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    • 5. 发明授权
    • Heat-resisting aromatic polyester resin and process for preparing the
same
    • 耐热芳香族聚酯树脂及其制备方法
    • US4426511A
    • 1984-01-17
    • US313670
    • 1981-10-21
    • Masahiro AsadaMiyuki MatsuuraKazuya Yonezawa
    • Masahiro AsadaMiyuki MatsuuraKazuya Yonezawa
    • C08G63/00C08G63/19C08G63/66C08G63/68C08G63/688C08G63/87C08G63/18
    • C08G63/19C08G63/6886C08G63/87
    • A heat resisting aromatic polyester resin comprising (a) recurring units of the formula (I): ##STR1## wherein X is a bivalent group selected from the group consisting of an unsubstituted or substituted bivalent hydrocarbon group having 1 to 10 carbon atoms,--O--, --S--, --SO.sub.2 --and--CO--, and (b) recurring units of the formula (II): ##STR2## wherein X is as defined above, R and R' are a group selected from the group consisting of alkyl, aryl, aralkyl, alkoxyl, aryloxyl and phenylalkoxyl groups having 1 to 20 carbon atoms, their substituted groups, a halogen atom and a mixture thereof, p+q=1 to 8, and m and n are 0 or 1, but n is not 0 when m is 1, provided that up to 10% by mole of the total of the units: ##STR3## in the formulas (I) and (II) may be replaced with units: ##STR4## the ratio of (a)/[(a)+(b)]being from 0.05 to 0.95 by mole. The polyester resin is substantially amorphous and soluble in some organic solvents, and has an excellent heat resistance. The polyester resin is prepared by reacting terephthaloyl chloride with alkali metal salts of at least two kinds of particular bivalent phenolic compounds in the presence of a phase transfer catalyst.
    • 一种耐热性芳族聚酯树脂,其包含(a)式(I)的重复单元:其中X是选自未取代或取代的具有1-10个碳原子的二价烃基的二价基团 ,-O - , - S - , - SO 2 - 和-CO-,和(b)式(II)的重复单元:其中X如上所定义,R和R' 选自具有1至20个碳原子的烷基,芳基,芳烷基,烷氧基,芳氧基和苯基烷氧基,其取代基,卤素原子及其混合物,p + q = 1-8,m和n分别为 0或1,但当m为1时,n不为0,只要式(I)和(II)中的总数高达10摩尔%,则可以用单位代替:
    • 10. 发明授权
    • Modified polyolefin polymer, its manufacturing method and resin
composition containing it
    • 改性聚烯烃聚合物,其制造方法和含有它的树脂组合物
    • US5294673A
    • 1994-03-15
    • US778144
    • 1991-12-26
    • Yoshikuni DeguchiKazuya Yonezawa
    • Yoshikuni DeguchiKazuya Yonezawa
    • C08F8/30C08F110/06C08F210/00C08F255/00C08F277/00C08F279/02C08F269/00
    • C08F277/00C08F210/00C08F255/00C08F279/02C08F8/30C08F110/06
    • The present invention provides a modified polyolefin type polymer having one structural unit having a glycidyl group represented by the following general formula (I) per 2-1,000 repeating units of olefin: ##STR1## (In the formula, Ar represents an aromatic hydrocarbon group 6-23 in carbon number having at least one glycidyloxy group, and R represents hydrogen atom or methyl group.), its manufacturing method and a resin composition containing the aforementioned modified polyolefin polymer. The polyolefin type polymer of the present invention is excellent not only in mechanical properties, heat resistance and resistance to oil, but also in dyeability, adhesiveness, antistatic property. It enables blending and conversion into alloys for its outstanding affinity with other resins.
    • PCT No.PCT / JP91 / 00552 Sec。 371 1991年12月26日第 102(e)日期1991年12月26日PCT 1991年4月24日PCT PCT。 出版物WO91 / 17192 日本公开日1991年11月14日。本发明提供一种具有一个结构单元的改性聚烯烃类聚合物,其具有每2-1,000个烯烃重复单元由以下通式(I)表示的缩水甘油基:(*化学结构*)(I )(式中,Ar表示碳数为6〜23的芳香族烃基,具有至少一个缩水甘油基氧基,R表示氢原子或甲基),其制造方法和含有上述改性聚烯烃聚合物的树脂组合物。 本发明的聚烯烃类聚合物不仅具有机械性能,耐热性和耐油性,而且在染色性,粘合性,抗静电性方面也是优异的。 它能够与其他树脂具有突出的亲和力,使其能够共混和转化成合金。