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1. 发明授权

US07135592B2 Process for producing polyfluoroalkyl ester of unsaturated carboxylic acid 有权
标题翻译：制备不饱和羧酸多氟烷基酯的方法
公开(公告)号：US07135592B2
公开(公告)日：2006-11-14
申请号：US11191398
申请日：2005-07-28
申请人： Katsuyuki Sato , Keisuke Kokin , Sunao Ikeda , Kimihiko Urata
发明人： Katsuyuki Sato , Keisuke Kokin , Sunao Ikeda , Kimihiko Urata
IPC分类号： C07C69/52 , C07C67/38
CPC分类号： C07C67/08 , C07C69/60 , C07C69/593 , C07C69/56 , C07C69/54
摘要： A polyfluoroalkyl ester of unsaturated carboxylic acid is produced in high yield in a more simple reactor and with much more reduction in the waste than the conventional process based on esterification reaction by subjecting a polyfluoroalkanol represented by the following general formula: Rf—R—OH where Rf is a polyfluoroalkyl group having 1–6 carbon atoms and R is an alkylene group having 1–6 carbon atoms, and an unsaturated carboxylic acid to dehydration reaction in a fluorine-containing solvent in the presence of an acid catalyst and a polymerization inhibitor.
摘要翻译：不饱和羧酸的多氟烷基酯在更简单的反应器中以高产率生产，与通过使由以下通式表示的多氟烷醇进行酯化反应相比，废弃物的还原性大大降低：公式描述=“在线公式”end =“lead”？> Rf-R-OH <？in-line-formula description =“In-line Formulas”end =“tail”？>其中Rf是具有 1-6个碳原子，R是具有1-6个碳原子的亚烷基，在酸性催化剂和聚合抑制剂存在下，在含氟溶剂中进行不饱和羧酸脱水反应。

2. 发明授权

US07772443B2 Iodine-containing fluoropolyether and process for producing the same 有权
标题翻译：含碘的含氟聚醚及其制备方法
公开(公告)号：US07772443B2
公开(公告)日：2010-08-10
申请号：US11921343
申请日：2006-05-22
申请人： Keisuke Kokin , Kimihiko Urata , Takehiro Sonoi
发明人： Keisuke Kokin , Kimihiko Urata , Takehiro Sonoi
IPC分类号： C07C43/12
CPC分类号： C07C41/22 , C07C43/126
摘要： An iodine-containing fluoropolyether represented by the following general formula [I]: RfO[CF(CF3)CF2O]mCF(CF3)(CH2)nI [I] (where Rf is a perfluoroalkyl group having 1-3 carbon atoms, m is an integer of 0-10, and n is an integer of 3-12), is a novel compound having a perfluoropolyetheralkyl group capable of giving a flexibility to the molecule chain through the etheral bond, said perfluoropolyether alkyl group being bonded to the alkyl iodide having an alkyl group having 3 or more carbon atoms, and can be produced by reaction of a fluoropolyether group-containing alcohol represented by the following general formula [II]: RfO[CF(CF3)CF2O]mCF(CF3)(CH2)nOH [II] (Where Rf, m, and n have the same meanings as defined above) with a metal iodide, preferably potassium iodide.
摘要翻译：由以下通式[I]表示的含碘含氟聚醚：RfO [CF（CF 3）CF 2 O] m CF（CF 3）（CH 2）n I [I]（其中Rf是具有1-3个碳原子的全氟烷基，m是是0〜10的整数，n为3〜12的整数）是具有通过醚键赋予分子链柔性的全氟聚醚烷基的新化合物，所述全氟聚醚烷基与烷基碘键合具有3个以上碳原子的烷基，可以通过由以下通式[II]表示的含氟聚醚基团的醇反应来制造：RfO [CF（CF 3）CF 2 O] m CF（CF 3）（CH 2）n OH [II]（其中Rf，m和n具有与上述相同的含义）与金属碘化物，优选碘化钾。

3. 发明申请

US20080108769A1 Fluorine-Containing Copolymer 失效
标题翻译：含氟共聚物
公开(公告)号：US20080108769A1
公开(公告)日：2008-05-08
申请号：US11791307
申请日：2005-11-18
申请人： Jun Kanega , Ji-Shan Jin , Katsumi Suzuki , Takashi Enokida , Keisuke Kokin
发明人： Jun Kanega , Ji-Shan Jin , Katsumi Suzuki , Takashi Enokida , Keisuke Kokin
IPC分类号： C08F16/12
CPC分类号： C08F214/184
摘要： A fluorine-containing copolymer, which comprises a hydroxyl-terminated fluorine-containing vinyl ether, represented by the following general formula: CF2═CFORfCH2OH (where Rf is a fluoroalkylene group, a fluoroalkyl ether group, or a fluoroalkoxyfluoroalkyl ether group, having 1-25 carbon atoms), and at least one of other fluorine-containing unsaturated monomers, where a high-molecular weight fluorine-containing copolymer having a melt viscosity (230° C.) of 0.1-100 g/10 min. is insoluble in a solvent, and can be used suitably for melt molding, whereas a low-molecular weight fluorine-containing copolymer having a glass transition temperature Tg of 20° C., or higher, and a number average molecular weight Mn of 1,000, or more is soluble in a solvent, and can be used suitably for coating agents, etc. The fluorine-containing copolymer has a high light transmissivity, and a low refractive index, and also has, as such, a good adhesiveness to various substrated without any surface treatment, any adhesives, or the like.
摘要翻译：包含由以下通式表示的羟基封端的含氟乙烯基醚的含氟共聚物：<？in-line-formula description =“In-line formula”end =“lead”？> CF _{其中R f是氟代亚烷基，氟代烷基醚基团，或具有1-25个碳原子的氟代烷氧基氟烷基醚基团）和至少一种其它含氟不饱和单体，其中熔体粘度（230℃）为0.1的高分子量含氟共聚物 -100g / 10min。不溶于溶剂，可适用于熔融成型，而玻璃化转变温度Tg为20℃以上，数均分子量Mn为1000的低分子量含氟共聚物，以上的溶剂可溶于溶剂，可以适用于涂布剂等。含氟共聚物透光性高，折射率低，并且具有良好的粘合性，适合各种不带底漆任何表面处理，任何粘合剂等。}

4. 发明授权

US08288483B2 Diurethane compound, process for producing the same, and acrylic rubber composition containing the same 有权
标题翻译：二氨基甲酸酯化合物，其制造方法和含有它们的丙烯酸类橡胶组合物
公开(公告)号：US08288483B2
公开(公告)日：2012-10-16
申请号：US12919718
申请日：2009-01-30
申请人： Daisuke Ito , Haruyoshi Tatsu , Keisuke Kokin , Hideyuki Ono
发明人： Daisuke Ito , Haruyoshi Tatsu , Keisuke Kokin , Hideyuki Ono
IPC分类号： C08C19/20 , C08C19/22 , C08J3/24 , C08F8/30
CPC分类号： C07C317/18 , C07C271/20 , C07C2603/18 , C07D339/08 , C08K5/205 , C08K5/36 , C08L33/08 , C08L75/04 , C08L2666/20
摘要： Disclosed is a diurethane compound R2(SO2)m(CH2)nOCONH—R1—NHCOO(CH2)n(SO2)mR2 produced by a method allowing a diamine compound H2NR1NH2 to react with a chloroformate compound ClCOO(CH2)n(SO2)mR2 or a method allowing a diisocyanate compound OCNR1NCO to react with a hydroxyl-containing compound R2(SO2)m(CH2)nOH. The diurethane compound is compounded with multivalent amine crosslinkable group-containing acrylic rubber together with a basic vulcanization accelerator to form an acrylic rubber composition. The acrylic rubber composition including the diurethane compound as a vulcanizing agent decreases a delay in the vulcanization rate due to prevention of scorching and also allows a vulcanized article to satisfy the compression set characteristics.
摘要翻译：公开了通过使二胺化合物H2NR1NH2与氯甲酸酯化合物ClCOO（CH2）n（SO2）mR2反应的方法制备的二氨基甲酸酯化合物R2（SO2）m（CH2）nOCONH-R1-NHCOO（CH2）n（SO2）或使二异氰酸酯化合物OCNR1NCO与含羟基化合物R2（SO2）m（CH2）nOH反应的方法。将二氨基甲酸酯化合物与多价胺交联基团的丙烯酸橡胶和碱性硫化促进剂一起混合以形成丙烯酸橡胶组合物。包含作为硫化剂的二氨基甲酸酯化合物的丙烯酸类橡胶组合物由于防止焦烧而降低硫化速度的延迟，并且还允许硫化制品满足压缩永久变形特性。

5. 发明申请

US20120041201A1 METHOD FOR PRODUCING FLUORINE-CONTAINING POLYETHER CARBOXYLIC ACID AMIDE 有权
标题翻译：生产含氟聚合物羧酸酰胺的方法
公开(公告)号：US20120041201A1
公开(公告)日：2012-02-16
申请号：US13265356
申请日：2010-04-16
申请人： Keisuke Kokin , Seiichiro Murata , Hideki Abe , Yusuke Takahashi
发明人： Keisuke Kokin , Seiichiro Murata , Hideki Abe , Yusuke Takahashi
IPC分类号： C07D239/42 , C07D213/75 , C07D235/30
CPC分类号： C08G65/007 , C08G65/33313 , C08G65/33317 , C10M133/38 , C10M133/40 , C10M133/44 , C10M133/46 , C10M149/12 , C10M2215/082 , C10M2215/221 , C10M2215/223 , C10M2215/224 , C10M2215/30 , C10N2220/021 , C10N2240/204
摘要： A fluorine-containing polyether carboxylic acid amide represented by the general formula: CnF2n+1O(C3F6O)mRfCONHAr, wherein Rf is a fluorocarbon group having 1 to 2 carbon atoms, Ar is a nitrogen-containing heterocyclic group, n is an integer of 1 to 3, and m is an integer of 10 to 30, is produced by reacting a fluorine-containing polyether carboxylic acid fluoride represented by the general formula: CnF2n+1(C3F6O)mRfCOF, wherein Rf, n, and m are as defined above, with a nitrogen-containing heterocyclic amine compound represented by the general formula: ArNH2, wherein Ar is as defined above; wherein the reaction is carried out while a reaction temperature is first increased to 80 to 100° C., and then increased at a temperature increase rate that produces a temperature difference of 3 to 5° C. after 48 hours.
摘要翻译：由通式C n F 2n + 1 O（C 3 F 6 O）m R f CONHAr表示的含氟聚醚羧酸酰胺，其中，Rf是碳原子数1〜2的氟烃基，Ar是含氮杂环基，n是1的整数至3，m为10〜30的整数，通过使由通式C n F 2n + 1（C 3 F 6 O）m R f COF表示的含氟聚醚羧酸氟化物，其中Rf，n和m如上定义而制备与由以下通式表示的含氮杂环胺化合物：ArNH 2，其中Ar如上所定义; 其中反应在反应温度首先升高至80〜100℃的同时进行，然后以48小时后产生3〜5℃的温度差的升温速度升高。

6. 发明授权

US07932335B2 Fluorine-containing elastomer and composition thereof 有权
标题翻译：含氟弹性体及其组合物
公开(公告)号：US07932335B2
公开(公告)日：2011-04-26
申请号：US11793861
申请日：2007-04-20
申请人： Mitsuru Maeda , Takashi Enokida , Keisuke Kokin , Satoru Saito , Jun Kanega
发明人： Mitsuru Maeda , Takashi Enokida , Keisuke Kokin , Satoru Saito , Jun Kanega
IPC分类号： C08F16/24
CPC分类号： C08F214/222 , C08F214/22 , C08K5/0025 , Y10S277/915 , Y10S277/945 , Y10T428/215 , C08L27/16
摘要： A fluorine-containing elastomer having a copolymer composition, which comprises (a) 50-85 mol. % of vinylidene fluoride, (b) 0-25 mol. % of tetrafluoroethylene, (c) 7-20 mol. % of perfluoro(methyl vinyl ether), (d) 2.5-15 mol. % of CF2═CFO[CF2CF(CF3)O]nCF3 (n: 2-6), (e) 0.1-2 mol. % of CF2═CFO[CF2CF(CF3)O]mCF2CF3 (m: 2-6), and (f) 0.1-2 mol. % of RfX (Rf: an unsaturated fluorohydrocarbon group having 2-8 carbon atoms, which can contain at least one ether bond, X: bromine or iodine), can provide a fluorine-containing elastomer composition, which comprises 100 parts by weight of the fluorine-containing elastomer, 0.1-10 parts by weight of an organic peroxide, 0.1-10 parts by weight of a polyfunctional unsaturated compound, and at least 2 parts by weight of an acid acceptor. The composition can give vulcanizates having a distinguished elongation at break at high temperatures such as 100° C., and distinguished compression set characteristics at low temperatures such as 0° C.
摘要翻译：具有共聚物组成的含氟弹性体，其包含（a）50-85mol。％偏二氟乙烯，（b）0-25mol。％的四氟乙烯，（c）7-20摩尔。％的全氟（甲基乙烯基醚），（d）2.5-15mol。 CF 2 = CFO [CF 2 CF（CF 3）O] n CF 3（n = 2-6）的％，（e）0.1-2mol。 CF 2 = CFO [CF 2 CF（CF 3）O] m CF 2 CF 3（m：2-6）的％，和（f）0.1-2mol。 RfX（Rf：具有2-8个碳原子的不饱和氟代烃基，其可以含有至少一个醚键，X：溴或碘）的％可以提供含氟弹性体组合物，其包含100重量份的含氟弹性体，0.1-10重量份有机过氧化物，0.1-10重量份多官能不饱和化合物和至少2重量份酸受体。组合物可以在高温如100℃下得到具有明显的断裂伸长率的硫化橡胶，并且在低温如0℃下具有显着的压缩变形特性。

7. 发明申请

US20100004415A1 Fluorine-Containing Elastomer and Composition Thereof 有权
标题翻译：含氟弹性体及其组成
公开(公告)号：US20100004415A1
公开(公告)日：2010-01-07
申请号：US11793861
申请日：2007-04-20
申请人： Mitsuru Maeda , Takashi Enokida , Keisuke Kokin , Satoru Saito , Jun Kanega
发明人： Mitsuru Maeda , Takashi Enokida , Keisuke Kokin , Satoru Saito , Jun Kanega
IPC分类号： C08F16/24
CPC分类号： C08F214/222 , C08F214/22 , C08K5/0025 , Y10S277/915 , Y10S277/945 , Y10T428/215 , C08L27/16
摘要： A fluorine-containing elastomer having a copolymer composition, which comprises (a) 50-85 mol. % of vinylidene fluoride, (b) 0-25 mol. % of tetrafluoroethylene, (c) 7-20 mol. % of perfluoro(methyl vinyl ether), (d) 2.5-15 mol. % of CF2═CFO[CF2CF(CF3)O]nCF3 (n: 2-6), (e) 0.1-2 mol. % of CF2═CFO[CF2CF(CF3)O]mCF2CF3 (m: 2-6), and (f) 0.1-2 mol. % of RfX (Rf: an unsaturated fluorohydrocarbon group having 2-8 carbon atoms, which can contain at least one ether bond, X: bromine or iodine), can provide a fluorine-containing elastomer composition, which comprises 100 parts by weight of the fluorine-containing elastomer, 0.1-10 parts by weight of an organic peroxide, 0.1-10 parts by weight of a polyfunctional unsaturated compound, and at least 2 parts by weight of an acid acceptor. The composition can give vulcanizates having a distinguished elongation at break at high temperatures such as 100° C., and distinguished compression set characteristics at low temperatures such as 0° C.
摘要翻译：具有共聚物组成的含氟弹性体，其包含（a）50-85mol。％偏二氟乙烯，（b）0-25mol。％的四氟乙烯，（c）7-20摩尔。％的全氟（甲基乙烯基醚），（d）2.5-15mol。％CF 2 CF 2 CF 2 CF（CF 3）O] n CF 3（n = 2-6），（e）0.1-2mol。％CF 2 CF 2 CF 2 CF（CF 3）O] m CF 2 CF 3（m：2-6），（f）0.1-2mol。 RfX（Rf：具有2-8个碳原子的不饱和氟代烃基，其可以含有至少一个醚键，X：溴或碘）的％可以提供含氟弹性体组合物，其包含100重量份的含氟弹性体，0.1-10重量份有机过氧化物，0.1-10重量份多官能不饱和化合物和至少2重量份酸受体。组合物可以在高温如100℃下得到具有明显的断裂伸长率的硫化橡胶，并且在低温如0℃下具有显着的压缩变形特性。

8. 发明授权

US09024077B2 Fluorine-containing vinyl ether compound and method for producing the same 有权
标题翻译：含氟乙烯基醚化合物及其制造方法
公开(公告)号：US09024077B2
公开(公告)日：2015-05-05
申请号：US13822718
申请日：2011-08-24
申请人： Soichiro Murakami , Keisuke Kokin , Seiichiro Murata
发明人： Soichiro Murakami , Keisuke Kokin , Seiichiro Murata
IPC分类号： C07C43/17 , C07C41/09 , C07C41/14
CPC分类号： C07C43/17 , C07C41/09 , C07C41/14
摘要： A fluorine-containing vinyl ether compound of the formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cOCH═CH2 is produced by subjecting a fluorine-containing alcohol of the formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cOH wherein n is an integer of 1 to 6, a is an integer of 1 to 4, b is an integer of 1 to 3, and c is an integer of 1 to 3, and 2-haloethyl vinyl ether of the formula: XCH2CH2OCH═CH2 to XCH2CH2OH-elimination reaction in the presence of a palladium-based catalyst and an aliphatic amine. The fluorine-containing vinyl ether compound contain a perfluoroalkyl group having 6 or less carbon atoms, which is said to have low bioaccumulation potential.
摘要翻译：通过使下式的含氟醇（C 1 F 2 n + 1（CH 2 CF 2）a（CF 2 CF 2））（CH 2 CH 2）a（CF 2 CF 2）b（CH 2 CH 2）c OCH = CH 2 ）b（CH 2 CH 2）cOH其中n为1至6的整数，a为1至4的整数，b为1至3的整数，c为1至3的整数，和2-卤代乙基乙烯基醚在钯基催化剂和脂族胺存在下，XCH2CH2OCH = CH2至XCH2CH2OH消除反应。含氟乙烯基醚化合物含有具有6个或更少碳原子的全氟烷基，据说具有低的生物累积潜力。

9. 发明申请

US20130178659A1 NOVEL FLUORINE-CONTAINING VINYL ETHER COMPOUND AND METHOD FOR PRODUCING THE SAME 有权
标题翻译：含新戊烯的乙烯基醚化合物及其生产方法
公开(公告)号：US20130178659A1
公开(公告)日：2013-07-11
申请号：US13822718
申请日：2011-08-24
申请人： Soichiro Murakami , Keisuke Kokin , Seiichiro Murata
发明人： Soichiro Murakami , Keisuke Kokin , Seiichiro Murata
IPC分类号： C07C43/17 , C07C41/09
CPC分类号： C07C43/17 , C07C41/09 , C07C41/14
摘要： A fluorine-containing vinyl ether compound of the formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cOCH═CH2 is produced by subjecting a fluorine-containing alcohol of the formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cOH wherein n is an integer of 1 to 6, a is an integer of 1 to 4, b is an integer of 1 to 3, and c is an integer of 1 to 3, and 2-haloethyl vinyl ether of the formula: XCH2CH2OCH═CH2 to XCH2CH2OH-elimination reaction in the presence of a palladium-based catalyst and an aliphatic amine. The fluorine-containing vinyl ether compound contain a perfluoroalkyl group having 6 or less carbon atoms, which is said to have low bioaccumulation potential.
摘要翻译：通过使下式的含氟醇（CnF2n + 1（CH2CF2）a（CF2CF2））（CF2CF2）b（CH2CH2）a（CF2CF2）b（CH2CH2）cOCH = CH2得到的含氟乙烯基醚化合物）b（CH 2 CH 2）cOH其中n为1至6的整数，a为1至4的整数，b为1至3的整数，c为1至3的整数，和2-卤代乙基乙烯基醚在钯基催化剂和脂族胺存在下，XCH2CH2OCH = CH2至XCH2CH2OH消除反应。含氟乙烯基醚化合物含有具有6个或更少碳原子的全氟烷基，据说具有低的生物累积潜力。

10. 发明授权

US08476435B2 Method for producing fluorine-containing polyether carboxylic acid amide 有权
标题翻译：含氟聚醚羧酸酰胺的制造方法
公开(公告)号：US08476435B2
公开(公告)日：2013-07-02
申请号：US13265356
申请日：2010-04-16
申请人： Keisuke Kokin , Seiichiro Murata , Hideki Abe , Yusuke Takahashi
发明人： Keisuke Kokin , Seiichiro Murata , Hideki Abe , Yusuke Takahashi
IPC分类号： C07D239/02
CPC分类号： C08G65/007 , C08G65/33313 , C08G65/33317 , C10M133/38 , C10M133/40 , C10M133/44 , C10M133/46 , C10M149/12 , C10M2215/082 , C10M2215/221 , C10M2215/223 , C10M2215/224 , C10M2215/30 , C10N2220/021 , C10N2240/204
摘要： A fluorine-containing polyether carboxylic acid amide represented by the general formula: CnF2n+1O(C3F6O)mRfCONHAr, wherein Rf is a fluorocarbon group having 1 to 2 carbon atoms, Ar is a nitrogen-containing heterocyclic group, n is an integer of 1 to 3, and m is an integer of 10 to 30, is produced by reacting a fluorine-containing polyether carboxylic acid fluoride represented by the general formula: CnF2n+1(C3F6O)mRfCOF, wherein Rf, n, and m are as defined above, with a nitrogen-containing heterocyclic amine compound represented by the general formula: ArNH2, wherein Ar is as defined above; wherein the reaction is carried out while a reaction temperature is first increased to 80 to 100° C., and then increased at a temperature increase rate that produces a temperature difference of 3 to 5° C. after 48 hours.
摘要翻译：由通式C n F 2n + 1 O（C 3 F 6 O）m R f CONHAr表示的含氟聚醚羧酸酰胺，其中，Rf是碳原子数1〜2的氟烃基，Ar是含氮杂环基，n是1的整数至3，m为10〜30的整数，通过使由通式C n F 2n + 1（C 3 F 6 O）m R f COF表示的含氟聚醚羧酸氟化物，其中Rf，n和m如上定义而制备与由以下通式表示的含氮杂环胺化合物：ArNH 2，其中Ar如上所定义; 其中反应在反应温度首先升高至80〜100℃的同时进行，然后以48小时后产生3〜5℃的温度差的升温速度升高。

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