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1. 发明授权

US4857419A Method of operating zinc-halogen secondary battery 失效
标题翻译：操作卤素二次电池的方法
公开(公告)号：US4857419A
公开(公告)日：1989-08-15
申请号：US144749
申请日：1988-01-19
申请人： Kenichiro Jinnai , Takafumi Hashimoto
发明人： Kenichiro Jinnai , Takafumi Hashimoto
IPC分类号： H01M10/44 , H01M12/08
CPC分类号： H01M10/44
摘要： In recharging a zinc-halogen secondary battery or battery, zinc dendrite is readily formed on the negative electrode and therefore it has been difficult to form a uniformly thick zinc layer on the negative electrode. This inevitably causes a short cyclic battery lifetime. To overcome this problem, electric pulse treatment is effected at the electrode before dc battery recharging process. In zinc oxide resolving treatment, an electrically positive pulse is applied to the negative electrode. In zinc fine crystal depositing treatment, an electrically negative pulse is applied to the negative electrode. Where the above pulse treatments are effected in combination in the electrolyte including a zinc dendrite inhibitor, a synergistic effect can be obtained.
摘要翻译：在对卤素二次电池或电池进行再充电时，负极上容易形成锌枝晶，因此难以在负极上形成均匀的锌层。这不可避免地导致短暂的循环电池寿命。为了克服这个问题，在直流电池充电过程之前，在电极处进行电脉冲处理。在氧化锌分解处理中，向负极施加电正脉冲。在锌微晶沉积处理中，向负极施加电负脉冲。在包含锌枝晶抑制剂的电解质中组合进行上述脉冲处理的情况下，可以获得协同效果。

2. 发明授权

US4614693A Metal-halogen secondary battery 失效
标题翻译：金属卤素二次电池
公开(公告)号：US4614693A
公开(公告)日：1986-09-30
申请号：US739224
申请日：1985-05-30
申请人： Takafumi Hashimoto , Yasuo Ando , Kenichiro Jinnai
发明人： Takafumi Hashimoto , Yasuo Ando , Kenichiro Jinnai
IPC分类号： H01M2/40 , H01M10/42 , H01M12/00
CPC分类号： H01M10/4214 , H01M2/40
摘要： A metal-halogen secondary battery has a high state of charging and a capability of storing a large electric power at a high density. In the secondary battery the electrolyte pressure in the positive electrode chamber is higher than the electrolyte pressure in the negative electrode chambers. The metal ions in the positive electrode chambers are permeated into the negative electrode chambers and reduced, and the halogen ions in the negative electrode chambers are also permeated into the positive electrode chambers and oxidized thereby contributing to the storage of the electric power.
摘要翻译：金属卤素二次电池具有高充电状态和高密度存储大电力的能力。在二次电池中，正极室中的电解液压力高于负极室中的电解液压力。正极室中的金属离子被渗透到负极室中并减少，并且负极室中的卤素离子也被渗透到正极室中并被氧化，从而有助于电力的存储。

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