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    • 3. 发明申请
    • PROCESS AND APPARATUS FOR THE POLYMERISATION OF OLEFINS
    • 烯烃聚合的方法和装置
    • US20130253148A1
    • 2013-09-26
    • US13988794
    • 2011-12-14
    • Andrew David BellJean-Louis ChamayouKevin Peter Ramsay
    • Andrew David BellJean-Louis ChamayouKevin Peter Ramsay
    • C08F2/34
    • C08F10/00C08F2/34C08F110/02C08F2/007
    • The present invention relates to a process for the gas-phase polymerisation of olefins in a fluidised bed reactor, which process comprises: a) passing a fluidising gas comprising one or more olefin monomers through a fluidised bed of polymer particles in the presence of a polymerisation catalyst, b) withdrawing a first gaseous stream comprising solid particles from the top of the reactor, c) passing the first gaseous stream to a gas/solids separator, separating solid particles therefrom, and forming a second gaseous stream comprising residual solid particles, d) passing at least a portion of the second gaseous stream to one or more heat exchangers to remove the heat of reaction, and e) recycling at least a portion of the cooled stream from step (d) as the fluidising gas in step (a), characterised in that the rate of fouling of the one or more heat exchangers is such that i) the increase in pressure drop across the heat exchangers is equivalent to less than 5% per year, and/or ii) the decrease in heat transfer of the heat exchangers is equivalent to less than 5% per year.
    • 本发明涉及在流化床反应器中烯烃气相聚合的方法,该方法包括:a)在聚合反应存在下使包含一种或多种烯烃单体的流化气体通过聚合物颗粒的流化床 催化剂,b)从反应器顶部排出包含固体颗粒的第一气流,c)将第一气流送至气/固分离器,从其中分离固体颗粒,形成包含残留固体颗粒的第二气流 )将至少一部分第二气流引导至一个或多个热交换器以除去反应热,以及e)将步骤(d)中的冷却流的至少一部分循环为步骤(a)中的流化气体, 其特征在于,所述一个或多个热交换器的结垢速率使得i)所述热交换器上的压降的增加等于每年小于5%,和/或ii)所述d 热交换器的热传递相当于每年少于5%。
    • 7. 发明授权
    • Process and apparatus for the polymerisation of olefins
    • 用于烯烃聚合的方法和设备
    • US09394382B2
    • 2016-07-19
    • US13988794
    • 2011-12-14
    • Andrew David BellJean-Louis ChamayouKevin Peter Ramsay
    • Andrew David BellJean-Louis ChamayouKevin Peter Ramsay
    • C08F2/34B01J8/24B01J8/44C08F10/00C08F110/02
    • C08F10/00C08F2/34C08F110/02C08F2/007
    • Process for gas phase polymerization of olefins in a fluidized bed reactor by (a) passing a fluidizing gas containing at least one olefin monomer through a fluidized bed of polymer particles in the presence of a polymerization catalyst to produce polymer at a polymer production rate of C Tonnes/hour, (b) withdrawing a first gaseous stream containing solid particles from the top of the reactor, (c) passing the first gaseous stream to a gas/solids separator, separating solid particles therefrom, and forming a second gaseous stream containing residual solid particles, (d) passing a portion of the second gaseous stream to at least one heat exchanger to remove heat of reaction whereby residual solid particles contact the heat exchanger, and (e) recycling a portion of the cooled stream from step (d) as the fluidizing gas in step (a). The heat exchangers have a heat exchange surface area which totals less than 120×C m2.
    • 在流化床反应器中通过(a)在聚合催化剂存在下使包含至少一种烯烃单体的流化气体通过聚合物颗粒的流化床将烯烃气相聚合的方法以聚合物生产速率C 吨/小时,(b)从反应器顶部排出含有固体颗粒的第一气态流,(c)将第一气流送至气体/固体分离器,从其中分离固体颗粒,并形成含有残留物的第二气流 固体颗粒,(d)将第二气流的一部分通入至少一个热交换器以除去反应热,由此残留的固体颗粒接触热交换器,和(e)将来自步骤(d)的冷却流的一部分再循环, 作为步骤(a)中的流化气体。 热交换器的热交换面积总计小于120×Cm2。
    • 9. 发明授权
    • Apparatus and process for gas phase fluidised bed polymerisation reaction
    • 气相流化床聚合反应的装置和方法
    • US08314198B2
    • 2012-11-20
    • US12737911
    • 2009-09-21
    • Thibault DumasKevin Peter Ramsay
    • Thibault DumasKevin Peter Ramsay
    • C08F2/01B01J19/00
    • C08F10/00B01J8/1809B01J8/1872B01J2208/00761B01J2208/00778B01J2208/00991C08F2/34C08F2/01
    • The present invention relates to an apparatus and a process for polymerization, and, in particular, provides an apparatus for gas phase fluidised bed polymerization of olefins, which apparatus comprises: A) a first section which is an upright cylindrical section having a diameter, D1, and cross-sectional area, A1, and B) a second section, provided vertically above the first section and centered about a common vertical axis to the upright cylindrical first section, the base of the second section having a cylindrical cross-section of diameter D1 and being joined to the top of the first section, and the horizontal cross-sectional area of the second section above its base being greater than the cross-sectional area of the first section, characterized in that: i) D1 is greater than 4.5 meters, and ii) the second section has a maximum horizontal cross-sectional area, A2, which is between 3.2 and 6 times the cross-sectional area, A1, of the first section.
    • 本发明涉及一种用于聚合的装置和方法,并且特别地提供了一种用于烯烃气相流化床聚合的装置,该装置包括:A)第一部分,其是直径为D1 和横截面积A1和B)第二部分,其垂直设置在第一部分上方并且围绕垂直圆柱形第一部分的共同垂直轴线居中,第二部分的基部具有圆柱形截面的直径 D1并且连接到第一部分的顶部,并且第二部分在其基部之上的水平横截面面积大于第一部分的横截面面积,其特征在于:i)D1大于4.5 米,并且ii)第二部分具有最大横截面积A2,其在第一部分的横截面积A1的3.2和6倍之间。
    • 10. 发明申请
    • APPARATUS AND PROCESS FOR GAS PHASE FLUIDISED BED POLYMERISATION REACTION
    • 气相流化床聚合反应的装置和方法
    • US20110152489A1
    • 2011-06-23
    • US12737911
    • 2009-09-21
    • Thiault DumasKevin Peter Ramsay
    • Thiault DumasKevin Peter Ramsay
    • C08F2/01B01J19/00
    • C08F10/00B01J8/1809B01J8/1872B01J2208/00761B01J2208/00778B01J2208/00991C08F2/34C08F2/01
    • The present invention relates to an apparatus and a process for polymerisation, and, in particular, provides an apparatus for gas phase fluidised bed polymerisation of olefins, which apparatus comprises: A) a first section which is an upright cylindrical section having a diameter, D1, and cross-sectional area, A1, and B) a second section, provided vertically above the first section and centred about a common vertical axis to the upright cylindrical first section, the base of the second section having a cylindrical cross-section of diameter D1 and being joined to the top of the first section, and the horizontal cross-sectional area of the second section above its base being greater than the cross-sectional area of the first section, characterised in that: i) D1 is greater than 4.5 metres, and ii) the second section has a maximum horizontal cross-sectional area, A2, which is between 3.2 and 6 times the cross-sectional area, A1, of the first section.
    • 本发明涉及一种用于聚合的装置和方法,并且特别地提供了一种用于烯烃的气相流化床聚合的装置,该装置包括:A)第一部分,其是具有直径D1的直立圆柱形部分 和横截面积A1和B)第二部分,其垂直设置在第一部分上方并且围绕垂直圆柱形第一部分的共同垂直轴线居中,第二部分的基部具有圆柱形截面的直径 D1并且连接到第一部分的顶部,并且第二部分在其基部之上的水平横截面面积大于第一部分的横截面面积,其特征在于:i)D1大于4.5 米,并且ii)第二部分具有最大横截面积A2,其在第一部分的横截面积A1的3.2和6倍之间。