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    • 6. 发明授权
    • Catalytic distillation column reactor and tray
    • 催化蒸馏塔反应器和托盘
    • US5338517A
    • 1994-08-16
    • US884378
    • 1992-05-18
    • William T. Evans, IIIKarl Stork
    • William T. Evans, IIIKarl Stork
    • B01D3/00B01D3/20B01J8/00B01J8/22B01J8/18
    • B01J8/0015B01D3/009B01D3/20B01J8/226Y10S203/06
    • A distillation column reactor is provided having special trays arranged within the column to provide better mixing and thus achieve better mass and energy transfer between the liquid, vapor and catalyst. The trays comprise a slotted support plate for the catalyst with openings to allow vapor passage through the catalyst from the tray below. A draft chimney or riser is provided directly above the slotted openings to increase the vapor velocity and carry the liquid and catalyst upward on the tray. A hood is included at the upper end of the chimney to direct the liquid-vapor-catalyst flow back down onto the tray. The liquid from the tray above is distributed onto the tray about the chimney by distributors which preferably extend below the static catalyst level on the tray.
    • 提供蒸馏塔反应器,其具有布置在塔内的特殊托盘,以提供更好的混合,从而在液体,蒸气和催化剂之间实现更好的质量和能量传递。 托盘包括用于催化剂的开槽支撑板,其具有允许蒸汽从下面的托盘通过催化剂的开口。 在开槽开口正上方设有一个烟囱或提升管,以增加蒸汽速度,并将液体和催化剂在托盘上向上运送。 在烟囱的上端处包括罩,以将液体蒸气催化剂流回到托盘上。 来自上述托盘的液体通过优选地延伸到托盘上的静态催化剂水平以下的分配器而分布在烟囱周围的托盘周围。
    • 7. 发明授权
    • Products of the condensation of phenolmonosulfonic acids,
dihydroxydiphenyl sulfones, urea and formaldehyde
    • 苯二酚酸,二羟基二苯基硫醚,尿素和甲醛的浓缩产物
    • US5155164A
    • 1992-10-13
    • US696912
    • 1991-05-08
    • Hermann GrafAdolf StuebingerKlaus LorenzOrtwin SchafferKarl Stork
    • Hermann GrafAdolf StuebingerKlaus LorenzOrtwin SchafferKarl Stork
    • C08G14/02
    • C08G14/02
    • Products of the condensation of phenolmonosulfonic acids, dihydroxydiphenyl sulfones, urea and formaldehyde can be obtained by(A) preparing a homogeneous reaction mixture in sulfuric acid from the phenolmonosulfonic acid and dihydroxydiphenyl sulfone in the molar ratio of from 3:1 to 10:1, with the proviso that the water content of the mixture is not more than 10% of the total weight of the components, and the mixture contains from 0.3 to 1.5 moles of sulfuric acid per mole of dihydroxydiphenyl sulfone, at from 100.degree. to 180.degree. C.,(B) subsequently, at from 40.degree. to 90.degree. C., carrying out a precondensation with 1 to 2 moles of formaldehyde and 0.5 to 1.5 moles of urea per mole of phenol units present in aqueous medium,(C) partially neutralizing the reaction mixture,(D) adding to the partially neutralized reaction mixture 0 to 0.5 mole of phenol per mole of phenol units present and then 0.1 to 0.8 mole of formaldehyde per mole of phenol units then present,(E) further condensing at from 40.degree. to 90.degree. C.,(F) shifting the pH of the reaction mixture into the neutral range and(G) subsequently acidifying with a weak acid.
    • 苯酚磺酸,二羟基二苯基砜,脲和甲醛缩合的产物可以通过以下方法获得:(A)在苯磺酸和二羟基二苯基砜的硫酸中以3:1至10:1的摩尔比制备均匀的反应混合物, 条件是混合物的水含量不超过组分总重量的10%,并且混合物含有0.3至1.5摩尔硫酸/摩尔二羟基二苯基砜,在100至180℃ (B)随后在40℃至90℃下,每1摩尔含水介质中的苯酚单元进行1至2摩尔甲醛和0.5至1.5摩尔脲的预缩合,(C)部分中和 反应混合物中,(D)向部分中和的反应混合物中加入每摩尔苯酚单元0至0.5摩尔苯酚,然后存在每摩尔苯酚单元0.1至0.8摩尔甲醛,(E)进一步冷凝 在40℃至90℃下,(F)将反应混合物的pH转移到中性范围,(G)随后用弱酸酸化。