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    • 3. 发明授权
    • Electrophotographic toner containing metal complex
    • 含有金属络合物的电子照相调色剂
    • US4624907A
    • 1986-11-25
    • US669370
    • 1984-11-08
    • Isao NiimuraKatsuichi MotohashiHiroyoshi YamagaNoboru Akuzawa
    • Isao NiimuraKatsuichi MotohashiHiroyoshi YamagaNoboru Akuzawa
    • G03G9/09G03G9/08G03G9/10
    • G03G9/091
    • An electrophotographic toner capable of being electrified negatively comprising:(a) a binder resin; and(b) a charge-controlling and coloring agent comprising at least one 2:1 type metal complex of the formula (I): ##STR1## where each of X.sub.1 and X.sub.2, which may be the same or different, is a hydrogen atom, a C.sub.1 -C.sub.5 alkyl group, a C.sub.1 -C.sub.5 alkoxy group, a nitro group or a halogen atom, each of m and m' is an integer of 1 to 3, each of R.sub.1 and R.sub.2, which may be the same or different, is a hydrogen atom, a C.sub.1 -C.sub.5 alkyl group, a C.sub.1 -C.sub.5 alkoxy group, a halgen atom, a nitro group, a sulfonamide group, a methylsulfonyl group, an ethylsulfonyl group, an acetyl amino group or a benzoyl amino group, each of n and n' is an integer of 1 to 3, Y.sup..sym. is an ammonium ion, an aliphatic ammonium ion, an alicyclic ammonium ion or a heterocyclic ammonium ion, and M is a chromium atom, a cobalt atom or an iron atom.
    • 能够负电荷的电子照相调色剂包括:(a)粘合剂树脂; 和(b)电荷控制和着色剂,其包含至少一种式(I)的2:1型金属络合物:其中X1和X2各自可以相同或不同,为氢原子 ,C1-C5烷基,C1-C5烷氧基,硝基或卤原子,m和m'各自为1〜3的整数,R1和R2各自可以相同或不同 是氢原子,C1-C5烷基,C1-C5烷氧基,卤原子,硝基,磺酰胺基,甲基磺酰基,乙基磺酰基,乙酰基氨基或苯甲酰氨基, n和n'分别为1〜3的整数,Y(+)为铵离子,脂肪族铵离子,脂环族铵离子或杂环铵离子,M为铬原子,钴原子或 铁原子。
    • 4. 发明授权
    • Azo moiety containing metal complexes in toners
    • 在调色剂中含有金属络合物的偶氮部分
    • US4563409A
    • 1986-01-07
    • US668323
    • 1984-11-05
    • Nobuo SuzukiTakeo KurahashiKatsuichi MotohashiGenpei SugiyamaTakayuki Sakai
    • Nobuo SuzukiTakeo KurahashiKatsuichi MotohashiGenpei SugiyamaTakayuki Sakai
    • C09B44/02C09B45/14G03G9/09G03G9/08
    • G03G9/091C09B44/02C09B45/14
    • A symmetric 2:1 metal complex represented by the general formula: ##STR1## where R is a hydrogen atom, an alkyl group having from 1 to 10 carbon atoms, an alkoxy group having from 1 to 4 carbon atoms, an alkoxycarbonyl group having from 2 to 5 carbon atoms, an acyl group having from 2 to 5 carbon atoms, an aminocarbonyl group, an alklyaminocarbonyl group having from 2 to 5 carbon atoms, an alkylsulfonyl group having from 1 to 3 carbon atoms, an aminosulfonyl group, an acylamino group having from 2 to 5 carbon atoms, a nitro group, a cyano group or a halogen atom, m is an integer of from 1 to 4, when m is 2 or more, the plurality of R may be the same or different substituents, Q is --NHCO--Y--Z or --CONH--Y--Z (where Y is an alkylene group having from 1 to 4 carbon atoms, and Z is a quaternary ammonium group), M is a chromium atom or a cobalt atom, and X.sup..crclbar. is an anion.
    • 由下式通式表示的对称2:1金属络合物:其中R是氢原子,具有1至10个碳原子的烷基,具有1至4个碳原子的烷氧基,具有1至4个碳原子的烷氧基 2至5个碳原子,具有2至5个碳原子的酰基,氨基羰基,2至5个碳原子的烷基氨基羰基,1至3个碳原子的烷基磺酰基,氨基磺酰基,酰氨基 具有2至5个碳原子,硝基,氰基或卤素原子,m为1至4的整数,当m为2以上时,多个R可以相同或不同,取代基Q 是-NHCO-YZ或-CONH-YZ(其中Y是具有1至4个碳原子的亚烷基,Z是季铵基团),M是铬原子或钴原子,X( - )是 一种阴离子。