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    • 5. 发明授权
    • Thermoplastic resin composition for refrigerator having improved environmental stress crack resistance
    • 具有改善的耐环境应力开裂性的用于冰箱的热塑性树脂组合物
    • US07956128B2
    • 2011-06-07
    • US11769956
    • 2007-06-28
    • Kang Yeol ParkHee Jung ParkJae Hyung Lee
    • Kang Yeol ParkHee Jung ParkJae Hyung Lee
    • C08C19/22C08F8/30C08G63/48
    • C08L55/02C08F279/04C08L25/12C08L51/04C08L2205/02C08L2205/03C08L2666/24C08L2666/02C08L2666/04
    • A thermoplastic resin composition for a refrigerator according to the present invention can include (A) about 20 to about 40 parts by weight of an acrylonitrile-butadiene-styrene graft copolymer resin prepared by grafting in emulsion polymerization about 60 to about 30% by weight of a monomer mixture comprising a cyanide vinyl compound and an aromatic vinyl compound to about 40 to about 70% by weight of a rubber polymer having an average particle size of about 0.1 to about 0.4 μm; (B) about 1 to about 20 parts by weight of a styrenic copolymer comprising (b1) about 0 to about 75% by weight of a styrenic copolymer prepared by copolymerizing about 5 to about 20% by weight of a rubber polymer having an average particle size of about 0.1 to about 10 μm, about 10 to about 30% by weight of a cyanide vinyl compound, and about 65 to about 85% by weight of an aromatic vinyl compound, and (b2) about 25 to about 100% by weight of a styrenic copolymer prepared by copolymerizing about 5 to about 20% by weight of a rubber polymer having an average particle size of about 0.1 to about 10 μm and about 80 to about 95% by weight of an aromatic vinyl compound; and (C) about 50 to about 79 parts by weight of a cyanide vinyl-aromatic vinyl copolymer.
    • 根据本发明的用于冰箱的热塑性树脂组合物可以包括(A)约20至约40重量份的通过在乳液聚合中接枝制备的丙烯腈 - 丁二烯 - 苯乙烯接枝共聚物树脂,其中约60至约30重量% 包含氰化乙烯基化合物和芳族乙烯基化合物的单体混合物至约40至约70重量%的平均粒度为约0.1至约0.4μm的橡胶聚合物; (B)约1至约20重量份的苯乙烯共聚物,其包含(b1)约0至约75重量%的苯乙烯共聚物,其通过共聚合约5至约20重量%的具有平均颗粒的橡胶聚合物 约0.1至约10μm,约10至约30重量%的氰化乙烯基化合物和约65至约85重量%的芳族乙烯基化合物,和(b2)约25至约100重量% 通过共聚约5至约20重量%的平均粒度为约0.1至约10μm和约80至约95重量%的芳族乙烯基化合物的橡胶聚合物制备的苯乙烯共聚物; 和(C)约50至约79重量份的氰化乙烯基芳族乙烯基共聚物。