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    • 1. 发明申请
    • WAFER-CLEANING SOLUTION AND PROCESS FOR THE PRODUCTION THEREOF
    • 清洁溶液及其生产方法
    • WO1997018582A1
    • 1997-05-22
    • PCT/JP1996003313
    • 1996-11-11
    • DAIKIN INDUSTRIES, LTD.KEZUKA, TakehikoSUYAMA, MakotoKAMIYA, FumihiroITANO, Mitsushi
    • DAIKIN INDUSTRIES, LTD.
    • H01L21/304
    • H01L21/02052C11D1/24C11D1/29C11D3/042C11D3/3947C11D7/08C11D11/0047
    • A wafer-cleaning solution comprising 20 to 60 wt.% of hydrogen fluoride containing 0.1 to 1000 ppm of at least one compound selected from among CnH2n+1ph(SO3M)Oph(SO3M), CnH2n+1phO(CH2CH2O)mSO3M and CnH2n+1O(CH2CH2O)mSO3M (wherein ph is phenylene; n is 5 to 20; m is 0 to 20; and M is hydrogen or a salt group) dissolved therein, and the balance of water (with the total amount being 100 wt.%); and a process for producing a wafer-cleaning solution by adding water, H2O2, HNO3, CH3COOH, NH4F and so on to the above solution. Another wafer-cleaning solution comprising HF, H2O2, HNO3, CH3COOH, NH4F, HCl, H3PO4, at least one ammonium hydroxide of the general formula: [(R1)(R2)(R3)(R4)N] OH (R1, R2, R3 and R4 being each independently optionally hydroxylated C1-C6 alkyl), 0,01 to 1000 ppm of at least one surfactant selected from among CnH2n+1ph(SO3M)Oph(SO3M), CnH2n+1phO(CH2CH2O)mSO3M and CnH2n+1O(CH2CH2O)mSO3M (wherein ph, n, m and M are each as described above) which is dissolved in the above compounds, and the balance of water (with the total amount being 100 wt.%).
    • 一种晶片清洁溶液,其包含20至60重量%的含有0.1至1000ppm的至少一种选自CnH2n + 1ph(SO3M)Oph(SO3M),CnH2n + 1phO(CH2CH2O)mSO3M和CnH2n + 1O的化合物的氟化氢 (CH2CH2O)mSO3M(其中ph为亚苯基; n为5〜20; m为0〜20; M为氢或盐基),余量为水(总量为100重量%) ; 以及通过向上述溶液中加入水,H 2 O 2,HNO 3,CH 3 COOH,NH 4 F等来制造晶片清洁溶液的方法。 另一种包含HF,H 2 O 2,HNO 3,CH 3 COOH,NH 4 F,HCl,H 3 PO 4,至少一种通式如下的氢氧化铵的晶片清洗溶液:[(R1)(R2)(R3)(R4)N] - (R 1,R 2,R 3和R 4各自独立地任选羟基化的C 1 -C 6烷基),0.01-1000ppm的至少一种选自CnH2n + 1ph(SO3M)Oph(SO3M),CnH2n + 1phO CH2CH2O)mSO3M和CnH2n + 10(CH2CH2O)mSO3M(其中ph,n,m和M各自如上所述),其余溶于上述化合物,余量为水(总量为100重量%) 。