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    • 2. 发明申请
    • ELECTROLYTE SYSTEM AND ENERGY STORAGE DEVICE USING SAME
    • 电解质系统和使用相同的能源储存装置
    • WO2003058746A1
    • 2003-07-17
    • PCT/US2002/039451
    • 2002-12-10
    • QUALLION LLCTSUKAMOTO, HisashiKOIKE, Tsuneaki
    • TSUKAMOTO, HisashiKOIKE, Tsuneaki
    • H01M10/40
    • H01M10/0567H01M4/485H01M4/525H01M6/5088H01M10/0525H01M10/0568H01M10/0569H01M10/058H01M10/4235H01M2300/0025Y10T29/49108
    • A secondary cell employs a nonaqueous electrolyte solution including a nonaqueous solvent and a salt, and a flame retardant material that is liquid at room temperature and pressure and substantially immiscible in the nonaqueous electrolyte solution. The nonaqueous electrolyte solution is formed by dissolving a salt, preferably an alkali metal salt, in a nonaqueous solvent. The nonaqueous solvent preferably includes a cyclic carbonate and/or a linear carbonate. The cyclic carbonate preferably contains an alkylene group with 2 to 5 carbon atoms, and the linear carbonate preferably contains a hydrocarbon group with 1 to 5 carbon atoms. Preferred salts include LiPF 6 and LiBF 4 at a concentration between about 0.1 and 3.0 moles/liter. The flame retardant material is preferably a halogen-containing compound in an amount by weight of nonaqueous solvent in a range of about 1 to about 99 wt%, and preferred halogen-containing compounds contain perfluoralkyl or perfluorether groups.
    • 二次电池采用包含非水溶剂和盐的非水电解质溶液,以及在室温和压力下液体并且在非水电解质溶液中基本上不混溶的阻燃材料。 非水电解质溶液通过将盐,优选碱金属盐溶解在非水溶剂中而形成。 非水溶剂优选包含环状碳酸酯和/或直链碳酸酯。 环状碳酸酯优选含有碳原子数2〜5的亚烷基,直链状碳酸酯优选含有碳原子数为1〜5的烃基。 优选的盐包括浓度为约0.1至3.0摩尔/升的LiPF 6和LiBF 4。 阻燃材料优选为非水溶剂的重量含量为约1-约99重量%的含卤素化合物,优选的含卤素化合物含有全氟烷基或全氟醚基团。