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1. 发明专利

JP2004330005A Absorbent using peelings of persimmon as raw material and method for separating uranium and thorium using it 审中-公开
标题翻译：使用PERSIMMON作为原材料的剥离物的吸收和使用其分离铀和钍的方法
公开(公告)号：JP2004330005A
公开(公告)日：2004-11-25
申请号：JP2003126135
申请日：2003-05-01
申请人： Katsutoshi Inoue , Kenjiro Makino , 勝利井上 , 賢次郎牧野
发明人： INOUE KATSUTOSHI , MURAKAMI HIROSHI , MAKINO KENJIRO , KANAZAWA CHIKAO
IPC分类号： G21F9/12 , B01D15/00 , B01D15/08 , B01J20/22 , C02F1/28
摘要： PROBLEM TO BE SOLVED: To provide a method for separating/removing uranium and thorium present in environment in low concentration using an inexpensive adsorbent, especially a method for separating/removing a very small amount of uranium and thorium coexisting in a rare-earth element.
SOLUTION: This adsorbent is inexpensively prepared by grinding astringent persimmons, which are caused in large quantities at the time of production of dried persimmons as they are and crosslinking the ground persimmons using a crosslinking agent such as para-formaldehyde or the like before washing and drying them. This adsorbent thus prepared is stirred along with water containing uranium and thorium in an existing stirring device and subsequently filtered off to remove uranium and thorium in water. Alternatively, a column is filled with the adsorbent and water containing uranium and thorium is passed through the column to remove uranium and thorium in water. An acid aqueous solution with a pH of 1 or below is passed through the column after adsorption to concentrate adsorbed uranium and thorium to elute them. The adsorbent is regenerated by this method to be again subjected to adsorption/removal.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供一种使用便宜的吸附剂分离/去除低浓度环境中存在的铀和钍的方法，特别是用于分离/除去少量稀有金属中的少量铀和钍的方法，地球元素解决方案：该吸附剂通过研磨收敛的柿子而成本低廉，这是在干柿子生产时大量引起的柿子柿，并且使用交联剂如对甲醛等交联地面柿子，洗涤并烘干。将如此制备的该吸附剂与现有搅拌装置中的含铀和钍的水一起搅拌，随后过滤除去水中的铀和钍。或者，用吸附剂填充柱，并且含有铀的水和钍通过柱以在水中除去铀和钍。吸附后，pH为1以下的酸性水溶液通过柱，浓缩吸附的铀和钍进行洗脱。通过该方法再生吸附剂以再次进行吸附/去除。版权所有（C）2005，JPO＆NCIPI

2. 发明专利

JP2004267805A Adsorbent made of residue of squeezed fruit as raw material and method for removing toxic substance by using the same 审中-公开
公开(公告)号：JP2004267805A
公开(公告)日：2004-09-30
申请号：JP2003000056
申请日：2003-01-06
申请人： Katsutoshi Inoue , Japan Science & Technology Agency , Sadenko Co Inc , Yamaso Micron:Kk , 勝利井上 , 有限会社山曹ミクロン , 株式会社佐電工 , 独立行政法人科学技術振興機構
发明人： INOUE KATSUTOSHI , KEDAR NATH GHIMIRE , MAKINO KENJIRO
IPC分类号： B09B3/00 , B01J20/24 , B01J20/30 , C02F1/28 , C02F1/42
摘要： PROBLEM TO BE SOLVED: To provide an advanced method for removing a heavy metal by using an inexpensive adsorbent by a easy and simple operation, which can fulfill the strict environmental regulation satisfactorily.
SOLUTION: The adsorbent to be used is prepared inexpensively by saponifying the squeezed residue from a mandrin or an apple by adding a small amount of an alkaline substance such as calcium hydroxide to the lees and crushing and mixing the alkaline substance-added lees by agitation, washing the saponified residue with water and drying washed saponified residue. The heavy metal such as lead, cadmium and arsenic in water is removed by agitating the prepared adsorbent with the water containing the heavy metal in an existing agitator-equipped apparatus and filtering the heavy metal-adsorbed adsorbent. When the heavy metal such as lead or cadmium exists in the water as a cation, this adsorbent can be used as it is. When the heavy metal such as arsenic exists in the water as an oxo anion, the one obtained by adsorbing/depositing a ferric ion on this adsorbent in advance is used.
COPYRIGHT: (C)2004,JPO&NCIPI

3. 发明专利

JP2005058951A Method for separation, removal, condensation and recovery of heavy metal, fat and protein in scallop internal organ immersed liquid 审中-公开
标题翻译：重金属离子液体中重金属，脂肪和蛋白质的分离，去除，冷凝和还原的方法
公开(公告)号：JP2005058951A
公开(公告)日：2005-03-10
申请号：JP2003294815
申请日：2003-08-19
申请人： Hokuyo:Kk , Katsutoshi Inoue , Japan Science & Technology Agency , Yamaso Micron:Kk , 勝利井上 , 有限会社山曹ミクロン , 株式会社北陽 , 独立行政法人科学技術振興機構
发明人： INOUE KATSUTOSHI , AKIBAYASHI TETSUO , KEDAR NATH GHIMIRE , MAKINO KENJIRO
IPC分类号： B09B3/00 , B01J20/24 , C02F1/28 , C02F1/56
摘要： PROBLEM TO BE SOLVED: To provide a method for efficiently adsorbing, desorbing, or eluting heavy metals like cadmium in acid immersion liquid in hollow of boiled scallop containing a large amount of fat and protein, and a method for efficiently separating and recovering fat and protein eluted into the acid immersion liquid together with the heavy metals.
SOLUTION: A basic substance like sodium carbonate is added to the acid immersion liquid, pH value is adjusted to about 6, the liquid is agitated to an extent, and filtered. An adsorbent of squeezed liquid residue of a mandarin orange and a little amount of a coagulant are added to completely adsorb the residue for 24 hours. Fat and protein are also coagulated, precipitated and separated to obtain clean liquid. Heavy metals in the adsorbent are desorbed and eluted as a heavy metal aqueous solution with a concentration suited to electrolytic gathering using sulfuric acid for electrolytic tail liquid. The adsorbent after desorption can be used as feed, fertilizer or bait together with the recovered fat and protein.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：待解决的问题：提供一种有效吸附，解吸或洗脱含有大量脂肪和蛋白质的煮沸扇贝中空的酸浸液中的重金属如镉的方法，以及有效分离和回收方法脂肪和蛋白质与重金属一起洗脱到酸浸液体中。解决方案：将酸碱浸液中的碱性物质加入到酸浸液中，将pH调节至约6，将液体搅拌至一定程度并过滤。加入普通橙汁和少量凝结剂的挤压液体残留物的吸附剂，以完全吸附残留物24小时。脂肪和蛋白质也凝结，沉淀和分离，得到清洁液体。吸附剂中的重金属被解吸并作为重金属水溶液洗脱，其浓度适用于使用硫酸进行电解尾液的电解收集。脱附后的吸附剂可与回收的脂肪和蛋白质一起用作饲料，肥料或诱饵。版权所有（C）2005，JPO＆NCIPI

4. 发明专利

JP2005305330A Production method for adsorbent of persimmon peel 审中-公开
标题翻译： PERSIMMON PEEL吸附剂的生产方法
公开(公告)号：JP2005305330A
公开(公告)日：2005-11-04
申请号：JP2004126809
申请日：2004-04-22
申请人： Katsutoshi Inoue , Kenjiro Makino , 勝利井上 , 賢次郎牧野
发明人： INOUE KATSUTOSHI , MAKINO KENJIRO , KANAZAWA CHIKAO
IPC分类号： B09B3/00 , B01J20/24
摘要： PROBLEM TO BE SOLVED: To provide a production method for an adsorbent using the whole amount of a persimmon peel by a safe crosslinking method using no harmful organic chemical for removal of a radioactive element such as uranium and a heavy metal such as lead and recovery of a valid metal such as copper and a precious metal.
SOLUTION: The crushed persimmon peel is added at a ratio of 1.0-0.5 kg, preferably 0.7-0.8 kg based on 1 dm
3 of concentrated sulfuric acid and is reacted at a temperature of 80-120°C, preferably 90-110°C for 12-48 hours, preferably 18-30 hours. Thereby, the adsorbent for accomplishing the above object can be produced.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：待解决的问题：提供一种使用全部量的柿子皮的吸附剂的制造方法，该安全交联法使用无有害有机化学物质去除放射性元素如铀和重金属如铅并回收有效金属如铜和贵金属。解决方案：以1.0 dmI浓缩硫酸的比例为1.0-0.5kg，优选0.7-0.8kg，加入破碎的柿饼，并在80℃的温度下反应， 120℃，优选90-110℃，12-48小时，优选18-30小时。由此，可以制造用于实现上述目的的吸附剂。版权所有（C）2006，JPO＆NCIPI

5. 发明专利

JP2005272751A Cellulose derivative and its production method 审中-公开
标题翻译：纤维素衍生物及其生产方法
公开(公告)号：JP2005272751A
公开(公告)日：2005-10-06
申请号：JP2004091186
申请日：2004-03-26
申请人： Katsutoshi Inoue , Mitsui Eng & Shipbuild Co Ltd , 三井造船株式会社 , 勝利井上
发明人： INOUE KATSUTOSHI , TSUJI KENICHI , NAGAHARA SATOSHI
IPC分类号： C08B15/06
摘要： PROBLEM TO BE SOLVED: To provide a cellulose derivative which is soluble in an organic solvent and is not hydrolyzed even when in contact with an acid or an alkali.
SOLUTION: The cellulose derivative is represented by general formula (I) (wherein R
1 and R
2 are each a 7-25C alkyl group; and R
3 is an amino or dithiocarbamate group). Preferably, in the formula, R
1 and R
2 are each a 10C linear alkyl group; and R
3 is a primary amino or dithiocarbamate group.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供可溶于有机溶剂的纤维素衍生物，即使在与酸或碱接触时也不水解。解决方案：纤维素衍生物由通式（I）表示（其中R 1 和R SB 2 均为7-25C烷基; R SB > 3 是氨基或二硫代氨基甲酸酯基）。优选地，在式中，R SB 1和R SB 2各自为10个直链烷基; R 3是伯氨基或二硫代氨基甲酸酯基。版权所有（C）2006，JPO＆NCIPI

6. 发明专利

JP2004216282A Process for removing fluoride ion 审中-公开
公开(公告)号：JP2004216282A
公开(公告)日：2004-08-05
申请号：JP2003007040
申请日：2003-01-15
申请人： Katsutoshi Inoue , Yamaso Micron:Kk , 勝利井上 , 有限会社山曹ミクロン
发明人： INOUE KATSUTOSHI , MAKINO KENJIRO
IPC分类号： C02F1/28 , B01J20/26 , B01J39/18 , C02F1/42
摘要： PROBLEM TO BE SOLVED: To provide a process by which a fluoride ion present with minor concentration in water having a pH around the neutral is efficiently removed; and its concentration is reduced to the environmental regulation value or less. SOLUTION: The process for removing the fluoride ion feeds an aqueous solution containing the fluoride of the minor concentration in a column filled with a resin formed by adsorbing/carrying a trivalent lanthanum or cerium ion having a pH of 2-7 to/on a strong acidic cation exchange resin having giant network structure. COPYRIGHT: (C)2004,JPO&NCIPI

7. 发明专利

JP2005305329A Adsorbent for gold 审中-公开
标题翻译：吸收金
公开(公告)号：JP2005305329A
公开(公告)日：2005-11-04
申请号：JP2004126808
申请日：2004-04-22
申请人： Katsutoshi Inoue , Kenjiro Makino , 勝利井上 , 賢次郎牧野
发明人： INOUE KATSUTOSHI , FUNAOKA MASAMITSU , MAKINO KENJIRO , KANAZAWA CHIKAO
IPC分类号： B01J20/24
摘要： PROBLEM TO BE SOLVED: To provide a method selectively and efficiently separating/recovering, at a low cost, gold existing at a low concentration in an oozing liquid, or the like, of an anode slime generated in an electrolytic refinement of a plating waste liquid and a base metal such as copper and nickel.
SOLUTION: A phenol compound is added to a wood powder generated in lumbering or the like, concentrated sulfuric acid is further added and the mixture is reacted. An adsorbent prepared by a substance isolated in the form that lignin is bonded to the phenol compound is used. Thereby, only gold can be selectively adsorbed from hydrochloric acid. Gold is recovered by incinerating/treating the adsorbent adsorbing the gold.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：为了提供一种方法，以低成本选择性地和有效地分离/回收在渗透液体等中以低浓度存在的金，所述渗透液体等在电解精炼中产生的阳极粘泥电镀废液和贱金属如铜和镍。解决方案：将酚化合物加入到以木材等形成的木粉中，进一步加入浓硫酸并使混合物反应。使用通过以木质素键合到酚化合物的形式分离的物质制备的吸附剂。因此，只有金可以从盐酸中选择性吸附。通过焚烧/处理吸附金的吸附剂回收金。版权所有（C）2006，JPO＆NCIPI

8. 发明授权

US08535625B2 Adsorbent and method of collecting precious metal using the same 有权
标题翻译：吸附剂和使用其收集贵金属的方法
公开(公告)号：US08535625B2
公开(公告)日：2013-09-17
申请号：US13403378
申请日：2012-02-23
申请人： Minoru Kurata , Kinya Atsumi , Hiroaki Fukuda , Katsutoshi Inoue , Keisuke Ohto , Hidetaka Kawakita
发明人： Minoru Kurata , Kinya Atsumi , Hiroaki Fukuda , Katsutoshi Inoue , Keisuke Ohto , Hidetaka Kawakita
IPC分类号： C22B3/00
CPC分类号： C22B3/24 , B01D15/00 , B01J20/24 , B01J20/262 , B01J20/267 , C02F1/286 , C02F1/288 , C02F2101/20 , C02F2103/16 , C02F2303/16 , C22B11/04 , Y02P10/234
摘要： An adsorbent contains a carbohydrate having an ether linkage. Alternatively, an adsorbent contains a carbohydrate having a cross-linkage formation produced by a dehydration reaction using a strong acid. In collection of a precious metal using the adsorbent, the adsorbent selectively adsorbs a precious metal dissolved in a solution.
摘要翻译：吸附剂含有具有醚键的碳水化合物。或者，吸附剂含有通过使用强酸的脱水反应产生的交联形成的碳水化合物。在使用吸附剂收集贵金属时，吸附剂选择性地吸附溶解在溶液中的贵金属。

9. 发明申请

US20120219479A1 ADSORBENT AND METHOD OF COLLECTING PRECIOUS METAL USING THE SAME 有权
标题翻译：使用该方法收集金属的吸附剂和方法
公开(公告)号：US20120219479A1
公开(公告)日：2012-08-30
申请号：US13403378
申请日：2012-02-23
申请人： Minoru Kurata , Kinya Atsumi , Hiroaki Fukuda , Katsutoshi Inoue , Keisuke Ohto , Hidetaka Kawakita
发明人： Minoru Kurata , Kinya Atsumi , Hiroaki Fukuda , Katsutoshi Inoue , Keisuke Ohto , Hidetaka Kawakita
IPC分类号： C01G7/00 , C08B1/00 , C07H15/00
CPC分类号： C22B3/24 , B01D15/00 , B01J20/24 , B01J20/262 , B01J20/267 , C02F1/286 , C02F1/288 , C02F2101/20 , C02F2103/16 , C02F2303/16 , C22B11/04 , Y02P10/234
摘要： An adsorbent contains a carbohydrate having an ether linkage. Alternatively, an adsorbent contains a carbohydrate having a cross-linkage formation produced by a dehydration reaction using a strong acid. In collection of a precious metal using the adsorbent, the adsorbent selectively adsorbs a precious metal dissolved in a solution.
摘要翻译：吸附剂含有具有醚键的碳水化合物。或者，吸附剂含有通过使用强酸的脱水反应产生的交联形成的碳水化合物。在使用吸附剂收集贵金属时，吸附剂选择性地吸附溶解在溶液中的贵金属。

10. 发明申请

US20110308355A1 Adsorption agent for noble metal, method for manufacturing the same, and method for recovering noble metal 有权
标题翻译：贵金属用吸附剂及其制造方法以及回收贵金属的方法
公开(公告)号：US20110308355A1
公开(公告)日：2011-12-22
申请号：US13134870
申请日：2011-06-20
申请人： Hisaya Kato , Toshiyuki Morishita , Kinya Atsumi , Minoru Kurata , Katsutoshi Inoue , Hidetaka Kawakita , Keisuke Ohto
发明人： Hisaya Kato , Toshiyuki Morishita , Kinya Atsumi , Minoru Kurata , Katsutoshi Inoue , Hidetaka Kawakita , Keisuke Ohto
IPC分类号： C22B11/00 , C12N1/00 , C22B9/02 , C12N1/12
CPC分类号： C02F1/286 , B01J20/305 , B01J20/3078 , B01J20/3085 , B01J20/3204 , B01J20/3248 , B01J2220/4843 , B01J2220/4875 , C02F3/322 , C02F2101/20
摘要： A noble metal adsorption agent includes algae or residue of algae having an amino group as a functional group. A noble metal is retrieved by a method including: adsorbing the noble metal on the noble metal adsorption agent; and retrieving the noble metal. The noble metal is solved in a liquid. Thus, by using the noble metal adsorption agent, the noble metal is selectively retrieved.
摘要翻译：贵金属吸附剂包括具有氨基作为官能团的藻类或藻类残留物。通过以下方法回收贵金属：将贵金属吸附在贵金属吸附剂上; 并检索贵金属。贵金属溶解在液体中。因此，通过使用贵金属吸附剂，选择性地回收贵金属。

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