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    • 3. 发明授权
    • Ballasted leuco dyes and photothermographic element containing same
    • 压实无色染料和含有其的光热敏成像元件
    • US5424183A
    • 1995-06-13
    • US200925
    • 1994-02-22
    • Takuzo IshidaRoger A. MaderDoreen C. LynchTran V. ThienKenneth L. Hanzalik
    • Takuzo IshidaRoger A. MaderDoreen C. LynchTran V. ThienKenneth L. Hanzalik
    • G03C8/40G03C1/494G03C1/498G03C8/14
    • G03C8/4033
    • Heat-developable photothermographic materials capable of providing stable color images of high resolution. These materials comprise a support bearing a layer of an image-forming composition comprising:(a) a photosensitive silver halide,(b) an organic silver compound,(c) a reducing agent for silver ion, and(d) a binder,The reducing agent comprises a ballasted leuco dye compound. The ballasted leuco dye compound comprises a compound of the general formula:D--BwhereinD represents the reduced chromophore of a thermally mobile dye; andB represents an organic group that reduces the thermal mobility of D in the aforementioned binder, said organic group B capable of being oxidatively cleaved. The molecular weight of B must not be so high that the resulting amount of D in the emulsion layer is insufficient to yield a dye image having a reflection optical density of at least 0.3 or a transmission optical density of at least 0.2. Advantages of the heat-developable photothermographic materials of this invention include the following:(1) capability of providing of pure, clear, and stable positive dye images at high photographic speed;(2) low silver requirement; and(3) reduced background stain.
    • 能够提供稳定的高分辨率彩色图像的可热成像光热敏成像材料。 这些材料包括承载成像组合物层的载体,其包含:(a)感光卤化银,(b)有机银化合物,(c)银离子还原剂和(d)粘合剂。 还原剂包括压载的无色染料化合物。 镇静无色染料化合物包含通式为D-B的化合物,其中D表示热移动染料的还原生色团; 并且B表示降低上述粘合剂中D的热迁移率的有机基团,所述有机基团B能够被氧化裂解。 B的分子量不能太高,乳液层中D的产生量不足以产生具有至少为0.3的反射光密度或至少为0.2的透射光密度的染料图像。 本发明的热显影光热成像材料的优点包括:(1)以高照相速度提供纯净,清晰和稳定的正染料影像的能力; (2)低银需求; 和(3)减少背景污点。