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1. 发明授权

US07217462B2 Metal foil-clad laminate 有权
标题翻译：金属箔覆层压板
公开(公告)号：US07217462B2
公开(公告)日：2007-05-15
申请号：US10841432
申请日：2004-05-10
申请人： Shuta Kihara , Ko Kedo
发明人： Shuta Kihara , Ko Kedo
IPC分类号： B32B15/08
CPC分类号： B32B27/281 , B32B7/12 , B32B15/08 , B32B27/34 , H05K3/386 , H05K2201/0154 , H05K2203/0759 , Y10S428/901 , Y10T428/31681 , Y10T428/31721
摘要： The metal foil-clad laminate of the present invention comprises at least one polyimide layer made of a polyimide having repeating units represented by the following formula I: wherein R and Φ are as defined in the specification, at least one insulating substrate, and at least one metal foil layer. The polyimide is excellent in thermopress-bonding property, solubility in solvents and heat resistance, and exhibits a low dielectric constant. The metal foil-clad laminate having the polyimide layer is suitably applicable to high-frequency printed wiring boards, etc.
摘要翻译：本发明的覆金属箔的层压体包含至少一层由聚酰亚胺构成的聚酰亚胺层，该聚酰亚胺具有由下式I表示的重复单元：其中R和Phi如说明书中所定义，至少一个绝缘基材，至少一个金属箔层。聚酰亚胺具有优异的耐热粘合性，在溶剂中的溶解性和耐热性，并且表现出低的介电常数。具有聚酰亚胺层的金属箔覆层压板适用于高频印刷线路板等

2. 发明授权

US06962756B2 Transparent electrically-conductive film and its use 有权
标题翻译：透明导电膜及其用途
公开(公告)号：US06962756B2
公开(公告)日：2005-11-08
申请号：US10284370
申请日：2002-10-31
申请人： Shuta Kihara , Hiroki Oguro , Ko Kedo
发明人： Shuta Kihara , Hiroki Oguro , Ko Kedo
IPC分类号： C08J5/18 , C08G73/10 , G02F1/1343 , H01L51/52 , H05B33/12 , B32B27/28
CPC分类号： C08G73/10 , G02F1/13439 , H01L51/5206 , H01L51/5237 , Y10T428/1023 , Y10T428/31504 , Y10T428/31721
摘要： A transparent electrically-conductive film comprising a substrate made of an aliphatic polyimide having a repeating unit of the formula [I] and a transparent electrically-conductive thin film layer, the transparent electrically-conductive thin film layer being provided on the substrate, wherein R is a tetravalent aliphatic group having 4 to 39 carbon atoms and Φ is a divalent aliphatic group having 1 to 39 carbon atoms or a divalent aromatic group having 6 to 39 carbon atoms; an organic EL element using the above film; a thin-film transistor substrate comprising a substrate formed of a film of a polyimide having a repeating unit of the formula [I] and, provided thereon, a thin-film transistor; and an organic EL element using the above transistor substrate.
摘要翻译：一种透明导电膜，其包含由具有式[I]的重复单元的脂族聚酰亚胺和透明导电薄膜层构成的基板，所述透明导电薄膜层设置在所述基板上，其中R 是具有4〜39个碳原子的四价脂肪族基团，Phi是碳原子数1〜39的2价脂肪族基团或碳原子数6〜39的2价芳香族基团。使用上述膜的有机EL元件; 薄膜晶体管基板，包括由具有式[I]的重复单元的聚酰亚胺膜形成的基板，并且在其上设置有薄膜晶体管; 以及使用上述晶体管基板的有机EL元件。

3. 发明授权

US08642181B2 Metal-clad white laminate 有权
标题翻译：金属包层白色层压板
公开(公告)号：US08642181B2
公开(公告)日：2014-02-04
申请号：US11574165
申请日：2005-08-19
申请人： Jitsuo Oishi , Shuta Kihara , Ko Kedo , Takakiyo Mine
发明人： Jitsuo Oishi , Shuta Kihara , Ko Kedo , Takakiyo Mine
IPC分类号： B32B15/08 , B32B9/00
CPC分类号： H05K3/386 , B32B7/12 , C09J179/08 , H05K1/0274 , H05K1/0346 , H05K1/0373 , H05K3/022 , H05K2201/0154 , H05K2201/0209 , H05K2201/0358 , H05K2201/2054 , Y10T428/12569 , Y10T428/2949 , Y10T428/2962 , Y10T428/31681
摘要： The present invention provides a metal-clad white laminate including: a white resin layer which is composed of a resin composition obtained by mixing a polyimide having a repeating unit as represented by a particular chemical structural formula with a white pigment; and at least one metal layer, the white resin layer being an adhesive layer for the metal layer. The metal-clad white laminate of the present invention uses a white resin composition which has high reflectance and whiteness and excellent light resistance, and is easy to be reduced in thickness and weight.
摘要翻译：本发明提供一种金属包覆白色层压体，其包括：白色树脂层，其由通过将具有由特定化学结构式表示的重复单元的聚酰亚胺与白色颜料混合而获得的树脂组合物组成; 和至少一个金属层，所述白色树脂层是用于所述金属层的粘合剂层。本发明的金属包覆白色层叠体使用白色树脂组合物，其具有高反射率和白度以及优异的耐光性，并且易于降低厚度和重量。

4. 发明申请

US20050037213A1 Metal foil-clad laminate 有权
标题翻译：金属箔覆层压板
公开(公告)号：US20050037213A1
公开(公告)日：2005-02-17
申请号：US10841432
申请日：2004-05-10
申请人： Shuta Kihara , Ko Kedo
发明人： Shuta Kihara , Ko Kedo
IPC分类号： B32B15/08 , B32B27/34 , H05K3/38
CPC分类号： B32B27/281 , B32B7/12 , B32B15/08 , B32B27/34 , H05K3/386 , H05K2201/0154 , H05K2203/0759 , Y10S428/901 , Y10T428/31681 , Y10T428/31721
摘要： The metal foil-clad laminate of the present invention comprises at least one polyimide layer made of a polyimide having repeating units represented by the following formula I: wherein R and Φ are as defined in the specification, at least one insulating substrate, and at least one metal foil layer. The polyimide is excellent in thermopress-bonding property, solubility in solvents and heat resistance, and exhibits a low dielectric constant. The metal foil-clad laminate having the polyimide layer is suitably applicable to high-frequency printed wiring boards, etc.
摘要翻译：本发明的覆金属箔的层压体包含至少一层由聚酰亚胺构成的聚酰亚胺层，该聚酰亚胺具有由下式I表示的重复单元：其中R和Phi如说明书中所定义，至少一个绝缘基材，至少一个金属箔层。聚酰亚胺具有优异的耐热粘合性，在溶剂中的溶解性和耐热性，并且表现出低的介电常数。具有聚酰亚胺层的金属箔覆层压板适用于高频印刷线路板等

5. 发明授权

US06541662B2 Process for producing a hydrogenation product of an aromatic carboxylic acid 失效
标题翻译：制备芳族羧酸的氢化产物的方法
公开(公告)号：US06541662B2
公开(公告)日：2003-04-01
申请号：US10021430
申请日：2001-12-19
申请人： Hiroshi Machida , Ko Kedo , Fumiya Zaima
发明人： Hiroshi Machida , Ko Kedo , Fumiya Zaima
IPC分类号： C07C6109
CPC分类号： C07C51/36 , C07C61/12 , C07C61/125 , C07C61/09
摘要： A process for producing a hydrogenation product of aromatic carboxylic acid which comprises continuously producing the hydrogenation product of aromatic carboxylic acid by hydrogenating an aromatic carboxylic acid having a melting point of 250° C. or higher in a solvent in the presence of a solid catalyst, wherein the hydrogenation is conducted in a condition such that substantially the entire amount of the aromatic carboxylic acid of a raw material is dissolved in the solvent by recycling a portion of a reaction liquid taken out of a reactor into the reactor. An aromatic carboxylic acid having a high melting point and hardly soluble in solvents can be hydrogenated at a suitable reaction temperature in accordance with a continuous process without using a great amount of a solvent and the reaction product of the object compound can be produced very efficiently.
摘要翻译：一种芳族羧酸的氢化产物的制造方法，其特征在于，在固体催化剂存在下，通过在溶剂中氢化熔点为250℃以上的芳香族羧酸，连续制造芳香族羧酸的氢化物，其特征在于，氢化反应是将从反应器中取出的反应液的一部分再循环到反应器中，将原料的芳香族羧酸的总量全部溶解在溶剂中的方式进行。可以在不使用大量溶剂的情况下，根据连续方法在合适的反应温度下氢化不溶于溶剂的高熔点，并且可以非常有效地制备目标化合物的反应产物。

6. 发明授权

US07871554B2 Process for producing polyimide film 有权
标题翻译：聚酰亚胺薄膜的制造方法
公开(公告)号：US07871554B2
公开(公告)日：2011-01-18
申请号：US11911260
申请日：2006-04-10
申请人： Jitsuo Oishi , Takashi Makinoshima , Ko Kedo , Shuta Kihara
发明人： Jitsuo Oishi , Takashi Makinoshima , Ko Kedo , Shuta Kihara
IPC分类号： B29C55/02 , D02J1/22
CPC分类号： B29C55/04 , B29C41/28 , B29C55/005 , B29K2079/08 , C08G73/10 , C08G73/1028 , C08J5/18 , C08J2379/08 , H05K1/0346 , H05K3/0011 , H05K2201/0108 , H05K2201/0154 , H05K2203/0271
摘要： The invention is directed to a process for producing polyimide film, including stretching, at 150° C. to 380° C. and a stretch ratio of 1.2 to 4.0, an unstretched polyimide film which is formed from a polyimide having a repeating unit represented by formula (1): (wherein R represents a tetravalent group derived from cyclohexane; and Φ represents a divalent aliphatic, alicyclic, or aromatic group, or a combination thereof that has a total number of carbon atoms of 2 to 39 and may have at least one connecting group selected from the group consisting of —O—, —SO2—, —CO—, —CH2—, —C(CH3)2—, —OSi(CH3)2—, —C2H4O—, and —S—) and which has an organic solvent content of 0.5 wt. % or more and less than 30 wt. %. The produced polyimide film exhibits transparency, excellent heat resistance, and reduced dimensional changes.
摘要翻译：本发明涉及一种制备聚酰亚胺膜的方法，包括在150℃至380℃拉伸和拉伸比为1.2至4.0的拉伸倍数，由具有重复单元的聚酰亚胺形成的未拉伸聚酰亚胺膜，所述聚酰亚胺膜具有由式（1）表示：（式中，R表示环己烷衍生的四价基团，Φ表示碳原子数为2〜39的二价脂肪族，脂环族或芳香族基团或其组合，一个选自-O - ， - SO 2 - ， - CO - ， - CH 2 - ， - C（CH 3）2 - ， - O（CH 3）2 - ， - C 2 H 4 O-和-S-的连接基团）并且其有机溶剂含量为0.5wt。％以上且小于30重量％％。所生产的聚酰亚胺膜具有透明性，优异的耐热性和尺寸变化的降低。

7. 发明申请

US20070292709A1 Metal-Clad White Laminate 有权
标题翻译：金属包层白色层压板
公开(公告)号：US20070292709A1
公开(公告)日：2007-12-20
申请号：US11574165
申请日：2005-08-19
申请人： Jitsuo Oishi , Shuta Kihara , Ko Kedo , Takakiyo Mine
发明人： Jitsuo Oishi , Shuta Kihara , Ko Kedo , Takakiyo Mine
IPC分类号： B32B27/34 , B32B15/088 , C08G73/10 , H05K1/03 , C08J7/04 , B32B27/20
CPC分类号： H05K3/386 , B32B7/12 , C09J179/08 , H05K1/0274 , H05K1/0346 , H05K1/0373 , H05K3/022 , H05K2201/0154 , H05K2201/0209 , H05K2201/0358 , H05K2201/2054 , Y10T428/12569 , Y10T428/2949 , Y10T428/2962 , Y10T428/31681
摘要： The present invention provides a metal-clad white laminate including: a white resin layer which is composed of a resin composition obtained by mixing a polyimide having a repeating unit as represented by a particular chemical structural formula with a white pigment; and at least one metal layer, the white resin layer being an adhesive layer for the metal layer. The metal-clad white laminate of the present invention uses a white resin composition which has high reflectance and whiteness and excellent light resistance, and is easy to be reduced in thickness and weight.
摘要翻译：本发明提供一种金属包覆白色层压体，其包括：白色树脂层，其由通过将具有由特定化学结构式表示的重复单元的聚酰亚胺与白色颜料混合而获得的树脂组合物组成; 和至少一个金属层，所述白色树脂层是用于所述金属层的粘合剂层。本发明的金属包覆白色层叠体使用白色树脂组合物，其具有高反射率和白度以及优异的耐光性，并且易于降低厚度和重量。

8. 发明申请

US20090160089A1 Process for Producing Polyimide Film 有权
标题翻译：生产聚酰亚胺薄膜的方法
公开(公告)号：US20090160089A1
公开(公告)日：2009-06-25
申请号：US11911260
申请日：2006-04-10
申请人： Jitsuo Oishi , Takashi Makinoshima , Ko Kedo , Shuta Kihara
发明人： Jitsuo Oishi , Takashi Makinoshima , Ko Kedo , Shuta Kihara
IPC分类号： B29C55/02 , C08G73/10
CPC分类号： B29C55/04 , B29C41/28 , B29C55/005 , B29K2079/08 , C08G73/10 , C08G73/1028 , C08J5/18 , C08J2379/08 , H05K1/0346 , H05K3/0011 , H05K2201/0108 , H05K2201/0154 , H05K2203/0271
摘要： The invention is directed to a process for producing polyimide film, including stretching, at 150° C. to 380° C. and a stretch ratio of 1.2 to 4.0, an unstretched polyimide film which is formed from a polyimide having a repeating unit represented by formula (1): (wherein R represents a tetravalent group derived from cyclohexane; and Φ represents a divalent aliphatic, alicyclic, or aromatic group, or a combination thereof that has a total number of carbon atoms of 2 to 39 and may have at least one connecting group selected from the group consisting of —O—, —SO2—, —CO—, —CH2—, —C(CH3)2—, —OSi(CH3)2—, —C2H4O—, and —S—) and which has an organic solvent content of 0.5 wt. % or more and less than 30 wt. %. The produced polyimide film exhibits transparency, excellent heat resistance, and reduced dimensional changes.
摘要翻译：本发明涉及一种制备聚酰亚胺膜的方法，包括在150℃至380℃拉伸和拉伸比为1.2至4.0的拉伸倍数，由具有重复单元的聚酰亚胺形成的未拉伸聚酰亚胺膜，所述聚酰亚胺膜具有由式（1）表示：（式中，R表示来自环己烷的四价基团，Phi表示碳原子数为2〜39的二价脂肪族，脂环族或芳香族基团或其组合，一个选自-O - ， - SO 2 - ， - CO - ， - CH 2 - ， - C（CH 3）2 - ， - O（CH 3）2 - ， - C 2 H 4 O-和-S-的连接基团）并且其有机溶剂含量为0.5wt。％以上且小于30重量％％。所生产的聚酰亚胺膜具有透明性，优异的耐热性和尺寸变化的降低。

9. 发明授权

US5436381A Process for producing a monoalkenyl aromatic hydrocarbon compound 失效
标题翻译：单链烯基芳烃化合物的制造方法
公开(公告)号：US5436381A
公开(公告)日：1995-07-25
申请号：US170495
申请日：1993-12-20
申请人： Makoto Takagawa , Kinji Kato , Norio Fushimi , Ko Kedo
发明人： Makoto Takagawa , Kinji Kato , Norio Fushimi , Ko Kedo
IPC分类号： B01J23/04 , C07B61/00 , C07C2/66 , C07C2/72 , C07C15/44
CPC分类号： B01J23/04 , C07C2/72 , C07C2521/04 , C07C2523/04
摘要： There is disclosed a process for producing a monoalkenylbenzene which comprises alkenylating a side chain of an aromatic hydrocarbon compound having at least one hydrogen atom bonded at .alpha.-position of the side chain (such as xylene) with a conjugated diene having 4 or 5 carbon atoms (such as butadiene) in the presence of a catalyst produced by calcining the mixture of potassium hydroxide and aluminum hydroxide and then heat treating the calcined product together with metallic sodium in an atmosphere of an inert gas. According to the aforesaid process, an industrially useful monoalkenylbenzene can be produced in high yield at a low cost with enhanced safety.
摘要翻译：公开了一种单链烯基苯的制备方法，该方法包括将具有至少一个在侧链（例如二甲苯）的α位键合的氢原子的芳族烃化合物的侧链与具有4或5个碳原子的共轭二烯链烯基化（例如丁二烯）在通过煅烧氢氧化钾和氢氧化铝的混合物产生的催化剂存在下，然后在惰性气体气氛中与金属钠一起热处理煅烧产物。根据上述方法，可以低成本，高安全性地以高产率生产工业上有用的单烯基苯。

10. 发明授权

US5334794A Process for producing monoalkenyl aromatic hydrocarbon compound 失效
标题翻译：单链烯基芳烃化合物的制备方法
公开(公告)号：US5334794A
公开(公告)日：1994-08-02
申请号：US47811
申请日：1993-04-15
申请人： Norio Fushimi , Ko Kedo , Kenji Inamasa , Makoto Takagawa
发明人： Norio Fushimi , Ko Kedo , Kenji Inamasa , Makoto Takagawa
IPC分类号： B01J23/04 , C07B61/00 , C07C2/72 , C07C15/44
CPC分类号： B01J23/04 , C07C2/72 , C07C2521/06 , C07C2523/04
摘要： A process for producing a monoalkenyl aromatic hydrocarbon compound which comprises alkenylating a side chain of an aromatic hydrocarbon compound having at least one hydrogen atom bonded at an .alpha.-position of the side chain (such as xylene) with a conjugated diene having 4 or 5 carbon atoms (such as butadiene) in the presence of a catalyst comprising a mixture obtained by heat treating metallic sodium together with a mixture of a zirconium oxide and a potassium compound in an inert gas atmosphere. An industrially useful monoalkenyl aromatic hydrocarbon compound is produced in a high yield at a low cost with enhanced safety from a specific aromatic hydrocarbon compound and a specific conjugated diene compound.
摘要翻译：一种单链烯基芳族烃化合物的制造方法，其特征在于，将具有至少一个在侧链的α位键合的氢原子（例如二甲苯）的芳香族烃化合物的侧链与具有4或5个碳原子的共轭二烯在包含通过在惰性气体气氛中将金属钠与氧化锆和钾化合物的混合物一起热处理获得的混合物的催化剂存在下的原子（例如丁二烯）。以低成本高产率生产工业上有用的单链烯基芳烃化合物，从特定芳烃化合物和特定共轭二烯化合物的安全性提高。

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