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1. 发明专利

TWI299049B 含水解性矽元素不飽和有機化合物及其製造方法,含矽原子聚合物及其乳液 HYDROLIZABLE SILICON-CONTAINING UNSATURATED ORGANIC COMPOUND AND ITS PRODUCTION METHOD, SILICON-CONTAINING POLYMER AND EMULISION THEREOF 失效
简体标题：含水解性硅元素不饱和有机化合物及其制造方法,含硅原子聚合物及其乳液 HYDROLIZABLE SILICON-CONTAINING UNSATURATED ORGANIC COMPOUND AND ITS PRODUCTION METHOD, SILICON-CONTAINING POLYMER AND EMULISION THEREOF
公开(公告)号：TWI299049B
公开(公告)日：2008-07-21
申请号：TW091112859
申请日：2002-06-13
申请人：可尼西股份有限公司 KONISHI CO., LTD.
发明人：佐藤慎一 SHINICHI SATO , 折口俊樹 TOSHIKI ORIGUCHI , 佐藤明寬 AKIHIRO SATO , 小川慎太郎 SHINTARO OGAWA , 川島康一郎 KOICHIRO KAWASHIMA , 井上文子 AYAKO INOUE , 森茂樹 SHIGEKI MORI , 野村幸弘 YUKIHIRO NOMURA
IPC分类号： C08L , C07F
CPC分类号： C07F7/18 , C08L71/02
摘要：本發明之含水解性矽元素之不飽和有機化合物之特徵
為如下述式[I]所示。

[式(1)中W為多價有機基。m、n為相同或不同之1以上之
整數。p為0或1、q為0或1。R1為「-NHCO-」或「-
OCOC(R4a)H-C(R4b)(R4c)-」,R4a、R4b、R4c為相同或不
同之氫原子或烴基。R2為具有碳-碳不飽和鍵之有機基。
R3為「-COO-」、「-R5O-」、「-R5S-CONH-」、「-
R5N(R6)-CONH-」或「-R5O-CONH-」,R5為2價有
機基,R6為氫原子或有機基。p、q至少有一個為1。
X為下述式(2a)至(2d)所示之基。但是,p為1且R3
為「-COO-」或「-R5O-」之同時q為1且R1為「-
OCOC(R4a)H-C(R4b)(R4c)-」時X不為下述式(2c)。

-S-R11-Si(OR8)t(R9)3-t (2c)
-Si(OR8)t(R9)3-t (2d)
式(2a)至(2d)中R7為2價有機基。R8、R9可相同或不
同,為氫原子或烴基。R10為2價有機基。R11為2價有機
基。Y為「可具有-Si(OR12a)h(R13a)3-h之有機基(R12a、R13a
可相同或不同,為氫原子或烴基、h為1至3之整數)」。
Y1、Y2為相同或不同之「可具有-Si(OR12b)i(R13b)3-i基之
有機基(R12b、R13b可相同或不同為氫原子或烴基、i為1
至3之整數)」。t為1至3之整數]
若使用本發明之含水解性矽元素不飽和有機化合物則
可提高黏合劑、密封材料、塗覆材料等之黏合性或抗水性
等性能。又,含有以本發明之含水解性矽元素不飽和有機
化合物作為單體成分之含水解性矽元素聚合物之乳液可作
為塗料等塗覆劑所使用之乳液。因此,本發明之含水解性
矽元素不飽和有機化合物、含水解性矽元素聚合物或該乳
液可用作為黏合劑、密封劑、塗覆劑(塗料等)之成分。
简体摘要：本发明之含水解性硅元素之不饱和有机化合物之特征为如下述式[I]所示。 [式(1)中W为多价有机基。m、n为相同或不同之1以上之整数。p为0或1、q为0或1。R1为“-NHCO-”或“- OCOC(R4a)H-C(R4b)(R4c)-”,R4a、R4b、R4c为相同或不同之氢原子或烃基。R2为具有碳-碳不饱和键之有机基。 R3为“-COO-”、“-R5O-”、“-R5S-CONH-”、“- R5N(R6)-CONH-”或“-R5O-CONH-”,R5为2价有机基,R6为氢原子或有机基。p、q至少有一个为1。 X为下述式(2a)至(2d)所示之基。但是,p为1且R3 为“-COO-”或“-R5O-”之同时q为1且R1为“- OCOC(R4a)H-C(R4b)(R4c)-”时X不为下述式(2c)。 -S-R11-Si(OR8)t(R9)3-t (2c) -Si(OR8)t(R9)3-t (2d) 式(2a)至(2d)中R7为2价有机基。R8、R9可相同或不同,为氢原子或烃基。R10为2价有机基。R11为2价有机基。Y为“可具有-Si(OR12a)h(R13a)3-h之有机基(R12a、R13a 可相同或不同,为氢原子或烃基、h为1至3之整数)”。 Y1、Y2为相同或不同之“可具有-Si(OR12b)i(R13b)3-i基之有机基(R12b、R13b可相同或不同为氢原子或烃基、i为1 至3之整数)”。t为1至3之整数] 若使用本发明之含水解性硅元素不饱和有机化合物则可提高黏合剂、密封材料、涂覆材料等之黏合性或抗水性等性能。又,含有以本发明之含水解性硅元素不饱和有机化合物作为单体成分之含水解性硅元素聚合物之乳液可作为涂料等涂覆剂所使用之乳液。因此,本发明之含水解性硅元素不饱和有机化合物、含水解性硅元素聚合物或该乳液可用作为黏合剂、密封剂、涂覆剂(涂料等)之成分。

2. 发明专利

TW200741058A 纖維製品用撥水劑审中-公开
简体标题：纤维制品用拨水剂
公开(公告)号：TW200741058A
公开(公告)日：2007-11-01
申请号：TW096106699
申请日：2007-02-27
申请人：小西股份有限公司 KONISHI CO., LTD.
发明人：井手本憲二 IDEMOTO KENJI , 澤本彰 SAWAMOTO AKIRA
IPC分类号： D06M
CPC分类号： D06M23/08 , D06M11/79 , D06M2200/11
摘要：本發明提供一種可賦予纖維製品良好撥水性之撥水劑。又,本發明提供一種以手指接觸於纖維製品表面上所賦予之撥水劑時,不易沾黏於手指上之撥水劑。本發明之撥水劑實質上含有:(a)平均一次粒徑未滿30nm之疏水性二氧化矽微粒子、(b)皮膜形成性醇鈦(titanium alkoxide)或其部分水解縮合物、與(c)用以使疏水性二氧化矽微粒子分散之分散介質。作為疏水性二氧化矽微粒子,可使用日本Aerosil公司製造之Aerosil R812、Aerosil R974、Aerosil RY200。作為皮膜形成性醇鈦類,可使用四異丙醇鈦、四丁醇鈦、四-2-乙基己醇鈦或該等之部分水解縮合物。作為分散介質,可使用異己烷、異辛烷或異壬烷。該撥水劑基本上不含(a)~(c)成分以外之成分。
简体摘要：本发明提供一种可赋予纤维制品良好拨水性之拨水剂。又,本发明提供一种以手指接触于纤维制品表面上所赋予之拨水剂时,不易沾黏于手指上之拨水剂。本发明之拨水剂实质上含有:(a)平均一次粒径未满30nm之疏水性二氧化硅微粒子、(b)皮膜形成性醇钛(titanium alkoxide)或其部分水解缩合物、与(c)用以使疏水性二氧化硅微粒子分散之分散介质。作为疏水性二氧化硅微粒子,可使用日本Aerosil公司制造之Aerosil R812、Aerosil R974、Aerosil RY200。作为皮膜形成性醇钛类,可使用四异丙醇钛、四丁醇钛、四-2-乙基己醇钛或该等之部分水解缩合物。作为分散介质,可使用异己烷、异辛烷或异壬烷。该拨水剂基本上不含(a)~(c)成分以外之成分。

3. 发明专利

CA2617276C STRIPPABLE FLOOR COATING AND METHOD OF FORMING THE COATING 未知
公开(公告)号：CA2617276C
公开(公告)日：2012-01-24
申请号：CA2617276
申请日：2006-07-28
申请人： DUSKIN CO LTD , KONISHI CO LTD
发明人： OGINO FUMITOSHI , OKURA YOSHIO
IPC分类号： C09D5/20 , B05D5/00 , C09G1/04 , C09G1/08 , C09G1/14 , E04F15/12
摘要： Disclosed is a strippable floor coating which includes an undercoat layer (A) to be applied to a floor surface, and a strippable overcoat layer (B) over the undercoat layer (A). The undercoat layer (A) is formed from an undercoating agent mainly containing a wax or analogue thereto and having film-formability. The overcoat layer (B) is formed from a floor polish composition mainly containing an aqueous emulsion. The undercoat layer (A) has greater adhesion to the floor surface than to the overcoat layer (B). Even when applied to various flooring materials, this strippable floor coating does not peel off practically and is excellent in soiling resistance and wear resistance to retain a beautiful appearance over long time. If necessary, the coating can be easily stripped off.

4. 发明专利

HK1130666A1 HAIR COSMETIC 未知
公开(公告)号：HK1130666A1
公开(公告)日：2010-01-08
申请号：HK09108636
申请日：2009-09-22
申请人： SHISEIDO CO LTD , KONISHI CO LTD
IPC分类号： A61K20060101 , A61Q20060101 , C08F20060101 , C08G20060101
摘要： Provided is a hair cosmetic that can exhibit hair styling capability, natural finishing capability, and hair style retentivity respectively at superior levels. The hair cosmetic contains a urethane-modified acrylic polymer having a structure in which a urethane polymer chain is bonded to an acrylic polymer chain through a linkage segment having a silicon-oxygen bond, in which the acrylic polymer chain is a residue of an acrylic polymer derived at least from an acrylic monomer (A) and a compound (B1) and/or a compound (B2), where the compound (B1) has a hydrolyzable silicon-containing group and an ethylenically unsaturated bond-containing group, and the compound (B2) has a hydrolyzable silicon-containing group and a mercapto group, and the urethane polymer chain is a residue of a urethane polymer (C) having a hydrolyzable silicon-containing group. The linkage segment in the urethane-modified acrylic polymer is preferably a silicone polymer chain.

5. 发明专利

HK1098491A1 VINYL-URETHANE COPOLYMER AND METHOD FOR PRODUCING SAME 未知
公开(公告)号：HK1098491A1
公开(公告)日：2007-07-20
申请号：HK07104857
申请日：2007-05-07
申请人： KONISHI CO LTD
IPC分类号： C08G20090101 , C08G81/00
摘要： To provide vinyl-urethane copolymers that can form cured articles having excellent hot-water resistance, water resistance, heat resistance, and weather resistance, and to provide production methods thereof. A vinyl-urethane copolymer contains at least one vinyl polymer chain and at least one urethane polymer chain, in which the vinyl polymer chain is combined with the urethane polymer chain through a linkage segment having a silicon-oxygen bond. A method produces a vinyl-urethane copolymer comprising at least one vinyl polymer chain and at least one urethane polymer chain, in which the vinyl polymer chain is combined with the urethane polymer chain through a linkage segment having a silicon-oxygen bond, by following Steps (X) and (Y): Step (X) of carrying out preparation of an aqueous dispersion or aqueous solution of a urethane polymer (A) having at least one silicon-containing hydrolyzable group; and Step (Y) of, in the aqueous dispersion or aqueous solution of the urethane polymer (A) having at least one silicon-containing hydrolyzable group, carrying out polymerization of an ethylenically unsaturated monomer (B) and carrying out preparation of a vinyl-urethane copolymer using a compound (C) having at least one functional group reactive with a silicon-containing hydrolyzable group and at least one functional group reactive with an ethylenically unsaturated bond-containing group in at least one period selected from before the polymerization reaction, during the polymerization reaction, and after the polymerization reaction.

6. 发明专利

HK1090071A1 Aqueous silylated urethane composition, aqueous adhesives for wrapping, and aqueous contact adhesives 未知
公开(公告)号：HK1090071A1
公开(公告)日：2006-12-15
申请号：HK06110377
申请日：2006-09-19
申请人： KONISHI CO LTD
IPC分类号： C08G20060101 , C08L75/04 , C08G18/08 , C08G18/12 , C08G18/28 , C08G18/83 , C08K20060101 , C08K5/17 , C08L20060101 , C09J20060101 , C09J175/04
摘要： A water-based silylated urethane composition is used as a water-based adhesive that has high safety, develops satisfactory tackiness in a short time and has excellent initial bond strength. The water-based silylated urethane composition contains following Components (A), (B) and (C): (A) a urethane prepolymer containing an anionic group and a tertiary amino group and having a terminal alkoxysilyl group, the urethane prepolymer (A) being a reaction product of an anionic-group-free polyol compound (A1), an anionic-group-containing polyol compound (A2), a compound (A3) containing a tertiary amino group and an isocyanate-reactive group, a polyisocyanate compound (A4), an alkoxysilane compound (A5) containing an isocyanate-reactive group, and an amine-based chain extender (A6); (B) a basic compound; and (C) water

7. 发明专利

DE60012442T2 未知
公开(公告)号：DE60012442T2
公开(公告)日：2004-12-02
申请号：DE60012442
申请日：2000-02-15
申请人： KONISHI CO LTD
发明人： ORIGUCHI TOSHIKI , OGAWA SHINTARO
IPC分类号： C08F2/44 , C08F2/16 , C08F2/22 , C08F18/08 , C08F255/02 , C08F263/04 , C08F285/00 , C08L51/00 , C09D151/00 , C09J131/04 , C09J151/00 , C09J151/06 , C09K19/04
摘要： A process of the invention produces a vinyl acetate polymer based emulsion by seed polymerization of vinyl acetate in an ethylene-vinyl acetate copolymer based emulsion. This process includes a step of performing seed polymerization while adding vinyl acetate to a system, and, prior to or subsequent to the step, a step of adding a polymerizable unsaturated monomer other than vinyl acetate to the system. The amount of the polymerizable unsaturated monomer other than vinyl acetate is, for example, about 0.05 to 10 parts by weight relative to 100 parts by weight of vinyl acetate. At least one monomer selected from acrylic esters, methacrylic esters, vinyl esters, and vinyl ethers can be used as the polymerizable unsaturated monomer other than vinyl acetate. The invented process can produce a vinyl acetate polymer based emulsion which has satisfactory low-temperature film-forming property and adhesive strength, even containing no plasticizer, and which can exhibit a high adhesive strength even when cured at low temperatures.

8. 发明专利

DE69410388T2 未知
公开(公告)号：DE69410388T2
公开(公告)日：1998-10-29
申请号：DE69410388
申请日：1994-10-19
申请人： DENKI KAGAKU KOGYO KK , KONISHI CO LTD
发明人： SATOH MIKITOSHI , KOGA MASAO , NAGASAWA SHIGERU , ASANO KUNIHIKO , UENOYAMA TOSHIYUKI , ONISHI KUNIHIRO
IPC分类号： C08F236/18 , C09J111/02 , C09J113/02
摘要： A method for producing a polychloroprene latex, which comprises copolymerizing chloroprene and an ethylenically unsaturated carboxylic acid in the presence of a polyvinyl alcohol, wherein a glycol ether is also present during the copolymerization.

9. 发明专利

DE60237096D1 BEFESTIGUNGS-/EINSTELLWERKZEUG FÜR PLATTENMATERIAL 未知
公开(公告)号：DE60237096D1
公开(公告)日：2010-09-02
申请号：DE60237096
申请日：2002-10-01
申请人： KONISHI CO LTD
发明人： FUKURA MASAOMI , OKAMOTO SHINICHI , HAMANISHI YOICHI
IPC分类号： E04F13/08 , F16B5/00 , F16B11/00

10. 发明专利

AT474976T 未知
公开(公告)号：AT474976T
公开(公告)日：2010-08-15
申请号：AT02775276
申请日：2002-10-01
申请人： KONISHI CO LTD
发明人： FUKURA MASAOMI , OKAMOTO SHINICHI , HAMANISHI YOICHI
IPC分类号： E04F13/08 , F16B5/00 , F16B11/00
摘要： Fixing/adjusting tools of the plate material to the structural body having a female member 1 and a male member 11 in which members are fitted to each other in an adjustable length, members are glued either to the structural body or the plate material respectively and members set in the adjusted length are settled by the adhesive, wherein the adhesive is previously injected before the adjusting the distance between the material plate and the structural body. The female member 1 has a base plate with a through hole 13 in a center and an external cylinder fixed vertically on the base plate. The male member has a base plate with a through hole 13 in a center and an internal cylinder fixed vertically on the base plate. The gap is formed between the inner wall of the external cylinder and the outer wall of the internal cylinder. The communicating section 6 is formed in the base of the female member 1 communicating with the gap. The guide cylinder 14 is formed protruding on the base plate of the male member 11 to guide the nozzle for injecting adhesive. In the contracted condition of the internal and external cylinders, the front edge of the guide cylinder meets an opening edge of the through hole 3 of the female member. Resultantly, the adhesive injected through the guide cylinder into the rear surface of the base plate of the female member, reach the gap between the internal and external cylinders passing the communicating section.

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