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    • 6. 发明申请
    • LOW TEMPERATURE Li/FeS2 BATTERY
    • 低温Li / FeS2电池
    • WO2006026415A3
    • 2006-09-28
    • PCT/US2005030379
    • 2005-08-25
    • EVEREADY BATTERY INCWEBBER ANDREW AKAPLIN DAVID A
    • WEBBER ANDREW AKAPLIN DAVID A
    • H01M4/58H01M6/16H01M10/052H01M10/0568H01M10/0569H01M10/36
    • H01M6/166H01M4/5815H01M6/164H01M10/052H01M10/0568H01M10/0569H01M2300/0037
    • The invention is an electrochemical battery cell, such as a Li/FeS 2 cell, with a nonaqueous liquid electrolyte having a solvent with a high ether content and a solute including LiI and one or more additional salts, preferably LiCF 3 SO 3 , that can avoid a sharp drop in voltage on high rate and high power discharge at low temperatures, while still providing reasonable capacity on high rate and high power discharge at room temperature. The electrolyte solvent includes 1,3-dioxolane and 1,2-dimethoxyethan in a volume ratio greater than 45 : 55 and less than 85 : 15. When the total solute concentration in the electrolyte is low (0.40 to 0.65 mol/l solvent), the solute contains at least 35 mole percent LiI, and when the total solute concentration in the electrolyte is high (greater than 0.65 to 2.0 mol/l solvent), the solute contains less than 35 mole percent LiI.
    • 本发明是一种电化学电池单元,例如Li / FeS 2 电池,其非水电解液含有具有高醚含量的溶剂和包含LiI和一种或多种其它盐的溶质,优选 LiCF 3 SO 3 3,可以避免在高速率和高功率放电下在低温下的电压急剧下降,同时在高速率和高功率放电方面仍然提供合理的容量 在室温下。 电解质溶剂包括体积比大于45:55且小于85:15的1,3-二氧戊环和1,2-二甲氧基乙烷。当电解质中的总溶质浓度低(0.40至0.65mol / l溶剂)时, 溶质含有至少35摩尔%的LiI,并且当电解质中的总溶质浓度高(大于0.65-2.0摩尔/升溶剂)时,溶质含有少于35摩尔%的LiI。
    • 7. 发明申请
    • LOW TEMPERATURE Li/FeS2 BATTERY
    • 低温Li / FeS2电池
    • WO2006026415A2
    • 2006-03-09
    • PCT/US2005/030379
    • 2005-08-25
    • EVEREADY BATTERY COMPANY, INC.WEBBER, Andrew, A.KAPLIN, David, A.
    • WEBBER, Andrew, A.KAPLIN, David, A.
    • H01M4/58H01M10/052H01M10/0568H01M10/0569H01M10/36
    • H01M6/166H01M4/5815H01M6/164H01M10/052H01M10/0568H01M10/0569H01M2300/0037
    • The invention is an electrochemical battery cell, such as a Li/FeS 2 cell, with a nonaqueous liquid electrolyte having a solvent with a high ether content and a solute including LiI and one or more additional salts, preferably LiCF 3 SO 3 , that can avoid a sharp drop in voltage on high rate and high power discharge at low temperatures, while still providing reasonable capacity on high rate and high power discharge at room temperature. The electrolyte solvent includes 1,3-dioxolane and 1,2-dimethoxyethan in a volume ratio greater than 45 : 55 and less than 85 : 15. When the total solute concentration in the electrolyte is low (0.40 to 0.65 mol/l solvent), the solute contains at least 35 mole percent LiI, and when the total solute concentration in the electrolyte is high (greater than 0.65 to 2.0 mol/l solvent), the solute contains less than 35 mole percent LiI.
    • 本发明是一种电化学电池组电池,例如Li / FeS 2电池,其具有非水液体电解质,所述非水电解液具有高醚含量的溶剂和溶质,所述溶质包括LiI 和一种或多种另外的盐,优选LiCF 3 SO 3,其可以避免在低速下高速率和高功率放电时电压的急剧下降,同时仍然提供合理的 室温下高倍率和高功率放电的容量。 电解质溶剂包括体积比大于45:55且小于85:15的1,3-二氧戊环和1,2-二甲氧基乙烷。当电解质中的总溶质浓度低(0.40至0.65mol / l溶剂)时, ,溶质含有至少35摩尔%的LiI,并且当电解质中的总溶质浓度高(大于0.65至2.0摩尔/升溶剂)时,溶质含有小于35摩尔%的LiI。