHDA的熔点的温度下进行热处理，从而异构化顺式异构体反式异构体，同时保持粉状或颗粒状态; （3）生产t-CHDA的方法，其中将粗CHDA保持在不低于c-CHDA的熔点并低于在惰性气氛中的t-CHDA的熔点的温度，同时保持流动，从而获得粉状或颗粒状t-CHDA; （4）一种纯化粗制CHDA的方法，其中通过氢化TPA等步骤得到的粗CHDA在惰性气体气氛中加热，挥发除去杂质。

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