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    • 1. 发明申请
    • REACTIVE AMINE-FUNCTIONAL SILICONE-POLYETHER BLOCK COPOLYMERS
    • 反应性胺官能聚硅氧烷嵌段共聚物
    • WO2011127108A1
    • 2011-10-13
    • PCT/US2011/031322
    • 2011-04-06
    • DOW CORNING CORPORATIONDEETH, Brian, P.KENNAN, John, JosephLEWIS, Kevin, Dale
    • DEETH, Brian, P.KENNAN, John, JosephLEWIS, Kevin, Dale
    • C08G77/46
    • C08G77/46
    • Silicone-polyether block copolymers are disclosed, having the average formula: R 4 R 1 2 Si(OR 5 2 Si) m {[R 2 O(C q H 2 q O) p R 2 R 1 2 Si(OR 5 2 Si) k ] n R 2 O(C q H 2 q O) p R 2 R 1 2 Si) m } h OSiR 1 2 R 4 wherein R 1 is C 1 -C 10 hydrocarbyl; R 2 is C 1 -C 10 hydrocarbylene; R 3 is R 1 or H; R 4 is -R 2 -NR 3 2 or -R 2 -NR 3 -R 2 -NR 3 2 ; R 5 is R 1 or R 4 ; h is 1 to 100; k is 2 to 500; m is 2 to 500; n is 0 to 30; p is 2 to 120; and q is 2 to 4. The silicone-polyether block copolymers comprise two terminal amine functionalities and may comprise varying degrees of pendent amine functionality. In a method for synthesizing linear silicone-polyether block copolymers of the above formula, a reaction mixture is formed by combining a polyether, an organosilicon component, an endblocking agent, and a catalyst. Thereupon, the reaction mixture is heated to produce a silicone-polyether block copolymer having at least one pendent amine functionality and a number-average molecular weight from 2000 to 500,000. Also disclosed are silicone-polyether block copolymers prepared according to the above method.
    • 公开了具有以下平均化学式的硅氧烷 - 聚醚嵌段共聚物:R 4 R 12 Si(OR 5 2Si)m {[R 2 O(C q H 2 q O)p R 2 R 2 Si(OR 5 2Si)k] n R 20(C q H 2 q O) 2Si)m} h OSiR1 2R4其中R1是C1-C10烃基; R2是C1-C10亚烃基; R3是R1或H; R4是-R2-NR3 2或-R2-NR3-R2-NR3 2; R5是R1或R4; h为1〜100; k为2〜500; m为2〜500; n为0〜30; p为2〜120; 并且q为2至4.硅氧烷 - 聚醚嵌段共聚物包含两个末端胺官能团并且可以包含不同程度的侧挂胺官能度。 在合成上述式的直链硅氧烷 - 聚醚嵌段共聚物的方法中,通过将聚醚,有机硅组分,封端剂和催化剂组合形成反应混合物。 因此,将反应混合物加热以产生具有至少一个侧挂胺官能团和数均分子量为2000至500,000的硅氧烷 - 聚醚嵌段共聚物。 还公开了根据上述方法制备的硅氧烷 - 聚醚嵌段共聚物。