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1. 发明申请

WO2012008717A3 APPARATUS FOR COPRODUCTING ISO TYPE REACTION PRODUCTS AND ALCOHOLS FROM OLEFINS, AND METHOD FOR COPRODUCTING THEM USING THE APPARATUS 审中-公开
公开(公告)号：WO2012008717A3
公开(公告)日：2012-01-19
申请号：PCT/KR2011/005046
申请日：2011-07-11
申请人： LG CHEM, LTD. , HONG, Moo-Ho , KO, Dong-Hyun , EOM, Sung-Shik , CHOE, Yong-Jin , KWON, O-Hak , KIM, Dae-Chul , CHOI, Jae-Hui
发明人： HONG, Moo-Ho , KO, Dong-Hyun , EOM, Sung-Shik , CHOE, Yong-Jin , KWON, O-Hak , KIM, Dae-Chul , CHOI, Jae-Hui
IPC分类号： C07C45/50 , C07C29/16 , C07C45/82 , C07B41/00 , B01J31/28
摘要： The present invention relates to an apparatus for coproducting iso-type reaction product and alcohol from olefin, and a method for coproducting using the apparatus, in which the hydroformylation reactor provides a sufficient reaction area due to the broad contact surface area between the olefin and the synthesis gases that are the raw materials by a distributor plate installed in the reactor, and the raw materials can be sufficiently mixed with the reaction mixture due to the circulation of the reaction mixture so that the efficiency of the production of the aldehyde is excellent; and also the hydrogenation reactor suppresses the side reaction so that the efficiency for producing aldehyde and alcohol are all increased, and also iso-type reaction product and alcohol can be efficiently co-produced.

2. 发明申请

WO2008147129A1 METHOD FOR THE HYDROFORMYLATION OF OLEFINS AND APPARATUS USING THE SAME 审中-公开
标题翻译：烯烃的水解方法和使用该方法的装置
公开(公告)号：WO2008147129A1
公开(公告)日：2008-12-04
申请号：PCT/KR2008/003029
申请日：2008-05-29
申请人： LG CHEM, LTD. , HONG, Moo-Ho , KO, Dong-Hyun , NA, Sang-Oeb , EOM, Sung-Shik , LEE, Sang-Gi , KWON, O-Hark , KIM, Dae-Chul , CHOI, JAE-Hui
发明人： HONG, Moo-Ho , KO, Dong-Hyun , NA, Sang-Oeb , EOM, Sung-Shik , LEE, Sang-Gi , KWON, O-Hark , KIM, Dae-Chul , CHOI, JAE-Hui
IPC分类号： C07C45/50
CPC分类号： C07C45/50 , B01J4/002 , B01J10/00 , B01J19/2465 , B01J2219/0011 , Y02P20/582 , C07C47/02
摘要： The present invention relates to a method for preparing aldehydes by reacting olefins with a synthesis gas including carbon monoxide and hydrogen, and to an apparatus therefore. More particularly, the present invention relates to a method for preparing aldehydes, characterized by spraying and supplying olefins, synthesis gas including carbon monoxide and hydrogen, and a catalyst composition into an oxo reactor through a nozzle, and to an apparatus therefore. According to the present invention, the hydroformylation efficiency can be improved, thereby obtaining desirable aldehydes with a high yield.
摘要翻译：本发明涉及一种通过使烯烃与包括一氧化碳和氢气在内的合成气反应制备醛的方法及其装置。更具体地说，本发明涉及一种制备醛的方法，其特征在于通过喷嘴将催化剂组合物喷射并供给烯烃，包括一氧化碳和氢气的合成气，以及催化剂组合物装入氧代反应器，因此涉及一种设备。根据本发明，可以提高加氢甲酰化效率，从而以高产率获得所需的醛。

3. 发明申请

WO2007029929A1 METHOD OF PREPARING ORGANIC ACIDS FROM ALDEHYDE COMPOUNDS BY MEANS OF LIQUID PHASE OXIDATION REACTION 审中-公开
标题翻译：通过液相氧化反应制备醛类化合物有机酸的方法
公开(公告)号：WO2007029929A1
公开(公告)日：2007-03-15
申请号：PCT/KR2006/003286
申请日：2006-08-22
申请人： LG CHEM, LTD. , KO, Dong-hyun , LEE, Sang-gi , KWON, O-hak , MOON, Ji-joong , KIM, Dae-chul , CHOI, Jae-hui , HONG, Bog-ki , EOM, Sung-shik
发明人： KO, Dong-hyun , LEE, Sang-gi , KWON, O-hak , MOON, Ji-joong , KIM, Dae-chul , CHOI, Jae-hui , HONG, Bog-ki , EOM, Sung-shik
IPC分类号： C07C51/235
CPC分类号： C07C51/235 , Y02P20/542 , Y02P20/582 , C07C53/124 , C07C53/00 , C07C53/128
摘要： The present invention provides a method of preparing organic acids from aldehyde compounds by means of liquid phase oxidation which converts an aldehyde group of a compound harboring one or more aldehyde groups into a carboxyl group by using an ionic liquid as a reaction solvent or a reaction catalyst. According to the present invention, the ionic liquid is less volatile even at high temperature and stable against heat, enhancing conversion rate and selectivity and further increasing yield. In addition, the ionic liquid can be easily separated and recycled from the reactant and product.
摘要翻译：本发明提供一种通过液相氧化从醛化合物制备有机酸的方法，其通过使用离子液体作为反应溶剂或反应催化剂将含有一个或多个醛基的化合物的醛基转化为羧基。根据本发明，离子液体即使在高温下也不易挥发，对热稳定，提高转化率和选择性，进一步提高产率。此外，离子液体可以容易地从反应物和产物中分离和再循环。

4. 发明申请

WO2010093208A3 CATALYST COMPOSITION FOR HYDROFORMYLATION AND METHOD FOR PREPARING ALDEHYDES USING THE SAME 审中-公开
标题翻译：用于加氢甲酰化的催化剂组合物和使用该方法制备醛的方法
公开(公告)号：WO2010093208A3
公开(公告)日：2010-11-25
申请号：PCT/KR2010000921
申请日：2010-02-12
申请人： LG CHEMICAL LTD , CHOI JAE-HUI , KO DONG-HYUN , EOM SUNG-SHIK , HONG MOO-HO , KWON O-HARK , KIM DAE-CHUL
发明人： CHOI JAE-HUI , KO DONG-HYUN , EOM SUNG-SHIK , HONG MOO-HO , KWON O-HARK , KIM DAE-CHUL
IPC分类号： B01J31/24 , B01J31/28 , C07C45/49
CPC分类号： C07C45/49 , B01J31/1875 , B01J31/20 , B01J31/2208 , B01J31/2404 , B01J2231/321 , B01J2531/822 , B01J2531/827 , B01J2531/845 , C07C45/50 , C07F9/46 , C07F9/5022 , C07F9/655345 , C07F9/6571 , C07F9/657127 , C07C47/228 , C07C47/02
摘要： The present invention relates to a catalyst composition for hydroformylation and a method for preparing aldehydes using the same, wherein the catalyst composition for hydroformylation comprises: a triaryl phosphine ligand; a phosphine oxide or phosphine sulfide ligand having a specific chemical formula; and a transition metal catalyst. The catalyst composition provides high catalyst activity and stability and selectivity to normal aldehydes when used in the hydroformylation for preparing aldehydes from olefins.
摘要翻译：本发明涉及用于加氢甲酰化的催化剂组合物和使用该催化剂组合物制备醛的方法，其中用于加氢甲酰化的催化剂组合物包含：三芳基膦配体; 具有特定化学式的氧化膦或硫化膦配体; 和过渡金属催化剂。当用于由烯烃制备醛的加氢甲酰化反应中时，该催化剂组合物提供了高的催化剂活性和对正常醛的稳定性和选择性。

5. 发明申请

WO2013183796A1 HYDROFORMYLATION METHOD HAVING IMPROVED CATALYST STABILITY IN REACTION 审中-公开
标题翻译：具有改进的反应中催化稳定性的氢化方法
公开(公告)号：WO2013183796A1
公开(公告)日：2013-12-12
申请号：PCT/KR2012/004408
申请日：2012-06-04
申请人： LG CHEM, LTD. , KO, Dong-Hyun , EOM, Sung-Shik , HONG, Moo-Ho , KWON, O-Hak , KIM, Dae-Chul , CHOI, Jae-Hui
发明人： KO, Dong-Hyun , EOM, Sung-Shik , HONG, Moo-Ho , KWON, O-Hak , KIM, Dae-Chul , CHOI, Jae-Hui
IPC分类号： C07C49/20 , C07C47/222 , B01J31/02 , C07F9/6571 , C07F9/06
CPC分类号： C07C45/56 , B01J31/02 , B01J31/0208 , B01J31/185 , B01J2231/321 , B01J2531/822 , C07C45/50 , C07C47/222 , C07C49/20 , C07F9/65746 , C07C47/02
摘要： Disclosed is a hydroformylation method having improved catalyst stability in a reaction. Advantageously, provided is a hydroformylation method in which a specific α,β-unsaturated carbonyl compound is incorporated during a hydroformylation reaction to prevent alkyl phosphite decomposed from a phosphite ligand from acting as a catalyst poison, thereby improving a yield of reaction and inhibiting decomposition of ligand and catalyst.
摘要翻译：公开了一种在反应中具有改善的催化剂稳定性的加氢甲酰化方法。有利地，提供加氢甲酰化方法，其中在加氢甲酰化反应期间引入特定的α，β-不饱和羰基化合物以防止从亚磷酸酯配体分解的亚磷酸烷基作为催化剂毒物，由此提高反应产率和抑制分解配体和催化剂。

6. 发明申请

WO2012008717A2 APPARATUS FOR COPRODUCTING ISO TYPE REACTION PRODUCTS AND ALCOHOLS FROM OLEFINS, AND METHOD FOR COPRODUCTING THEM USING THE APPARATUS 审中-公开
标题翻译：用于从油脂中混合ISO类型反应产物和醇的装置，以及使用装置共同制造它们的方法
公开(公告)号：WO2012008717A2
公开(公告)日：2012-01-19
申请号：PCT/KR2011005046
申请日：2011-07-11
申请人： LG CHEMICAL LTD , HONG MOO-HO , KO DONG-HYUN , EOM SUNG-SHIK , CHOE YONG-JIN , KWON O-HAK , KIM DAE-CHUL , CHOI JAE-HUI
发明人： HONG MOO-HO , KO DONG-HYUN , EOM SUNG-SHIK , CHOE YONG-JIN , KWON O-HAK , KIM DAE-CHUL , CHOI JAE-HUI
IPC分类号： C07C45/50 , B01J31/28 , C07B41/00 , C07C29/16 , C07C45/82
CPC分类号： C07C45/50 , C07C29/141 , C07C29/175 , C07C45/82 , C07C47/02 , C07C31/12 , C07C31/125
摘要： The present invention relates to an apparatus for coproducting iso-type reaction product and alcohol from olefin, and a method for coproducting using the apparatus, in which the hydroformylation reactor provides a sufficient reaction area due to the broad contact surface area between the olefin and the synthesis gases that are the raw materials by a distributor plate installed in the reactor, and the raw materials can be sufficiently mixed with the reaction mixture due to the circulation of the reaction mixture so that the efficiency of the production of the aldehyde is excellent; and also the hydrogenation reactor suppresses the side reaction so that the efficiency for producing aldehyde and alcohol are all increased, and also iso-type reaction product and alcohol can be efficiently co-produced.
摘要翻译：本发明涉及一种用于从烯烃中共同引发异型反应产物和醇的装置，以及使用该装置的副产物的方法，其中加氢甲酰化反应器由于烯烃与烯烃之间的宽接触表面积而提供足够的反应面积通过安装在反应器中的分配器板作为原料的合成气体，并且由于反应混合物的循环，原料可以与反应混合物充分混合，使得醛的生产效率优异; 并且氢化反应器抑制副反应，使得生成醛和醇的效率全部增加，并且可以有效地共同生产异型反应产物和醇。

7. 发明申请

WO2010082793A2 APPARATUS FOR PRODUCING ALCOHOLS FROM OLEFINS 审中-公开
标题翻译：用于从烯烃生产醇的装置
公开(公告)号：WO2010082793A2
公开(公告)日：2010-07-22
申请号：PCT/KR2010000283
申请日：2010-01-15
申请人： LG CHEMICAL LTD , GO DONG-HYUN , EOM SUNG-SHIK , CHOE YONG-JIN , LEE CHAN-HONG , HONG MOO-HO , KWON O-HARK , KIM DAE-CHUL , CHOI JAE-HUI
发明人： GO DONG-HYUN , EOM SUNG-SHIK , CHOE YONG-JIN , LEE CHAN-HONG , HONG MOO-HO , KWON O-HARK , KIM DAE-CHUL , CHOI JAE-HUI
IPC分类号： C07C29/152 , C07C29/157
CPC分类号： C07C29/141 , B01J23/72 , B01J25/02 , B01J31/20 , B01J31/2234 , B01J31/2404 , B01J2231/321 , B01J2531/822 , C07C45/50 , C07C31/125 , C07C47/02
摘要： The present invention relates to an apparatus for producing alcohols from olefins, comprising: a hydroformylation reactor wherein aldehydes are produced from olefins; a hydrogenation reactor wherein the aldehydes are hydrogenated to produce alcohols; and a distillation column. The hydroformylation reactor is equipped with a distributor plate which has a broad contact surface for providing sufficient reaction area for reactants such as olefins and synthesis gas, and allows the reaction mixture to circulate and mix sufficiently, which contribute to excellent efficiency in terms of production of aldehydes. In addition, the hydrogenation reactor suppresses sub-reactions to improve the production yield of alcohols.
摘要翻译：本发明涉及一种用于从烯烃生产醇的设备，包括：加氢甲酰化反应器，其中醛由烯烃生产; 氢化反应器，其中醛被氢化以产生醇; 和蒸馏塔。加氢甲酰化反应器配备有分布板，其具有宽的接触表面，用于为反应物例如烯烃和合成气提供足够的反应面积，并允许反应混合物充分循环和混合，这有助于在生产方面优异的效率醛。此外，氢化反应器抑制副反应以提高醇的产率。

8. 发明授权

KR101544133B1 Mask for face beauty and manufacturing method thereof 有权
标题翻译：面料美容及其制造方法
公开(公告)号：KR101544133B1
公开(公告)日：2015-08-12
申请号：KR20150057394
申请日：2015-04-23
申请人： KIM DAE CHUL , JUNG YOUNG BO
发明人： KIM DAE CHUL , JUNG YOUNG BO
IPC分类号： A45D44/00 , A45D44/22 , A61K8/02
摘要： 본 발명은 게르마늄 분말과 아파타이트가 적정 비율로 배합된 실리콘 재질의 안면 미안용 마스크 및 이의 제조방법에 관한 것이다.
본 발명에 따른 안면 미안용 마스크는 안면 형상에 대응되는 입체적인 타원형상을 가지는 안면부; 상기 안면부의 양측에 일체로 연장 형성되는 한 쌍의 밴드부; 및 상기 밴드부에 구비되어 상기 한 쌍의 밴드부를 결합시키는 고정수단을 포함하되, 상기 안면부는, 얼굴의 눈 부분에 대응하는 위치에 형성된 안공; 상기 안공 하부에 위치하고 사람의 코 부분에 대응하는 위치에 형성된 돌출부; 및 상기 돌출부 하부에 위치하고 사람 얼굴의 입 부분에 대응하는 위치에 형성된 입공을 구비하고, 상기 돌출부의 일측에는 사람의 콧구멍에 대응하는 위치에 형성된 절개공이 형성되며, 상기 밴드부는 사람의 귀에 대응되는 위치에 일정 부분 절개되어 형성된 귀공을 포함하고, 상기 안면부 및 밴드부는 실시콘 재질로 형성되고, 상기 실리콘 재질은 게르마늄 분말 및 아파타이트 분말이 혼합되어 형성된다.
상기한 구성에 의해 본 발명에 따른 안면 미안용 마스크는 실리콘 재질의 안면 마스크를 얼굴 형상에 대응되도록 형성하되, 상기 안면 마스크에 얼굴 피부의 노폐물을 제거하고, 세균의 기생을 억제할 수 있도록 원적외선을 다량 방사하고 음이온을 생성하는 게르마늄 분말과, 상기 원적외선과 음이온이 피부 깊숙이 침투할 수 있도록 촉매작용을 하는 아파타이트를 적정 비율로 배합함으로써, 얼굴 피부의 건강과 미용을 증진시킴은 물론 혈액순환을 촉진할 수 있다.
摘要翻译：本发明涉及一种面部美容用面罩，其特征在于，以适当比率混合锗电力和磷灰石的硅材料制成。根据本发明，面部美容用面具包括：与脸部形状对应的三维椭圆形的面部单元，一对带状单元，其形成为一体地延伸到面单元的两侧; 以及固定装置，其布置在带单元上并将带单元彼此连接。面部单元包括：形成在与脸部的眼睛区域相对应的位置上的眼孔; 突出部，其位于眼孔下方并形成在与人的鼻部区域对应的位置; 以及位于突出部下方并形成在与人的面部的唇部区域对应的位置的唇孔。在突起的一侧，在对应于人的鼻孔的位置上形成切口孔。带单元包括通过在对应于人的耳朵的位置部分地切割而形成的耳孔。面单元和带单元由硅材料制成，其通过混合锗电源和磷灰石粉而形成。根据本发明，用于面部美容的面具由硅材料制成，并且形成为对应于面部的形状。锗粉以大量的远红外线照射面罩，并产生阴离子以去除面皮上的废物并防止细菌寄生，并且进行催化剂作用以制造远红外线的磷灰石和阴离子深深渗透皮肤，以适当的比例混合。因此，面部美容面膜可以促进面部皮肤的健康，可以增强面部皮肤的美丽，也可促进血液循环。

9. 发明公开

KR20200145653A 접이식 미로 메이즐링 구조 审中-公开
公开(公告)号：KR20200145653A
公开(公告)日：2020-12-30
申请号：KR20200025167
申请日：2020-02-28
申请人： KIM DAE CHUL
发明人： KIM DAE CHUL
IPC分类号： A63F9/00 , A63F9/10 , A63F9/12
摘要： 본발명은접이식미로메이즐링구조에관한것으로서, 보다상세하게는접으면서미로의길을찾아가도록된 미로메이즐링구조로서, 접을수 있도록된 페이퍼본체와, 상기페이퍼본체에인쇄되는미로인쇄부들로이루어진미로부로이루어지며, 상기페이퍼본체를접어상기미로인쇄부들을연결하여미로의길을찾도록되어, 미로인쇄부들이인쇄된페이퍼본체를접으면서, 미로인쇄부들은연결하여길을찾아미로를탈출하도록함으로써, 이용자에게재미를선사함과아울러두뇌개발에도움을줄 수있게되는효과가있다.

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