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    • 2. 发明授权
    • Steel products having superior weathering, method of producing the steel
products, and method of forming weathering protective rust on steel
product surfaces
    • 具有优良耐候性的钢制品,钢制品的制造方法,以及在钢制品表面形成耐候性锈蚀的方法
    • US6068712A
    • 2000-05-30
    • US225503
    • 1999-01-06
    • Yasuyashi YamaneKazuhiko ShiotaniFumimaru KawabataToshiyuki HoshinoKeniti AmanoKimihiro Nishimura
    • Yasuyashi YamaneKazuhiko ShiotaniFumimaru KawabataToshiyuki HoshinoKeniti AmanoKimihiro Nishimura
    • C23C8/14C23C8/18C23C8/80
    • C23C8/14C23C8/18
    • The invention provides a steel product having superior weathering which is coated with a rust layer containing 50 or more weight % of non-crystalline rust, a method of producing the steel product, and a method of forming weathering protective rust on a material surface of the steel product. A material of a steel product is placed in an atmosphere in which the dew point is kept constant and the temperature of the steel product material is repeatedly varied between a temperature range of 5.degree. C. or more higher than the dew point and a temperature range of 5.degree. C. or more lower than the dew point. Weathering protective rust is thereby formed on the material surface of the steel product and a steel product having superior weathering is obtained. Preferably, the atmosphere contains 15 to 50 volume % of oxygen gas, and the temperature of the steel product is varied at a rising rate of 0.1 to 2.degree. C./minute and a lowering rate of 0.01 to 2.degree. C./minute. Alternatively, a desired steel product can also be obtained by placing a material of the steel product in an atmosphere containing 15 to 50 volume % of oxygen gas, keeping constant the dew point in the atmosphere, and keeping the temperature of the steel product material in the atmosphere at a certain value in a temperature range between a temperature 5.degree. C. lower than the dew point and a temperature 20.degree. C. lower than the dew point; or by placing a material of the steel product in an atmosphere containing 15 to 50 volume % of oxygen gas, and forming and keeping a water film with a thickness not more than 500 .mu.m but not less than 50 .mu.m on a material surface of the steel product.
    • 本发明提供一种具有优良耐候性的钢制品,其涂有含有50重量%以上非结晶锈的锈层,该钢制品的制造方法以及在该材料表面上形成耐候性锈蚀的方法 钢制品。 将钢材的材料放置在露点保持恒定的气氛中,并且钢产品材料的温度在5℃以上的温度范围内反复变化,并且温度范围 比露点低5℃或更高。 由此,在钢材的材料表面形成耐候性保护锈,得到耐候性优异的钢制品。 优选气氛含有15〜50体积%的氧气,钢产品的温度以0.1〜2℃/分钟的升高速度变化,0.01〜2℃/分钟的降低速度。 或者,也可以通过将钢材的材料放置在含有15〜50体积%的氧气的气氛中,使大气中的露点保持恒定,并将钢材的温度保持在 在一定温度范围内的气氛在比露点低5℃的温度和比露点低20℃的温度范围内; 或通过将钢制品的材料放置在含有15〜50体积%的氧气的气氛中,在其材料表面上形成并保持厚度不大于500μm〜50μm的水膜 钢铁产品。