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1. 发明申请

WO2012037389A3 INKS WITH ALKALI METALS FOR THIN FILM SOLAR CELL PROCESSES 审中-公开
标题翻译： INKS与ALKALI金属薄膜太阳能电池工艺
公开(公告)号：WO2012037389A3
公开(公告)日：2012-05-31
申请号：PCT/US2011051815
申请日：2011-09-15
申请人： PRECURSOR ENERGETICS INC , FUJDALA KYLE L , ZHU ZHONGLIANG , PADOWITZ DAVID , MARKOFF JOHNSON PAUL R , CHOMITZ WAYNE A , KUCHTA MATTHEW C
发明人： FUJDALA KYLE L , ZHU ZHONGLIANG , PADOWITZ DAVID , MARKOFF JOHNSON PAUL R , CHOMITZ WAYNE A , KUCHTA MATTHEW C
IPC分类号： H01L31/18 , H01L31/0216 , H01L31/042
CPC分类号： H01L31/022425 , H01L21/0237 , H01L21/02485 , H01L21/02491 , H01L21/0251 , H01L21/02568 , H01L21/02576 , H01L21/02579 , H01L21/02581 , H01L21/02601 , H01L21/02628 , H01L31/0322 , H01L31/03923 , H01L31/046 , Y02E10/52 , Y02E10/541 , Y02P70/521
摘要： Processes for making a thin film solar cell on a substrate by providing a substrate coated with an electrical contact layer, depositing an ink onto the contact layer of the substrate, wherein the ink contains an alkali ion source compound suspended or dissolved in a carrier along with photovoltaic absorber precursor compounds, and heating the substrate. The alkali ion source compound can be MalkMB(ER)4 or Malk(ER). The processes can be used for CIS or CIGS.
摘要翻译：通过提供涂覆有电接触层的基材，在基板的接触层上沉积墨，在基板上制造薄膜太阳能电池的方法，其中所述墨含有悬浮或溶解在载体中的碱离子源化合物以及光伏吸收剂前体化合物，并加热基材。碱离子源化合物可以是MalkMB（ER）4或Malk（ER）。这些过程可用于CIS或CIGS。

2. 发明申请

WO2012037391A3 ANNEALING PROCESSES FOR PHOTOVOLTAICS 审中-公开
公开(公告)号：WO2012037391A3
公开(公告)日：2012-03-22
申请号：PCT/US2011/051817
申请日：2011-09-15
申请人： PRECURSOR ENERGETICS, INC. , FUJDALA, Kyle, L. , ZHU, Zhongliang , PADOWITZ, David , MARKOFF JOHNSON, Paul, R. , CHOMITZ, Wayne, A. , KUCHTA, Matthew C.
发明人： FUJDALA, Kyle, L. , ZHU, Zhongliang , PADOWITZ, David , MARKOFF JOHNSON, Paul, R. , CHOMITZ, Wayne, A. , KUCHTA, Matthew C.
IPC分类号： H01L31/042 , H01L31/18
摘要： Processes for making a solar cell by depositing various layers of components on a substrate and converting the components into a thin film photovoltaic absorber material. Processes of this disclosure can be used to control the stoichiometry of metal atoms in making a solar cell for targeting a particular concentration and providing a gradient of metal atom concentration. A selenium layer can be used in annealing a thin film photovoltaic absorber material.

3. 发明申请

WO2003051892A1 PARTIALLY FLUORINATED NAPHTHYL-BASED BORATES 审中-公开
标题翻译：部分氟化的基于硼酸的硼酸盐
公开(公告)号：WO2003051892A1
公开(公告)日：2003-06-26
申请号：PCT/US2002/036201
申请日：2002-11-12
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , RODRIGUEZ, George , RIX, Francis, C. , RAVISHANKAR, Periagaram, S. , KUCHTA, Matthew, C.
发明人： RODRIGUEZ, George , RIX, Francis, C. , RAVISHANKAR, Periagaram, S. , KUCHTA, Matthew, C.
IPC分类号： C07F5/00
CPC分类号： C08F10/00 , C07F5/027 , C08F4/65912 , C08F4/65927 , C08F210/16 , C08F4/65908 , C08F210/14 , C08F2500/17
摘要： Non-coordinating anions or anion precursors are disclosed. These non-coordinating anions serve as the activator for olefin polymerization catalyst systems. As such, they abstract an alkyl leaving group from a metallocene catalyst precursor leaving an activated catalyst charge balanced by a non-coordinating anion. These anions are formed by 3 or 4 partially fluorinated naphthyl ligands coordinated around boron (or other Group-13 element) creating corresponding tris-borane or tetrakis-borate complexes.
摘要翻译：公开了非配位阴离子或阴离子前体。这些非配位阴离子用作烯烃聚合催化剂体系的活化剂。因此，它们从茂金属催化剂前体中抽出烷基离去基团，留下由非配位阴离子平衡的活化催化剂电荷。这些阴离子由3或4个部分氟化的萘配体形成，硼配位在硼（或其他13族元素）周围，产生相应的三 - 硼烷或四硼酸盐络合物。

4. 发明申请

WO2011017235A9 METHODS FOR PHOTOVOLTAIC ABSORBERS WITH CONTROLLED STOICHIOMETRY 审中-公开
标题翻译：用于具有受控制的光刻胶的光伏吸收器的方法
公开(公告)号：WO2011017235A9
公开(公告)日：2011-09-22
申请号：PCT/US2010044054
申请日：2010-08-02
申请人： PRECURSOR ENERGETICS INC , FUJDALA KYLE L , CHOMITZ WAYNE A , ZHU ZHONGLIANG , KUCHTA MATTHEW C , HUANG QINGLAN
发明人： FUJDALA KYLE L , CHOMITZ WAYNE A , ZHU ZHONGLIANG , KUCHTA MATTHEW C , HUANG QINGLAN
IPC分类号： H01L31/042 , H01L31/0216
CPC分类号： H01L31/18 , C09D11/52 , H01L31/0322 , Y02E10/541 , Y02P70/521
摘要： This invention includes processes for making a photovoltaic absorber layer having a predetermined stoichiometry on a substrate by depositing a precursor having the predetermined stoichiometry onto the substrate and converting the deposited precursor into a photovoltaic absorber material. This invention further includes processes for making a photovoltaic absorber layer having a predetermined stoichiometry on a substrate by (a) providing a polymeric precursor having the predetermined stoichiometry; (b) providing a substrate; (c) depositing the precursor onto the substrate; and (d) heating the substrate.
摘要翻译：本发明包括通过将具有预定化学计量的前体沉积到衬底上并将沉积的前体转化成光伏吸收材料来制造在衬底上具有预定化学计量的光伏吸收层的方法。本发明还包括通过（a）提供具有预定化学计量的聚合物前体制备在基底上具有预定化学计量的光伏吸收剂层的方法; （b）提供基材; （c）将前体沉积到基底上; 和（d）加热基材。

5. 发明申请

WO2011017235A3 METHODS FOR PHOTOVOLTAIC ABSORBERS WITH CONTROLLED STOICHIOMETRY 审中-公开
标题翻译：具有控制化学计量的光伏吸收剂的方法
公开(公告)号：WO2011017235A3
公开(公告)日：2011-06-03
申请号：PCT/US2010044054
申请日：2010-08-02
申请人： PRECURSOR ENERGETICS INC , FUJDALA KYLE L , CHOMITZ WAYNE A , ZHU ZHONGLIANG , KUCHTA MATTHEW C , HUANG QINGLAN
发明人： FUJDALA KYLE L , CHOMITZ WAYNE A , ZHU ZHONGLIANG , KUCHTA MATTHEW C , HUANG QINGLAN
IPC分类号： H01L31/042 , H01L31/0216
CPC分类号： H01L31/18 , C09D11/52 , H01L31/0322 , Y02E10/541 , Y02P70/521
摘要： This invention includes processes for making a photovoltaic absorber layer having a predetermined stoichiometry on a substrate by depositing a precursor having the predetermined stoichiometry onto the substrate and converting the deposited precursor into a photovoltaic absorber material. This invention further includes processes for making a photovoltaic absorber layer having a predetermined stoichiometry on a substrate by (a) providing a polymeric precursor having the predetermined stoichiometry; (b) providing a substrate; (c) depositing the precursor onto the substrate; and (d) heating the substrate.
摘要翻译：本发明包括通过在衬底上沉积具有预定化学计量的前体并且将沉积的前体转换成光伏吸收体材料来在衬底上制造具有预定化学计量的光伏吸收体层的方法。本发明还包括通过以下步骤制备在基底上具有预定化学计量的光电吸收层的方法：（a）提供具有预定化学计量的聚合物前体; （b）提供衬底; （c）将前体沉积到基底上; 和（d）加热基材。

6. 发明申请

WO2011017238A3 POLYMERIC PRECURSORS FOR CAIGAS ALUMINUM-CONTAINING PHOTOVOLTAICS 审中-公开
公开(公告)号：WO2011017238A3
公开(公告)日：2011-02-10
申请号：PCT/US2010/044057
申请日：2010-08-02
申请人： PRECURSOR ENERGETICS, INC. , FUJDALA, Kyle L. , CHOMITZ, Wayne A. , ZHU, Zhongliang , KUCHTA, Matthew C.
发明人： FUJDALA, Kyle L. , CHOMITZ, Wayne A. , ZHU, Zhongliang , KUCHTA, Matthew C.
IPC分类号： C07F19/00 , C08G79/00 , C09D11/00 , B05D1/02 , H01L31/04
摘要： This invention relates to compounds, polymeric compounds, and compositions used to prepare semiconductor and optoelectronic materials and devices including thin film and band gap materials. This invention provides a range of compounds, polymeric compounds, compositions, materials and methods directed ultimately toward photovoltaic applications, transparent conductive materials, as well as devices and systems for energy conversion, including solar cells. In particular, this invention relates to polymeric precursor compounds and precursor materials for preparing photovoltaic layers. In particular, this invention relates to molecular precursor compounds and precursor materials for preparing photovoltaic layers including CAIGAS.

7. 发明申请

WO2011017237A2 POLYMERIC PRECURSORS FOR CAIGS AND AIGS SILVER-CONTAINING PHOTOVOLTAICS 审中-公开
标题翻译：聚合物前驱体用于含银光伏的CAIGS和AIGS
公开(公告)号：WO2011017237A2
公开(公告)日：2011-02-10
申请号：PCT/US2010/044056
申请日：2010-08-02
申请人： PRECURSOR ENERGETICS, INC. , FUJDALA, Kyle L. , CHOMITZ, Wayne A. , ZHU, Zhongliang , KUCHTA, Matthew C. , HUANG, Qinglan
发明人： FUJDALA, Kyle L. , CHOMITZ, Wayne A. , ZHU, Zhongliang , KUCHTA, Matthew C. , HUANG, Qinglan
IPC分类号： C07F19/00 , C08G79/00 , C09D11/00 , B05D1/02 , H01L31/04
CPC分类号： C07F1/005 , C07C391/00 , C09D11/02 , C09D11/52 , Y10T428/13 , Y10T428/24628 , Y10T428/263 , Y10T428/265 , Y10T428/2958 , Y10T428/31678
摘要： This invention relates to compounds, polymeric compounds, and compositions used to prepare semiconductor and optoelectronic materials and devices including thin film and band gap materials. This invention provides a range of compounds, polymeric compounds, compositions, materials and methods directed ultimately toward photovoltaic applications, transparent conductive materials, as well as devices and systems for energy conversion, including solar cells. In particular, this invention relates to polymeric precursor compounds and precursor materials for preparing photovoltaic layers. A precursor compound may contain repeating units {M B (ER)(ER)} and {M A (ER)(ER)}, wherein each M A is Cu or Ag, each M B is In or Ga, each E is S, Se, or Te, and each R is independently selected, for each occurrence, from alkyl, aryl, heteroaryl, alkenyl, amido, silyl, and inorganic and organic ligands.
摘要翻译：本发明涉及用于制备包括薄膜和带隙材料的半导体和光电子材料和器件的化合物，聚合物化合物和组合物。本发明提供了一系列最终针对光伏应用的化合物，聚合物化合物，组合物，材料和方法，透明导电材料以及用于能量转换的装置和系统，包括太阳能电池。特别地，本发明涉及用于制备光伏层的聚合前体化合物和前体材料。前体化合物可以含有重复单元{M B（ER）（ER）}和{M A（ER）（ER）}，其中每个M A Cu或Ag，每个M B是In或Ga，每个E是S，Se或Te，并且每个R在每次出现时独立地选自烷基，芳基，杂芳基，烯基，酰胺基，甲硅烷基和无机和有机配体。

8. 发明申请

WO2006096881A1 METHODS FOR OLIGOMERIZING OLEFINS 审中-公开
标题翻译：低聚烯烃的方法
公开(公告)号：WO2006096881A1
公开(公告)日：2006-09-14
申请号：PCT/US2006/008926
申请日：2006-03-09
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , ACKERMAN, Lily, J. , BEI, Xiaohong , BOUSSIE, Thomas, R. , DIAMOND, Gary, M. , HALL, Keith, A. , LAPOINTE, Anne, M. , LONGMIRE, James, M. , MURPHY, Vincent, J. , SUN, Pu , VERDUGO, Dawn , SCHOFER, Susan , DIAS, Eric , MCCONVILLE, David, H. , LI, Robert, T. , WALZER, John , RIX, Francis , KUCHTA, Matthew
发明人： ACKERMAN, Lily, J. , BEI, Xiaohong , BOUSSIE, Thomas, R. , DIAMOND, Gary, M. , HALL, Keith, A. , LAPOINTE, Anne, M. , LONGMIRE, James, M. , MURPHY, Vincent, J. , SUN, Pu , VERDUGO, Dawn , SCHOFER, Susan , DIAS, Eric , MCCONVILLE, David, H. , LI, Robert, T. , WALZER, John , RIX, Francis , KUCHTA, Matthew
IPC分类号： C07C2/32 , C08F4/69 , C08F10/02
CPC分类号： C07C2/32 , C07C2531/22 , C08F10/00 , C08F110/02 , C08F2500/02 , C08F4/69103 , C08F4/69146 , C08F4/69275 , C07C11/02 , C07C11/107
摘要： The present invention provides a method of producing oligomers of olefins, comprising reacting olefins with a catalyst under oligomerization conditions. The catalyst can be the product of the combination of a chromium compound and a pyridyl amine or a heteroaryl-amine compound. In particular embodiments, the catalyst compound can be used to trimerize or tetramerize ethylene to 1-hexene, 1-octene, or mixtures of 1-hexene and 1-octene.
摘要翻译：本发明提供一种生产烯烃低聚物的方法，包括在低聚条件下使烯烃与催化剂反应。催化剂可以是铬化合物和吡啶基胺或杂芳基 - 胺化合物的组合的产物。在具体实施方案中，催化剂化合物可用于将乙烯三聚或四聚为1-己烯，1-辛烯或1-己烯和1-辛烯的混合物。

9. 发明申请

WO2005068514A1 OLEFIN POLYMERIZATION CATALYST SYSTEM 审中-公开
标题翻译： OLEFIN聚合催化剂体系
公开(公告)号：WO2005068514A1
公开(公告)日：2005-07-28
申请号：PCT/US2004/036845
申请日：2004-11-05
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , KUCHTA, Matthew, C. , RIX, Francis, C.
发明人： KUCHTA, Matthew, C. , RIX, Francis, C.
IPC分类号： C08F10/00
CPC分类号： C08F210/18 , C07F7/00 , C07F7/006 , C07F7/28 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F210/06 , C08F4/659 , C08F4/64151 , C08F236/20 , C08F2500/11 , C08F2500/17 , C08F2500/21 , C08F2500/25
摘要： This invention relates to a catalyst precursor compound comprising a tridentate phenoxy-amide-amine group bound to a group 3 to 12 metal or lanthanide metal. In particular, this invention relates to a catalyst precursor compound represented by the formula wherein: M is a group 3 to group 12 transition metal or lanthanide metal, provided however N' is not part of a pyridine ring when M is a group 8, 9, or 10 metal; Q is oxygen or sulfur; N is nitrogen; N 1 is nitrogen; R 1 , is a hydrogen, a hydrocarbyl, a substituted hydrocarbyl, a halocarbyl, a substituted halocarbyl, a heteroatom or heteroatom containing group; R 2 and R 3 are independently, a hydrogen, a halogen, a hydrocarbyl, a substituted hydrocarbyl, a halocarbyl, or a substituted halocarbyl, a heteroatom or heteratom containing group and R 2 and R 3 together may form a multidentate ligand, such as a bidentate dianionic ligand; R 4 is hydrogen, a hydrocarbyl, a substituted hydrocarbyl, a halocarbyl, a substituted halocarbyl, a heteroatom or heteroatom containing group; R 5 is a hydrogen, a hydrocarbyl, a substituted hydrocarbyl, a halocarbyl, a substituted halocarbyl, a heteroatom or heteroatom containing group; R 6 , R 7 , and R 8 are, independently, a hydrogen, a hydrocarbyl, a substituted hydrocarbyl, a halocarbyl, a substituted halocarbyl, a heteroatom or heteroatom containing group, and any two of R 1 , R 6 , R 7 , and R 8 may form a fused ring system; each R 9 is, independently, hydrogen, a hydrocarbyl, a substituted hydrocarbyl, a halocarbyl, a substituted halocarbyl group, or a heteroatom or heteroatom containing group; R 10 is a hydrocarbyl, a substituted hydrocarbyl, a halocarbyl, a substituted halocarbyl group, or a heteroatom or heteroatom containing group; where any two adjacent R groups may form a ring structure.
摘要翻译：本发明涉及一种催化剂前体化合物，其包含与第3〜12族金属或镧系元素金属结合的三齿苯氧基 - 酰胺 - 胺基。特别地，本发明涉及由下式表示的催化剂前体化合物：其中M是第3族至第12族过渡金属或镧系元素金属，但是当M为第8,9族时，N'不是吡啶环的一部分，或10金属; Q是氧或硫; N是氮; N 1是氮; R1，是氢，烃基，取代的烃基，卤代烃基，取代的卤代烃基，杂原子或杂原子的基团; R 2和R 3独立地为氢，卤素，烃基，取代的烃基，卤代烃基或取代的卤代烃基，杂原子或含杂原子的基团，并且R 2和R 3一起可以形成多齿配体，例如二齿二离子配体 ; R 4是氢，烃基，取代的烃基，卤代烃基，取代的卤代烃基，杂原子或含杂原子的基团; R5是氢，烃基，取代的烃基，卤代烃基，取代的卤代烃基，杂原子或含杂原子的基团; R 6，R 7和R 8独立地为氢，烃基，取代的烃基，卤代烃基，取代的卤代烃基，杂原子或含杂原子的基团，R 1，R 6，R 7和R 8中的任何两个可以形成稠合环系; 每个R 9独立地是氢，烃基，取代的烃基，卤代烃基，取代的卤代烃基或含杂原子或杂原子的基团; R 10是烃基，取代的烃基，卤代烃基，取代的卤代烃基或含杂原子或杂原子的基团; 其中任何两个相邻的R基团可以形成环结构。

10. 发明申请

WO2012037391A2 ANNEALING PROCESSES FOR PHOTOVOLTAICS 审中-公开
标题翻译：光伏行业的退火流程
公开(公告)号：WO2012037391A2
公开(公告)日：2012-03-22
申请号：PCT/US2011051817
申请日：2011-09-15
申请人： PRECURSOR ENERGETICS INC , FUJDALA KYLE L , ZHU ZHONGLIANG , PADOWITZ DAVID , MARKOFF JOHNSON PAUL R , CHOMITZ WAYNE A , KUCHTA MATTHEW C
发明人： FUJDALA KYLE L , ZHU ZHONGLIANG , PADOWITZ DAVID , MARKOFF JOHNSON PAUL R , CHOMITZ WAYNE A , KUCHTA MATTHEW C
IPC分类号： H01L31/042 , H01L31/18
CPC分类号： H01L31/022425 , H01L21/0237 , H01L21/02485 , H01L21/02491 , H01L21/0251 , H01L21/02568 , H01L21/02576 , H01L21/02579 , H01L21/02581 , H01L21/02601 , H01L21/02628 , H01L31/0322 , H01L31/03923 , H01L31/046 , Y02E10/52 , Y02E10/541 , Y02P70/521
摘要： Processes for making a solar cell by depositing various layers of components on a substrate and converting the components into a thin film photovoltaic absorber material. Processes of this disclosure can be used to control the stoichiometry of metal atoms in making a solar cell for targeting a particular concentration and providing a gradient of metal atom concentration. A selenium layer can be used in annealing a thin film photovoltaic absorber material.
摘要翻译：通过在基底上沉积各层组分并将这些组分转化成薄膜光伏吸收剂材料来制造太阳能电池的方法。本公开的方法可用于控制金属原子的化学计量，以制造用于靶向特定浓度的太阳能电池并提供金属原子浓度的梯度。硒层可用于退火薄膜光伏吸收剂材料。

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