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1. 发明授权

US5720867A Process for the electrochemical recovery of the metals copper, zinc, lead, nickel or cobalt 失效
标题翻译：金属铜，锌，铅，镍或钴的电化学回收方法
公开(公告)号：US5720867A
公开(公告)日：1998-02-24
申请号：US549014
申请日：1995-10-27
申请人： Nikola Anastasijevic , Gerhard Jedlicka , Karl Lohrberg
发明人： Nikola Anastasijevic , Gerhard Jedlicka , Karl Lohrberg
IPC分类号： C25C1/00 , C25C7/00 , C25D21/06 , C25D9/00 , C25D15/00 , C25D21/18
CPC分类号： C25C1/00 , C25C7/00
摘要： An electrolytic cell comprising bipolar electrodes is employed for electrochemical deposition of copper, zinc, lead, nickel or cobalt. An interior space is provided between the cathode side and the anode side of a bipolar electrode. The electrolyte can flow substantially without an obstruction through the interelectrode space between adjacent electrodes. The current densities in the interelectrode space amount to 800 to 8000 A/m.sup.2. Gas is evolved on the anode side of the bipolar electrodes and causes liquid to flow along the anode side. In the middle of the height of the anode side that liquid flow has a vertical component having a velocity of 5 to 100 cm/second. Electrolyte solution flows from the upper edge portion of the anode side to a return flow space, in which the solution flows downwardly. From the return flow space the solution is returned to the lower portion of the interelectrode space.
摘要翻译：使用包含双极电极的电解池用于铜，锌，铅，镍或钴的电化学沉积。在双极电极的阴极侧和阳极侧之间设置内部空间。电解质可以基本上流过相邻电极之间的电极间空间而阻塞。电极间空间的电流密度为800〜8000A / m2。气体在双极电极的阳极侧放出，并使液体沿阳极侧流动。在阳极侧的高度的中间，液体流具有5-100cm /秒的速度的垂直分量。电解质溶液从阳极侧的上边缘部分流向其中溶液向下流动的回流空间。从返回流动空间中，溶液返回到电极间空间的下部。

2. 发明授权

US4502935A Electrolytic cell having a membrane and vertical electrodes 失效
标题翻译：具有膜和垂直电极的电解槽
公开(公告)号：US4502935A
公开(公告)日：1985-03-05
申请号：US507840
申请日：1983-06-24
申请人： Karl Lohrberg , Peter Kohl , G/u/ nter Haas
发明人： Karl Lohrberg , Peter Kohl , G/u/ nter Haas
IPC分类号： C25B9/00 , C25B9/08 , C25B9/20 , C25B11/02 , C25B9/04
CPC分类号： C25B9/08 , C25B11/02
摘要： In an electrolytic cell having a membrane and vertical electrodes composed of a plurality of units,a. the electrode having one polarity is horizontally divided into a plurality of units,b. the electrode having the opposite polarity is vertically divided into a plurality of units, andc. the units of at least one of the two electrodes are adapted to be displaced by spring elements. Spacers are suitably provided between the units of that electrode which is not contacted by the membrane.
摘要翻译：在具有由多个单元构成的膜和垂直电极的电解槽中，具有一个极性的电极被水平地分成多个单元，b。具有相反极性的电极被垂直分成多个单元，c。两个电极中的至少一个电极的单元适于被弹簧元件移位。间隔物适宜地设置在不与膜接触的该电极的单元之间。

3. 发明授权

US4247375A Process of electrolyzing aqueous solution of alkali halides 失效
标题翻译：电解卤化碱水溶液的工艺
公开(公告)号：US4247375A
公开(公告)日：1981-01-27
申请号：US62270
申请日：1979-07-30
申请人： Karl Lohrberg
发明人： Karl Lohrberg
IPC分类号： C25B1/46 , C25B15/08 , C25B1/34
CPC分类号： C25B15/08 , C25B1/46
摘要： An improvement in a process of electrolyzing an aqueous solution of an alkali metal halide in a membrane cell in which a pH above 1.0 is maintained in the anode chamber, the alkali metal halide solution is removed from the anode chamber and its concentration and pH are increased is described. The improvement resides in thereafter decreasing the pH of at least a portion of the resultant solution to below 1.0 and thereafter adjusting the pH to 1.0 to 6.0 and returning the so adjusted solution to the anode chamber.
摘要翻译：在阳极室中保持pH高于1.0的膜池中电解碱金属卤化物水溶液的方法的改进，从阳极室除去碱金属卤化物溶液，并且其浓度和pH增加被描述。改进之处在于将所得溶液的至少一部分的pH降低到1.0以下，然后将pH调节至1.0至6.0并将如此调节的溶液返回到阳极室。

4. 发明专利

BR8606411A 未知
公开(公告)号：BR8606411A
公开(公告)日：1987-10-13
申请号：BR8606411
申请日：1986-12-23
申请人： KARL LOHRBERG
发明人： LOHRBERG KARL
IPC分类号： B01D3/20 , B01J10/00 , C01B11/02
摘要： Chlorine dioxide is increasibly used to bleach pulp and the like. Chlorine dioxide is produced in a reactor, which contains a plurality of superimposed bubble cap trays, which are provided with passages for the gas and with duct, which is independent of the gas passages and serves as an overflow for the liquid. In order to maintain a maximum ClO3/acid ratio for the longest time possible, the reaction chamber above each bubble cap tray is divided into a large number of reaction compartments by vertical partitions, which define openings for the passage of the reaction liquid. Acid can be supplied to each compartment. The partitions can be used to define in each reaction chamber any desired number of reaction compartments, which are connected in parallel for the flow of acid and are connected in series for the flow of the chlorate solution.

5. 发明授权

US5637206A Process for the electrochemical production of ammonium polysulfide 失效
标题翻译：多硫化铵电化学生产工艺
公开(公告)号：US5637206A
公开(公告)日：1997-06-10
申请号：US599885
申请日：1996-02-14
申请人： Nikola Anastasijevic , Eilhard Hillrichs , Karl Lohrberg , Gert Ungar
发明人： Nikola Anastasijevic , Eilhard Hillrichs , Karl Lohrberg , Gert Ungar
IPC分类号： C01C1/20 , C25B1/00 , C23F11/00 , C02F1/461
CPC分类号： C25B1/00 , C01C1/20
摘要： The ammonium polysulfide is produced in at least one electrochemical cell, to which an aqueous ammonium sulfide solution is supplied as electrolyte. The cell comprises an anode, a gas diffusion cathode, and between the anode and the cathode an electrolyte chamber, where the cell voltage is 0.01 to 5V. The cathode has an electrically conductive, gas-permeable carbon layer, over which flows gas containing free oxygen, and which is in contact with the electrolyte. O.sub.2 -containing gas is introduced into the electrolyte chamber, thereby forming hydroperoxide anions (OOH.sup.-) in the electrolyte chamber. From the electrolyte chamber a solution containing ammonium polysulfide and a residual gas are withdrawn.
摘要翻译：多硫化铵在至少一个电化学电池中产生，其中作为电解质供应硫化铵水溶液。电池包括阳极，气体扩散阴极，阳极和阴极之间，电池电压为0.01至5V。阴极具有导电的，透气的碳层，在其上流动含有游离氧的气体，并与电解质接触。含氧气体被引入到电解质室中，从而在电解质室中形成氢过氧化物阴离子（OOH-）。从电解槽中取出含有多硫化铵和残余气体的溶液。

6. 发明授权

US4839003A Process for producing alkali hydroxide, chlorine and hydrogen by the electrolysis of an aqueous alkali chloride solution in a membrane cell 失效
标题翻译：通过在膜电池中电解碱性氯化碱水溶液来生产碱金属氢氧化物，氯和氢的方法
公开(公告)号：US4839003A
公开(公告)日：1989-06-13
申请号：US116433
申请日：1987-11-03
申请人： Rainer Dworak , Karl Lohrberg
发明人： Rainer Dworak , Karl Lohrberg
IPC分类号： C01D3/16 , C25B1/46 , C25B15/08
CPC分类号： C25B15/08 , C01D3/16
摘要： Alkali hydroxide, chlorine and hydrogen are produced from an aqueous alkali chloride solution by membrane electrolysis. A high-NaCl solid salt, which contains impurities, is dissolved in water in a salt dissolver. Precipitating chemicals are added to the salt solution to precipitate the impurities. The resulting mixture is fed to a thickener, from which precipitates and clarified raw brine are separately withdrawn. The clarified raw brine from the thickener is divided at a ratio between 2:1 and 20:1 into first and second partial streams. The larger first partial stream is mixed with the salt solution and the precipitating chemicals before entering the thickener and the resulting mixture is fed to the thickener. The second partial stream of the clarified raw brine is fed through a fine purifier to the electrolytic cell. Spent brine from the electrolytic cell is fed to the salt dissolver.
摘要翻译：通过膜电解由氯化碱水溶液制备氢氧化碱，氯和氢。将含有杂质的高NaCl固体盐溶解在盐溶解器中的水中。将沉淀的化学品加入到盐溶液中以沉淀杂质。将所得混合物加入到增稠剂中，从中分离出沉淀物和澄清的生盐水。来自增稠剂的澄清的原料盐水以2:1至20:1的比例分成第一和第二部分流。在进入增稠剂之前，较大的第一部分流与盐溶液和沉淀化学品混合，并将所得混合物进料至增稠剂。澄清的生盐水的第二部分流通过细小的净化器送入电解池。将来自电解池的废水进料到盐溶解器中。

7. 发明授权

US4294815A Process of producing chlorine dioxide and, if desired, chlorine 失效
标题翻译：生产二氧化氯的方法，如果需要的话氯气
公开(公告)号：US4294815A
公开(公告)日：1981-10-13
申请号：US93708
申请日：1979-11-13
申请人： Karl Lohrberg , Siegfried Bielz , Paul Janisch
发明人： Karl Lohrberg , Siegfried Bielz , Paul Janisch
IPC分类号： C25B1/26 , B01J19/24 , C01B11/02
CPC分类号： B01J19/2465 , B01J19/2475 , C01B11/025
摘要： A process for the production of chlorine dioxide by membrane electrolysis of aqueous sodium chloride, reaction of hydrogen and chlorine so-formed to form hydrogen chloride and reaction of the so-formed hydrogen chloride with the sodium chlorate also formed by the electrolysis to form chlorine dioxide is disclosed. Also disclosed is the production of chlorine by such a process.
摘要翻译：通过膜电解氯化钠水溶液生产二氧化氯的方法，如此形成的氢和氯的反应形成氯化氢，并且如此形成的氯化氢与氯酸钠的反应也通过电解形成，形成二氧化氯被披露。还公开了通过这种方法生产氯。

8. 发明授权

US4278568A Process of manufacturing sheet metal elements or strip having a catalytic surface structure 失效
标题翻译：制造具有催化表面结构的金属片或带材的方法
公开(公告)号：US4278568A
公开(公告)日：1981-07-14
申请号：US50018
申请日：1979-06-19
申请人： Karl Lohrberg , Heinz Wullenweber , Jurgen Muller , Bernd Sermond
发明人： Karl Lohrberg , Heinz Wullenweber , Jurgen Muller , Bernd Sermond
IPC分类号： B01J25/00 , B01J35/06 , B01J37/02 , B21B3/00 , C25B11/00 , C25B11/06 , H01M4/98 , B01J25/02 , B01J35/02
CPC分类号： B01J25/00 , B01J35/06 , B01J37/0225 , C25B11/00
摘要： In the manufacture of sheet metal elements or strip having a catalytic surface structure, a mixture of skeleton material powder, and of Raney alloy powder is rolled onto the starting sheet metal element or strip substrate, sintered in a reducing atmosphere, whereafter the soluble component of the Raney alloy is dissolved out.To ensure an adequate adherence of the catalytic surface structure, the operation in which the above-mentioned mixture is rolled onto the substrate is accompanied by a simultaneous cold-working of the substrate with a deformation of 20 to 60% within each cold-forming step.The coated sheet metal element or strip substrates or any spherical bodies made therefrom serve as electrodes in electrolytic processes.
摘要翻译：在具有催化表面结构的钣金元件或带材的制造中，将骨架材料粉末和阮内合金粉末的混合物轧制到起始金属片或基材上，在还原气氛中烧结，然后将可溶成分阮内合金溶出。为了确保催化剂表面结构的适当粘附，将上述混合物轧制到基材上的操作伴随着在每个冷成型步骤中基板的变形为20至60％的同时冷加工。涂覆的金属板金属元件或带状基板或由其制成的任何球形体在电解过程中用作电极。

9. 发明授权

US5167939A Process for removing calcium and magnesium ions from an aqueous alkali chloride solution for use in membrane electrolysis 失效
标题翻译：从用于膜电解的水性碱性氯化物溶液中去除钙和镁离子的方法
公开(公告)号：US5167939A
公开(公告)日：1992-12-01
申请号：US741311
申请日：1991-08-07
申请人： Karl Lohrberg , Rainer Dworak
发明人： Karl Lohrberg , Rainer Dworak
IPC分类号： B01D15/04 , B01J39/04 , B01J47/02 , C01D3/14 , C01D3/16 , C02F1/42 , C02F1/66 , C25B1/26 , C25B15/00
CPC分类号： C01D3/145
摘要： The aqueous alkali chloride solution is coarsely purified first. In the succeeding fine purifier the solution, which contains calcium ions, magnesium ions and undissolved magnesium compounds, is passed through a plurality of purification stages (ion exchange stages), which contain cation exchange granulate. In the fine purifier the solution having a pH value of about 10 to 11 is passed through a first ion exchange stage and the solution coming from the first ion exchange is acidified to decrease its pH value by at least 0.5. The solution is subsequently passed through at least one second ion exchange stage and a solution which is virtually free of undissolved magnesium compounds is withdrawn from the fine purification means. The acidified solution fed to the second ion exchange stage has preferably a pH value of 5 to 10.
摘要翻译：首先对碱性氯化钠水溶液进行粗提纯。在后续的微量净化器中，含有钙离子，镁离子和未溶解的镁化合物的溶液通过含有阳离子交换颗粒的多个纯化阶段（离子交换阶段）。在微量净化器中，将pH值为约10至11的溶液通过第一离子交换阶段，并且来自第一离子交换的溶液被酸化以将其pH值降低至少0.5。随后将溶液通过至少一个第二离子交换阶段，并且从精细纯化装置中取出基本上不含未溶解的镁化合物的溶液。进料到第二离子交换阶段的酸化溶液的pH值优选为5〜10。

10. 发明授权

US4938944A Method of and reactor for producing chlorine dioxide 失效
标题翻译：生产二氧化氯的方法和反应器
公开(公告)号：US4938944A
公开(公告)日：1990-07-03
申请号：US361036
申请日：1989-06-02
申请人： Rainer Dworak , Peter Kohl , Karl Lohrberg , Reinhard Muller
发明人： Rainer Dworak , Peter Kohl , Karl Lohrberg , Reinhard Muller
IPC分类号： C01B11/02
CPC分类号： C01B11/025 , B01J14/00 , B01J19/245 , B01J2219/00083
摘要： For the production of a gaseous mixture contains chlorine dioxide and chlorine, alkali chlorate in an aqueous solution with acid is reacted in a reactor. The reactor comprises a plurality of superimposed reaction levels which are traversed by the solution from top to bottom. In the lower portion of the reactor the solution in which chlorate and acid have been depleted is reboiled in a reboiling chamber by an indirect heating at a temperature in the range from 100.degree. to 110.degree. C. The depleted solution is conducted from the reboiling chamber to a pressure chamber, in which a pressure of at least 1.2 bar is maintained. In the pressure chamber the solution is reboiled at temperatures from 110.degree. to 150.degree. C. and the vapors formed by the reboiling in the pressure chamber are conducted through the reboiling chamber for an indirect heating therein.
摘要翻译：为了生产含有二氧化氯和氯的气态混合物，在酸的水溶液中的氯酸碱在反应器中反应。反应器包括多个叠加的反应水平，其通过溶液从上到下穿过。在反应器的下部，其中氯酸盐和酸已经耗尽的溶液通过在100-110℃的温度下间接加热在再沸室中再沸腾。贫化溶液从再沸室到压力室，其中保持至少1.2巴的压力。在压力室中，溶液在110℃至150℃的温度下再沸腾，通过再沸器形成的蒸气通过再沸腾室进行间接加热。

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